• Title/Summary/Keyword: elution

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Migration of THO & Np in a Fractured Granite Core at Deep Underground Laboratory

  • PARK Chung-Kyun;CHO Won-Zin;HAHN Pil-Soo;KIENZLER B.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.255-263
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    • 2005
  • Migration experiments of THO and 237Np have performed through a sampled granite core in Chemlab2 probe at the Aspo hard Rock laboratory. The elution curves of THO were analysed to determine hydraulic properties such as the extent of dispersion effect according to flow rates. The retardation phenomena of the solutes were observed and described with elution curves and migration plumes. After migration test, the rock core was opened, and the remaining radioactivities on the rock fracture surfaces were measured. The transport process was simulated with a two-dimensional channel model. The mass transport process was described with three types of basic processes ; advection, sorption and matrix diffusion. By the combination of these processes, effects of each process on transport were described in terms of elution curves and migration plumes. By comparing the simulation results to the experimental one, it was possible to analyse the retardation effect quantitatively.

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Enrichment of Magnesium Isotopes by Monoazacrown Bonded Merrifield Peptide Resin.

  • Kim, Dong Won
    • Bulletin of the Korean Chemical Society
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    • v.22 no.6
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    • pp.570-574
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    • 2001
  • Magnesium isotope separation was investigated by chemical ion exchange with the 1-aza-12-crown-4 bonded Merrifield peptide resin using an elution chromatographic technique. The capacity of the novel azacrown ion exchanger was 1.0 meq/g dry resin. The heavier isotopes of magnesium were enriched in the resin phase, while the lighter isotopes were enriched in the solution phase. The single stage separation factor was determined according to the method of Glueckauf from the elution curve and isotopic assys. The separation factors of $^{24}Mg^{2+}$-$^{25}Mg^{2+}$, $^{24}Mg^{2+}$-$^{26}Mg^{2+}$, and $^{25}Mg^{2+}$-$^{26}Mg^{2+}$ were 1.008, 1.019, and 1.006, respectively.

Quantitative Analysis of DNA Single-strand Breaks in EL 4 cells and Mouse Spleen Lymphocytes after Irradiation (방사선에 의한 EL 4 백서 백혈병 세포 및 정상 백서 비장 임파구 DNA Single-Strand Breaks의 정량적 분석과 측정)

  • Yoo Seong Yul;Cho Chul Koo;Koh Kyung Hwan;Park Woo Yoon;Park Young Hwan;Kim Sung Ho;Kim Tae Hwan;Chung In Yong
    • Radiation Oncology Journal
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    • v.8 no.2
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    • pp.137-144
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    • 1990
  • The filter elution technique was used to assay Co-60 $\gamma$ ray-induced DNA single-strand breaks(SSB) in EL 4 mouse leukemia cell and mouse spleen lymphocyte. The lymphocytes were stimulated with lipopolysaccharide (LPS, 20 $\mug/ml$) to label [${^3}H$] thymidine. EL 4 cells and lymphocytes in suspension were exposed at $0^{\circ}C$ to 0 Gy, 1 Gy, 5 Gy,10 Gy of Co-60 radiation and elution procedure was performed at PH 12.1. The number of DNA single-strand breaks increased with increasing doses of $\gamma$ rays. The strand scission factor (SSF) was estimated in each experiment (eluted volume 21 ml). The slope for EL 4 cells was $0.01301\pm0.00096\;Gy^{-1}(n=5)$ and the slope for lymphocytes was $0.01097\pm0.00091\;Gy^{-1}(n=5)$. The slopes were significantly different (P<0.005). Thus EL 4 cells were more sensitive to induction of DNA SSB by ionizing radiation than lymphocytes.

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Influences of Roasting Conditions to Herbal Tea Containing Saururus chinensis, Artemisia capillarisin, Zizyphus vulgaris, Angelica gigas, Paeoniae radix and Cnidium officinale on Its Benzo[${\alpha}$]pyrene Changes (로스팅 조건이 삼백초, 인진쑥, 산조인, 당귀, 작약 및 천궁을 첨가한 한방차의 벤조피렌 변화에 미치는 영향)

  • Jang, Jae-Seon;Choi, Jeong-Yun;Oh, Sung-Cheon
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.703-710
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    • 2014
  • The following is the study result of herbal tea roasted at different temperatures between $80{\sim}140^{\circ}C$. Depending on treatment temperature the water content decreased, some carbonization occurred and crude ash content relatively increased. Also crude protein and crude fat decreased little. Solid elution rate of herbal tea showed 0.15~0.32%(w/w) and the rate of solid elution decreased with higher roasting temperature. There was no big change in $80{\sim}110^{\circ}C$ treatment section but the solid elution decreased rapidly in $110{\sim}140^{\circ}C$ section. The reason for decreasing solid elution rate at higher treatment temperature is because the compact inner tissue makes elution difficult. Benzopyrene content (0.29~0.51ppb) showed a tendency to increase with higher treating temperature. From this result, the $B({\alpha})P$ content differed depending on the treatment temperature and raw materials. In case of roasting, the actual inside temperature is around $200^{\circ}C$ but since the surface temperature of the roaster reaches around $2000^{\circ}C$ some portion of $B({\alpha})P$ content was presumed to be produced from the area that came in contact with this surface. When the processing which is a main component of food carbohydrate, protein, fat reason despite serve heat treatment as a whole is to be detected even though the $B({\alpha})P$ in this way is considered to be.

