• Title/Summary/Keyword: electrolytic reduction

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Corrosion Behavior of $Y_2O_3$ Coating in an Electrolytic Reduction Process (전해환원공정에서 $Y_2O_2$ 코팅층의 부식거동)

  • Cho, Soo-Haeng;Hong, Sun-Seok;Kang, Dae-Seung;Jeong, Myeong-Soo;Park, Byung-Heong;Hur, Jin-Mok;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.33-39
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    • 2010
  • The electrolytic reduction of a spent oxide fuel involves a liberation of the oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. Accordingly, it is essential to choose the optimum material for the processing equipment that handles the high molten salt. In this study, hot corrosion studies were performed on bare as well as coated superalloy specimens after exposure to lithium molten salt at $675^{\circ}C$ for 216 h under an oxidizing atmosphere. The IN713LC superalloy specimens were sprayed with an aluminized NiCrAlY bond coat and then with an $Y_2O_3$ top coat. The bare superalloy reveals an obvious weight loss due to spalling of the scale by the rapid scale growth and thermal stress. The chemical and thermal stability of the top coat has been found to be beneficial for increasing to the corrosion resistance of the structural materials for handling high temperature lithium molten salts.

Reduction of DC-link Capacitance for Single-Phase Transformerless Photovoltaic Power Converters (절연형 단상 태양광 PCS의 직류링크 커패시터 저감)

  • Nguyen, Hoang Vu;Lee, Dong-Choon
    • Proceedings of the KIPE Conference
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    • 2016.07a
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    • pp.365-366
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    • 2016
  • This paper presents a single-phase transformerless photovoltaic (PV) power converter systems based on the AC/DC boost inverter, which is capable of solving the leakage current and second-order ripple power issues. By eliminating the inherent ripple power in single-phase inverter, the bulky electrolytic capacitor can be replaced by a small film capacitor. The validity of the proposed scheme has been verified by the simulation results.

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A Study of Metal Technology in Ancient Silla Dynasity (고대신라의 금속기술 연구)

  • 강성군;조종수
    • Journal of the Korean institute of surface engineering
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    • v.8 no.1
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    • pp.1-9
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    • 1975
  • The crorosion film of gilt bronz, silver and iron objects, which were excaved from Ancient Tomb of Silla Dynasty, was removed by the electrolytic reduction process. These metallic objects were mainly investigated for microstructure, designs and gilting film etc. Most iron objects might be made by hot forging process. The cold extrusion technique might be used for gold and silver objects, in addition to an amalgam method might be applied for the gilting Au film on Cu-alloy surface. For the gilting on glass surface, first, a Cu alloy was cladded on glass , next, Au-film was obtained on the Cu-ally by the amagum method.

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Continuous Nitrate Removal using Bipolar ZVI Packed Bed Electrolytic Cell (영가철(Fe0) 충진 복극전해조를 이용한 질산성질소의 연속식 제거 연구)

  • Jeong, Joo-Young;Kim, Han-Ki;Shin, Ja-Won;Park, Joo-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1B
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    • pp.79-84
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    • 2012
  • Nitrate is a common contaminant in groundwater aquifer. The present study investigates the performance of the bipolar zero valent iron (ZVI, $Fe^0$) packed bed electrolytic cell in removing nitrate in different operating conditions. The packing mixture consists of ZVI as electronically conducting material and silica sand as non-conducting material between main cathode and anode electrodes. In the continuous experiments for the simulated wastewater (contaminated groundwater, initial nitrate about 30 mg/L as N and electrical conductivity about 300 ${\mu}S/cm$), over 99% removal of nitrate was achieved in the applied voltage 600 V and at the flow rate of 20 mL/min. The optimum packing ratio (v/v) and flow rate were determined to be 1:1~2:1 (silica sand to ZVI), 30 mL/ min respectively. Effluent pH was proportional to nitrate influx concentration, and ammonia which is the final product of nitrate reduction was about 60% of nitrate influx. Magnetite was observed on the surface of the used ZVI as major oxidation product.

