• Title/Summary/Keyword: electron magnetic resonance

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Magnetic dependence of cyclotron resonance in the electron-piezoelectric phonon interacting materials

  • Park, Jung-Il;Sug, Joung-Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.1
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    • pp.16-22
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    • 2020
  • Based on quantum transport theory, we investigated theoretically the magnetic field dependence of the quantum optical transition of quasi 2-dimensional Landau splitting system, in CdS and ZnO Through the analysis of the current work, we found the increasing properties of the cyclotron resonance line-profiles (CRLPs) which show the absorption power and the cyclotron resonance line-widths (CRLWs) with the magnetic field in CdS and ZnO We also found that that CRLWs, γtotal(B) of CdS < γtotal(B) of ZnO in the magnetic field region B < 15 Tesla.

A Study on the Optimal Magnet for ECR (ECR 용 최적 마그네트에 관한 연구)

  • Kim, Y.T.;Kim, Y.J.;Kim, K.S.;Lee, Y.J.;Son, M.H.
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.649-652
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    • 1992
  • ECR(Electron Cyclotron Resonance) occure at ${\omega}_c$=${\omega}$, ${\omega}_c$:electron cycltron frequency, ${\omega}$:electromagnetic wave frequency. ECR system have several merit, 1) power transefer efficiency 2) low neutral gas pressure (below 1 mTorr) 3) high plasma density($10^{12}$ $cm^{-3}$). It is applicated variously in the field of semiconductor and new materials as the manufacturing equipment. Magnetic field in ECR system contruct resonance layer (${\omega}$=2.45GHz, $B_z$=875 Gauss) and control plasma. Plasma is almost generated at resonance layer. If the distance between substrate and resonance layer is short, uniformity of plasma is related with profile of resonance layer. Plasma have the property "Cold in Field", so directonality of magnetic field is one of the control factors of anisotropic etching. In this study, we calculate B field and flux line distribution, optimize geometry and submagnet current and improve of magnetic field directionality (99.9%) near substrate. For the purpose of calculation, vector potential A(r,z) and magnetic field B(r,z), green function and numerical integration is used. Object function for submagnet optimization is magnetic field directionality on the substrate and Powell method is used as optimization skim.

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Cyclotron Resonance of the Wannier-Landau Transition System Based on the Ensemble Projection Technique

  • Jung-Il Park
    • Journal of the Korean Magnetic Resonance Society
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    • v.27 no.4
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    • pp.28-34
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    • 2023
  • We study the linear-nonlinear quantum transport theory of Wannier-Landau transition system in the confinement of electrons by a square well confinement potential. We use the projected Liouville equation method with the ensemble density projection technique. We select the dynamic value under a linearly oscillatory external field. We derive the dynamic value formula and the memory factor functions in three electron phonon coupling systems and electron impurity coupling systems of two transition types, the intra-band transitions and inter-band transitions. We obtain results that can be applied directly to numerical analyses. For simple example of application, we analyze the absorption power and line-widths of ZnO, through the numerical calculation of the theoretical result in the Landau system.

Magnetic Property of BixCa1-xMnO3: Experimental and First Principles Calculation Study

  • Na, Sung-Ho;Kim, Dong-Jin
    • Journal of Magnetics
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    • v.14 no.1
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    • pp.1-6
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    • 2009
  • The magnetic properties of ${Bi_x}{Ca_{1-x}}{MnO_3}$ for x = 0.12, 0.13, 0.14, 0.15, and 0.16 were examined by measuring magnetic susceptibility, resistivity and electron magnetic resonance at different temperatures. ${Bi_x}{Ca_{1-x}}{MnO_3}$ showed complicated magnetic structure that varies with temperature and composition, particularly around Bi composition x. 0.15. The aim of this study was to determine how the magnetic and physical properties of ${Bi_x}{Ca_{1-x}}{MnO_3}$ change in this region. In addition, first principles calculations of the magnetic phase of ${Bi_x}{Ca_{1-x}}{MnO_3}$ for x = 0, 0.125, 0.25 were carried out, and the spin state, electric and magnetic characteristics are discussed.