Studies of Egg-Shell Calcium (I) - The Effects of Elution Condition of Egg-Shell Calcium on Elution Quantity and Ionization Rate - (난각칼슘에 관한 연구(I) - 난각칼슘의 용출 조건이 용출량과 이온화율에 미치는 영향 -)

  • 이숙경;박종호
    • Journal of Food Hygiene and Safety
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    • v.17 no.4
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    • pp.183-187
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    • 2002
  • This study was performed to investigate the utility of egg-shell calcium with calcium soak egg-shell in the vinegar. We compared examination eluted quantity with ionization rate in each condition. The results were as follows. 1 The degree of elution and ionization of calcium was proportional to the amount of vinegar and added acetic acid in the vinegar for elution. And ionization rate was the most high in case of 200 ml vinegar volume. 2. fluted quantity were increased in the rank order to 4$0^{\circ}C$ > 3$0^{\circ}C$ > 2$0^{\circ}C$ by temperature but the rank order of ionization of calcium was 3$0^{\circ}C$ > 2$0^{\circ}C$ > 4$0^{\circ}C$ by temperature. The occurrence of unacceptable flavor resulting from the immersion at 4$0^{\circ}C$ was another obstacle to adopt. 3. Eluted quantity and ionization rate of the egg-shell calcium were appeared excellent in case of the brewage vinegar at ventilation condition. The case of brown rice vinegar did not show a considerable difference, but eluted quantity and ionization rate were appeared the most excellent to the other sample. 4. The optimum condition for elution and ionization of the egg-shell calcium was appeared Immersing egg-shells in the brewed rice-bran vinegar at 3$0^{\circ}C$ for three days.

Elution Patterns of Native Sulfate and Breakthough Curve′s of Anions from Bt Soils of Chungwon Series (청원통 Bt 토양에 내재된 황산이온의 용출특성과 음이온의 파쇄특성)

  • Chung Doug-Young;Jin Hyun-O
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.2 no.4
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    • pp.190-197
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    • 2000
  • Anions such as C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, P $O_4$$^{3-}$, and organic anions, that do not become a part of the clay mineral crystal lattice, are of considerable interest in soils which are a potential sink caused by acid rain. In this paper, elution of native sulfate and breakthrough curves (BTC) were obtained from miscible displacement of non-specifically or specifically adsorbed anions through non-saturated or saturated Bt soil of Chungwon series. The shape and position of the BTC's could be affected by adsoprtion and ion exchange onto the soil particle surfaces. Measured BTC's for oxalic acid under unsaturated and saturated conditions showed that less pore volumes were required to displace the native S $O_4$$^{2-}$S from the soil column, and that maximum detection limit of oxalic acid reached earlier than under unsaturated. The retarded BTC's to the righthand side could be attributed by different adsorption behavior of each anion, although BTC's may be influenced by the smaller order of velocity change. The alternate breakthrough and elution curves show the rapid approach to the maximum detection limit of C/Co = 1, compared to progressive tailing of elution curve to reach to C/Co = 0. The probable explanation for asymmetric elution patterns for both anion is that the anion was selectively adsorbed on the positively charged soil surface from the solution passing in the soil column. On the other hand, the variations of pH in effluent showed that pH was increased to 7 in the first 6 pore volume and then gradually decreased to pH 4.

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A Study on the Elution Characteristics of Heavy Metals from the Industrial Sludges by the Variation of pH (pH 변화에 따른 산업종류별 오니류의 중금속 용출특성에 관한 연구)

  • 박종환;정문식
    • Journal of Environmental Health Sciences
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    • v.20 no.2
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    • pp.14-21
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    • 1994
  • This study was carried out to find out the elution characteristics of 4 kinds of sludges and a dust by the variation of pH. Four kinds of sludges were obtained from the Industrial wastes, and the dust, from the iron-and-steel waste. These samples were analyzed by "Official Method for Waste", and the results were summarized as follows. 1. The amounts of heavy metals The concentrations of Cu were 1,940

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Studies on the components of Umbelliferous plants in Korea (VI) Chemical components of the roots of Angelica gigas $N_AKAI$. (한국산산형식물의 성분연구 VI 참당귀근의 Coumarin 및 당성분)

  • 지형준
    • YAKHAK HOEJI
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    • v.13 no.1
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    • pp.47-50
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    • 1969
  • The ether extract of Dang-Gui, the dried root of Angelica gigas N$_{AKAI}$, was placed into a column with aluminium oxide gel. The elution of it with a mixture of n-hexane and ethyl acetate afforded Nodakenetin (I) and the elution with a mixture of n-hexane, ethyl acetate, acetone and methyl alcohol yielded Umbelliferon (II) and Nodakenin (III). Three coumarin derivatives were identified by comparing with authentic samples. The existence of sucrose and glucose was also proved.

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Ligand Exchange Studies with an Iminodiacetic Acid Ion Exchange Resin (Iminodiacetic Acid 이온 교환수지를 사용한 Ligand Exchange 에 대한 연구)

  • CHONG MIN BAK
    • Journal of the Korean Chemical Society
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    • v.11 no.2
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    • pp.56-59
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    • 1967
  • Mixtures of amines can be separated by elution chromatography on a chelating resin, Dowex A-1 loaded with nickel ions based on ligand exchange. Aqueous ammonia is used as the eluent. The method has proved particulary effective for separating aromatic amines.

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