Verification on Cold-Tolerance of Some Fruit Trees as Species for Urban Greening Plants

  • Lee, Jin-Hee;Oh, Hee-Young;Kwon, O-Man
    • Journal of Environmental Science International
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    • v.26 no.10
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    • pp.1155-1166
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    • 2017
  • This study selected commonly known species of fruit trees, and re-selected the species that endure the stress of extreme cold weather and physiologically restore themselves to the previous state until the following year. Then we could go ahead to propose the species that were appropriate as urban greening plants in weather condition of any part of the country. To do this, we conducted an experiments for six species of fruit trees based on the preference of the general public and recommendation of the experts; Morus alba (English name: mulberries), Diospyros kaki (English name: Persimmon), Prunus persia (English name: Peach), Elaeagnus umbellata var. coreana (English name: Korean Autumn Olive), Malus domestica 'Alps Otome' (English name: Alps Otome), and Prunus mume (English name: Blue Plum). The experiment verifies whether the trees survive without any stress from the cold weather under the national climate conditions (one in the suburbs of Seoul: Yongin city, one in the central Chungcheong region: Daejeon city, and in the southern Gyeongsang region: Jinju city in Korea). The experiment lasted for a year from August 2016 to August 2017. The levels of electrolytic efflux, chlorophyll content, plant height, fresh weight, and dry weight were measured four times (on August of 2016, January, February, and August of 2017) for each tree planted bare ground outdoors. Results showed that Diospyros kaki, Prunus persia, and Malus domestica 'Alps Otome' were proven durable and resistant to winters of all three areas (one in the suburbs of Seoul: Yongin city, one in the central Chungcheong region: Daejeon city, and in the southern Gyeongsang region: Jinju city in Korea). Especially, the increase of chlorophyll content and the reduction of electrolytic efflux were noticeable in Prunus persia than in the other two species, proving itself as the most cold-tolerant among the six species used in the experiment. In addition, interpreting from the physiological restoration data of one-year span before and after getting through winterer, Prunus persia was proven to be the most cold-tolerant species.

Recovery of Silver from Artificial Photographic Wastewater by Continuous Flow Electrolytic Process (순환공정법(循環工程法)을 적용(適用)한 인공(人工) 사진폐액(寫眞廢液)으로부터의 전해채취(電解採取)에 의한 은(銀)의 회수(回收))

  • Chung, Won-Ju;Kim, Dong-Su
    • Resources Recycling
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    • v.16 no.1 s.75
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    • pp.68-72
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    • 2007
  • The influences of reduction time, potential difference and ionic concentration flow rate have been investigated on the electrolytic recovery of silver from artificial photographic wastewater in continuous flow reactor system. As the initial concentration of silver ion and applied potential were increased, the amount of silver recovered was observed to be raised. Also, the electrolytically recovered material from artificial wastewater was proved to be pure silver based on the qualitative analyses by EPMA and XRD.

Electrochemical oxidation-reduction and determination of urea at enzyme free PPY-GO electrode

  • Mudila, Harish;Prasher, Parteek;Rana, Sweta;Khati, Beena;Zaidi, M.G.H.
    • Carbon letters
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    • v.26
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    • pp.88-94
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    • 2018
  • This manuscript explains the effective determination of urea by redox cyclic voltammetric analysis, for which a modified polypyrrole-graphene oxide (PPY-GO, GO 20% w/w of PPY) nanocomposite electrode was developed. Cyclic voltammetry measurements revealed an effective electron transfer in 0.1 M KOH electrolytic solution in the potential window range of 0 to 0.6 V. This PPY-GO modified electrode exhibited a moderate electrocatalytic effect towards urea oxidation, thereby allowing its determination in an electrolytic solution. The linear dependence of the current vs. urea concentration was reached using square-wave voltammetry in the concentration range of urea between 0.5 to $3.0{\mu}M$ with a relatively low limit of detection of $0.27{\mu}M$. The scanning electron microscopy was used to characterize the morphologies and properties of the nanocomposite layer, along with Fourier transform infrared spectroscopy. The results indicated that the nanocomposite film modified electrode exhibited a synergistic effect, including high conductivity, a fast electron-transfer rate, and an inherent catalytic ability.