• Title/Summary/Keyword: electrolytic reduction

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Analysis on the heat-resisting method of the electrolytic metal reduction reactor in the test facility for the spent fuel waste (사용후핵연료 시험시설에서 전기 금속 전환반응기의 내열 방안 분석)

  • 김영환;윤지섭;정재후;홍동희;박기용;진재현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.776-779
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    • 2003
  • To reduce the storage space of spent fuel used at the atomic power plants in the over the world, the uranium elements contained in the spent fuel is being extracted and effectively stored. For this, the spent fuel are oxidized and deoxidized. In this study, it is produced the heat-resisting methods about the spent fuel management technology research and test facility for the spent fuel waste for spent fuel minimized. The first considered processes in the facility are the electrolytic metal reduction reactor process. Since the electrolytic metal reduction reactor is operated at the high temperature range, we have to consider the heat-resisting methods for the devices. For the heat-resisting methods, we have searched and analyzed technical reference for the heat-resisting methods. We have calculated thermal stress and strain of each devices by the commercial analysis software, ANSYS. D.S. It is experimented for inspecting confidence rate of analysis results. By using the results, we have analyzed the problems of parts and determined the heat-resisting material, commercial parts, and the size of parts and O-ring. Based on these results, it is produced the heat-resisting methods of magnesia filter, cathode, and reactor for the electrolytic metal reduction reactor.

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Study of the Elimination of the Electrolytic Capacitors and Reduction of the Ripple Current on the Output Node in the One-Stage PFC Flyback Converter for the LED Lighting (LED 조명용 One-Stage PFC Flyback 컨버터에서의 출력단 리플 저감과 전해 커패시터의 제거에 관한 연구)

  • Jeon, Yong-Sung;Jin, Dal-Lae;La, Jae-Du;Kim, Young-Seok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.11
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    • pp.1625-1633
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    • 2012
  • In the lighting industry, a Lighting Emitting Diode (LED) is increasingly used because of many advantages and a eco-friendly product comparing with the conventional lighting. However, the LED lighting has to include various AC/DC converters because the direct current is used for the LED lighting. Among a lot of power converters, the flyback converter is widely used for the LED lighting and includes some electrolytic capacitors for the voltage regulation. But the electrolytic capacitor has shorter lifetime than the LED element. It makes the expected life-time of the converter having the electrolytic capacitor shorter than the LED element. This paper proposes the single-stage PFC flyback converter without electrolytic capacitors. To verify the performance of the proposed converter, simulated and experimental works were carried out.

Effect of Compounding Electrolytic Machining in Ball End Milling (볼엔드밀 절삭가공에서 전해복합의 효과)

  • 주종길;박규열
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.1025-1028
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    • 2001
  • In this report, a new method compounding the electrolytic machining with ball end milling process to increase the machining efficiency was introduced. From the experimental result, it was confirmed that effect of cutting force reduction and finer surface roughness can be obtained in a certain condition of ball end milling and electrolytic machining conditions.

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Study of the Electrolytic Reduction of Uranium Oxide in LiCl-Li$_{2}$O Molten Salts with an Integrated Cathode Assembly

  • Park Sung-Bin;Seo Chung-seok;Kang Dae-Seung;Kwon Seon-Gil;Park Seong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.2
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    • pp.105-112
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    • 2005
  • The electrolytic reduction of uranium oxide in a LiCl-Li$_{2}$O molten salt system has been studied in a 10 g U$_{3}$O$_{8}$ /batch-scale experimental apparatus with an integrated cathode assembly at 650$^{\circ}C$. The integrated cathode assembly consists of an electric conductor, the uranium oxide to be reduced and the membrane for loading the uranium oxide. From the cyclic voltammograms for the LiCl-3 wt$\%$ Li$_{2}$O system and the U$_{3}$O$_{8}$-LiCl-3 wt$\%$ Li$_{2}$O system according to the materials of the membrane in the cathode assembly, the mechanisms of the predominant reduction reactions in the electrolytic reactor cell were to be understood; direct and indirect electrolytic reduction of uranium oxide. Direct and indirect electrolytic reductions have been performed with the integrated cathode assembly. Using the 325-mesh stainless steel screen the uranium oxide failed to be reduced to uranium metal by a direct and indirect electrolytic reduction because of a low current efficiency and with the porous magnesia membrane the uranium oxide was reduced successfully to uranium metal by an indirect electrolytic reduction because of a high current efficiency.