On Inversion Rations for Push-Pull Paramagnetic Masers (상자성 풋쉬플메이서의 반전화)

  • Cho, Cheol
    • 전기의세계
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    • v.21 no.3
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    • pp.53-56
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    • 1972
  • Electron paramagnetic resonance is one of the concrete forms of magnetic resonance and the superposition of an external magnetic field causes an orientation of the magnetic moment of an atom. On the assumption that both pumped levels be saturated and all relaxation times equal the inversion ratio for a push-pull paramagnetic maser is obtained and compared with those of three-level paramagnetic masers and the magnetic field intensities for 9 and 10 Gc push-pull ruby maser oriented with an angle of 54.deg.44' between the caxis and the magnetic field are, also, obtained.

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ESR detection of optically-induced hyperpolarization of nitrogen vacancy centers in diamond

  • An, Min-Gi;Shim, Jeong Hyun;Kim, Kiwoong;Oh, Sangwon;Jeong, Keunhong
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.1
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    • pp.9-15
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    • 2020
  • Nitrogen vacancy center (NV center) in diamond has recently been appeared as a promising candidate for hyperpolarization applications due to its optical pumping property by laser. Optically Detected Magnetic Resonance (ODMR) has been used as a conventional method to obtain the resonance spectrum of NV centers. ODMR, however, has a shortcoming of sensitivity and a limitation of subjects, such that the degree of hyperpolarization can hardly be estimated, and that the spins other than NV centers are invisible. In contrast, Electron Spin Resonance (ESR) spectroscopy is known to proportionally reflect the degree of spin polarization. In this work, we successfully observed the optically-induced hyperpolarization of NV spins in diamond through CW-ESR spectroscopy with an X-band system. All the NV peaks were identified by calculating the eigenvalues of NV spin Hamiltonian. The intensities of NV peaks were enhanced over 240 times after optical pumping. The enhanced peaks corresponding to the transition from |ms=0> to |ms=-1> revealed inverted phases, while other peaks remained in-phase. The optically-induced hyperpolarization on NV spins can be a useful polarization source, leading to 13C nuclear hyperpolarization in diamond.

Constructing Overhauser Dynamic Nuclear Polarization-Nuclear Magnetic Resonance System Using Benchtop Electron Paramagnetic Resonance Spectrometer

  • Saun, Seung-Bo;Kim, JiWon;Han, Oc Hee
    • Journal of the Korean Magnetic Resonance Society
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    • v.22 no.2
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    • pp.34-39
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    • 2018
  • The Nuclear Magnetic Resonance (NMR) technique using Dynamic Nuclear Polarization (DNP) procedures is one of the promising techniques that enable overcoming low sensitivity problems in NMR spectroscopy. We constructed an ODNP-NMR system using a commercial benchtop EPR spectrometer. The $^1H$ NMR peak area of water in aqueous solutions of 4-hydroxy-TEMPO was enhanced more than 95 times in the ODNP-NMR experiments. Our signal enhancement results were about 55% of the previously reported result. This could be due to non-uniform microwave power over a sample and unwanted sample heating by microwave. However, this portable ODNP-NMR spectrometer will be eventually useful for site-specific detection with nano-scale spatial resolutions and molecular dynamics studies with significantly improved signal sensitivity.

Pulsed Electron Paramagnetic Resonance Application on the Photoinduced Charge Separation of Alkylphenothiazine Derivatives in Molecular Assemblies

  • Kang, Young-Soo;Park, Chan-Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.4 no.2
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    • pp.82-90
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    • 2000
  • Photoinduced charge separation of alkylphenothiazines in molecular assemblies such as positively, negatively and neutrally charged micelle interface results in the paramagnetic phenothiazine cation radical. This was studied as a model system for the light energy conversion into chemical energy. The photoproduced phenothaizne cation radical was identified and its amount was quantized with electron spin resonance (ESR). The microenvironment of photoproduced cation radical was studied with pulsed-ESR. Such a charge separation is enhanced by the optimization of various structural factors of the molecular assemblies. The structural factors of molecular assemblies have focused on the interface charge, interface structure with different headgroups and interfacial perturbation by disolving interface active organic additives.

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