• 제목/요약/키워드: electrodeposited

검색결과 340건 처리시간 0.022초

무전해 Ni 복합도금 과정에서 분말의 공석기구에 대한 연구(II) (A Study on the Mechanism for the Formation of Partices in electroless Ni Composite Coating(II))

  • 이원해;이승평
    • 한국표면공학회지
    • /
    • 제22권2호
    • /
    • pp.78-87
    • /
    • 1989
  • Mechanism of formation of electroless composite coatings is similar to that of electrodeposited composite coating, but the amount of particles entraped in electroless coating is higher that the one of electrodeposited coatings. The methol of entrapment by the metal for SiC and Al2O3 particles is different from that for WC particles. In the former case the particles are gracually engulfed by the depositing metal, wheran with WC a metal envelope is rapidly fomed around each particles. This difference can be attributed to the difference in electrical resistivity of the particles. Inclusion density of SiC and Al2O3 particles during copeposition depend on the particle size, agitation condition, vabration conditions and electrolyte temperatures.

  • PDF

A Self-standing and Binder-free Electrodes Fabricated from Carbon Nanotubes and an Electrodeposited Current Collector Applied in Lithium-ion Batteries

  • Luais, Erwann;Mery, Adrien;Abou-Rjeily, John;Sakai, Joe;Tran-Van, Francois;Ghamouss, Fouad
    • Journal of Electrochemical Science and Technology
    • /
    • 제10권4호
    • /
    • pp.373-380
    • /
    • 2019
  • In this paper, we report the preparation of a flexible, self-standing and binder-free carbon nanotubes (CNTs) electrode with an electro-generated current collector. The copper current collector layer was electrodeposited on the backside of CNTs self-standing film obtained by a simple filtration process. The obtained CNTs-Cu assembly was used as a negative electrode in Li-ion batteries exhibiting good performance along with proving its applicability in flexible batteries.

정펄스 및 역펄스 방법을 이용하여 구리 전해도금 시 전착층의 표면 형상과 고유저항에 미치는 효과 (Effect of Pulse and Pulse-Reverse Current on Surface Morphology and Resistivity of Electrodeposited Copper)

  • 우태균;박일송;설경원
    • 한국재료학회지
    • /
    • 제17권1호
    • /
    • pp.56-59
    • /
    • 2007
  • Recently, requirement for the ultra thin copper foil increases with smaller and miniaturized electronic components. In this study, we evaluated the surface morphology, crystal phase ana surface roughness of the copper film electrodeposited by pulse method without using additives. Homogeneous and dense copper crystals were formed on the titanium substrate, and the optimum condition was 25% duty cycle. Moreover, the surface roughness(Ra), $0.295{\mu}m$, is the smallest value in this condition. It is thought that this copper foil is good for electromigration inhibition due to the preferential crystal growth of Cu (111)

Interfacial Properties of Electrodeposited Carbon Fiber/Epoxy Composites using Electro-Micromechanical Techniques and Nondestructive Evaluations

  • Park, Joung-Man;Lee, Sang-Il
    • Macromolecular Research
    • /
    • 제9권1호
    • /
    • pp.20-29
    • /
    • 2001
  • Interfacial adhesion and nondestructive behavior of electrodeposited (ED) carbon fiber rein-forced composites were evaluated using electro-micromechanical techniques and acoustic emission (AE). The interfacial shear strength (IFSS) of the ED carbon fiber/epoxy composites was higher than that of the untreated fiber. This might be expected because of the possibility of chemical or hydrogen bonding in an electrically adsorbed polymeric interlayer. The logarithmic electrical resistivity of the untreated single-carbon fiber composite increased suddenly to infinity when fiber fracture occurred, whereas that of the ED composite increased relatively gradually to infinity. This behavior may arise from the retarded fracture time due to enhanced IFSS. In single- and ten-carbon fiber composites, the number of AE signals coming from interlayer failure of the ED carbon fiber composite was much larger than that of the untreated composite. As the number of the each first fiber fractures increased in the ten-carbon fiber composite, the electrical resistivity increased stepwise, and the slope of the logarithmic electrical resistance increased.