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Dyeability and Antibacterial Activity of the Fabrics with Elm-Bark Extracts (느릅나무 껍질 추출액에 의한 섬유의 염색성 및 항균성)

  • 최영희;권오경;문제기
    • Textile Coloration and Finishing
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    • v.15 no.3
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    • pp.140-145
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    • 2003
  • The purpose of this study is searching the Elm-Bark dyes' dyeability and antibacterial activities according to the dyeing time, pH, a mordant and the method of mordancy. We used two kinds of Elm-Bark dyes which's extracted by the Electrolytic reduction water and Distilled water. Silk fabric and Cotton/nylon union fabric was used for this study. The results are as follow. K/S value is increased according to the dyeing time and the suitable pH level is pH 3. Dyeability is good with Iron(II) sulfate$(FeSO_4\cdot{7H}_2O)$ on the pre-mordancy and Potassium dichromate$(K_2Cr_2O_7)$ on the post-mordancy. The Elm-Bark dyes by the Electrolytic reduction water has good colorfastness more than by the Distilled water. Antibacterial activities is excellent and the ratio is over than 99.5%.

Electrolytic Reduction Characteristics of Titanium Oxides in a LiCl-Li2O Molten Salt (LiCl-Li2O 용융염에서 타이타늄 산화물의 전해환원 특성)

  • Lee, Jeong;Kim, Sung-Wook;Lee, Sang-Kwon;Hur, Jin-Mok;Choi, Eun-Young
    • Journal of the Korean Electrochemical Society
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    • v.18 no.4
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    • pp.156-160
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    • 2015
  • Experiments using a metal oxide of a non-nuclear material as a fuel are very useful to develop a new electrolytic reducer for pyroprocessing. In this study, the titanium oxides (TiO and $TiO_2$) were selected and investigated as the non-nuclear fuel for the electrolytic reduction. The immersion tests of TiO and $TiO_2$ in a molten 1.0 wt.% $Li_2O$-LiCl salt revealed that they have solubility of 156 and 2100 ppm, respectively. Then, the Ti metals were successfully produced after the separate electrolytic reduction of TiO and $TiO_2$ in a molten 1.0 wt.% $Li_2O$-LiCl salt. However, Ti was detected on the platinum anode used for the electrolytic reduction of $TiO_2$ unlike TiO due to the dissolution of $TiO_2$ into the salt.

Characteristics of Strong Alkaline Electrolyzed Water Produced in All-in-one Electrolytic Cell (일체형 전해조에서 생산된 강알카리성 전해수의 특성)

  • Lee, Ho Il;Rhee, Young Woo;Kang, Kyung Seok
    • Clean Technology
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    • v.18 no.4
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    • pp.446-450
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    • 2012
  • Strong alkaline electrolyzed water which is produced in cathode by electrolyzing the solution where electrolytes (NaCl, $K_2CO_3$ etc.) are added in diaphragm electrolytic cell, is eco-friendly and has cleaning effects. So, it is viewed as a substitution of chemical cleaner. In addition, strong alkaline electrolyzed water is being used by some Japanese automobile and precision parts manufacturing industries. When strong alkaline electrolyzed water is produced by using diaphragm electrolytic cell, it is necessarily produced at the anode side. Since strong acidic electrolyzed water produced is discarded when its utilization cannot be found, production efficiency of electrolyzed water is consequently decreased. Also, there is a weakness electrolytic efficiency is decreasing due to the pollution of diaphragm. In order to overcome this, non-diaphragm all-in-one electrolytic cell integrated with electrode reaction chamber and dilution chamber was applied. Strong alkaline electrolyzed water was produced for different composition of electrolytes, and their properties and characteristics were identified. In comparing the properties between strong alkaline electrolyzed water produced in diaphragm electrolytic cell and that produced in all-in-one electrolytic cell, the differences in ORP and chlorine concentration were found. In emulsification test to confirm surface-active capability, similar results were obtained and strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell was identified to be useable as a cleaner like strong alkaline electrolyzed water produced in diaphragm electrolytic cell. Strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell is thought to have sterilizing power because it has active chlorine which is different from strong alkaline electrolyzed water produced in diaphragm electrolytic cell.

Synthesis of Cyclitol Derivatives (IV) Electrolytic Reduction of DL-epi-inosose-2 (Cyclitol 유도체 합성에 관한 연구 (제4보) DL-epi-inosose-2의 전해환원)

  • Sohn, Joo-Hwan;Nam, Chong-Woo;Park, Heung-Cho
    • Journal of the Korean Chemical Society
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    • v.16 no.2
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    • pp.93-99
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    • 1972
  • To obtain the various kinds of inositol stereomers, we have selected the process of electrolytic reduction of DL-epi-inosose-2 using Ni, Ta, Cu, Mo, Pb, Sn, W, Cd and Hg etc., as cathode. We think that this process gives greater variety than chemical processes. DL-epi-inosose-2 was synthesized by chemical oxidation of myo-inositol, dissolved in aqueous solution of potassium hydroxide, and used as electrolytic solution. To prevent anodic oxidation of cathode products the H-type diaphragm cell was used. As the results of paper chromatography of cathodic products, we obtained the $R_f$ values of myo-inositol and epi-inositol were in good agreement with literature values.

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TiN Anode for Electrolytic Reduction of UO2 in Pyroprocessing (TiN 양극을 이용한 파이로프로세싱 UO2 전해환원)

  • Kim, Sung-Wook;Choi, Eun-Young;Park, Wooshin;Im, Hun Suk;Hur, Jin-Mok
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.3
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    • pp.229-233
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    • 2015
  • Developing novel anode materials to replace the Pt anode currently used in electrolytic reduction is an important issue on pyroprocessing. In this study, the electrochemical behavior of TiN was investigated as the conductive ceramic anode which evolves O2 gas during the reaction. The feasibility and stability of the TiN anode was examined during the electrolytic reduction of UO2. The TiN anode could electrochemically convert UO2 to metallic U in a LiCl–Li2O molten salt electrolyte. No oxidation of TiN was observed during the reaction; however, the formation of voids in the bulk section appeared to limit the lifetime of the TiN anode.

Odor Emission from Sediments in Sewer Systems and Odor Removal using an Electrolytic Oxidation Process (하수관거에 퇴적된 유기물에 의한 악취 발생과 산화전리시스템을 이용한 악취 저감)

  • Ahn, Hae-Young;Shin, Seung-Kyu;Song, Ji-Hyeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.703-710
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    • 2011
  • Odor emission from domestic sewer systems has become a serious environmental problem. An investigation on a sewer manhole revealed that anaerobic decay of sediment organic matters (SOMs) and related declines of oxidation reduction potential (ORP) in the sediment layer were the main reason of the production of volatile sulfur compounds. In addition, as the anaerobic decaying period continued, the odor intensity rapidly increased with increasing concentrations of $H_2S$ and dimethyl sulfide. As a feasible method to control SOMs and to minimize odor emission potentials, an electrolytic oxidation process has been employed to the sediment sludge phase. In this study, voltages applied to the electrolytic oxidation process were varied as a main system parameter, and its effects on odor removal efficiencies and reaction characteristics were investigated. At the applied voltages greater than 20 V, the system efficiently oxidized the organic matter, and the ORP in the sludge phase increased rapidly. As a consequence, the removal efficiency of hydrogen sulfide was found to be >99% within 60 minutes of the electrolytic oxidation. Overall, the electrolytic oxidation process can be an alternative to control odor emission from sewer systems, and a threshold input energy needs to be determined to achieve effective operation of the process.