  • PDF

Electrocatalysis of Oxygen Reduction by Au Nanoparticles Electrodeposited on Polyoxometalate-Modified Electrode Surfaces

  • Choi, Kyung-Min;Choi, Su-Hee;Kim, Jong-Won
    • 전기화학회지
    • /
    • 제12권1호
    • /
    • pp.75-80
    • /
    • 2009
  • The effect of polyoxometalate monolayers on the electrodeposition of Au nanoparticles (AuNPs) on glassy carbon (GC) surfaces was examined by electrochemical and scanning electron microscope techniques. The presence of $SiMo_{12}O^{4-}_{40}$-layers resulted in average particle sizes of ca. 60 nm, which is larger than AuNPs deposited on bare GC surfaces. AuNPs electrodeposited on $SiMo_{12}O^{4-}_{40}$-modified GC surfaces for 20 s exhibited the best electrocatalytic activity for oxygen reduction. This system exhibited similar or slightly better efficiency for oxygen reduction than a bare Au electrode. Rotating disk electrode experiments were also performed and revealed that the catalytic reduction of oxygen on AuNPs deposited on $SiMo_{12}O^{4-}_{40}$-modified GC electrodes is a two-electron process.

Cure Monitoring and Nondestructive Evaluation of Carbon Fiber/Epoxy Composites by the Measurements of Electrical Resistance and AE

  • Lee Sang-Il;Yoon Dong-Jin;Park Joung-Man
    • 한국복합재료학회:학술대회논문집
    • /
    • 한국복합재료학회 2004년도 추계학술발표대회 논문집
    • /
    • pp.264-267
    • /
    • 2004
  • Cure monitoring and nondestructive characteristics of carbon fiber/epoxy composites were evaluated by the measurements of electrical resistance and acoustic emission (AE). Logarithmic electrical resistivity of the untreated single-carbon fiber composite increased suddenly to infinity when the fiber fracture occurred, whereas that of the electrodeposited composite increased relatively broadly up to infinity. As curing temperature increased. logarithmic electrical resistivity of steel fiber increased. On the other hand, electrical resistance of carbon fiber decreased due to the intrinsic electrical properties based on the band theory. The apparent modulus of the electrodeposited composite was higher than that of the untreated composite due to the improved interfacial shear strength (IFSS).

  • PDF

Formation of biaxial-texture of Ni substrates for deposition of YBCO superconductor by electrodeposition

  • 이규환;유재무;정형식
    • 한국초전도학회:학술대회논문집
    • /
    • 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
    • /
    • pp.289-292
    • /
    • 2000
  • In order to evade the patent of Oak Ridge National Laboratory (RABiTS process) and search for more economical process, a new process for producing the biaxially textured Ni tape by electrodeposition has been investigated. Electrodeposition was performed in the modified Watts bath. The crystal orientations of electrodeposited Ni were analysed by X-ray pole figure, ${\phi}$-scan and ${\omega}$-scan. The electrodeposited Ni tape showed cube texture with good out-of plane(< 8${\circ}$) and in-plane alignment(< 20${\circ}$).

  • PDF

Current Density and Thickness Effects on Magnetic Properties of Electrodeposited CoPt Magnetic Films

  • Kim, Hyeon Soo;Jeong, Soon Young;Suh, Su Jeong
    • Journal of Magnetics
    • /
    • 제18권4호
    • /
    • pp.417-421
    • /
    • 2013
  • The dominant magnetization reversal behavior of electrodeposited CoPt samples with various thicknesses deposited at different current densities was the domain wall motion by means of wall pinning. The magnetic interaction mechanism was dipolar interaction for all samples. The dipolar interaction strength was significantly affected by the sample thickness rather than by the current density, while the magnetic properties were closely related to the current density.

강재의 마그네타이트 피복에 관한 연구 (Magnetite film on iron)

  • 김헌규;강탁
    • 한국표면공학회지
    • /
    • 제25권2호
    • /
    • pp.66-72
    • /
    • 1992
  • Magnetite film on iron surface could be coated in strongly alkaline solution (12M NaH\OH) which contained additives such as NaHCO3, KCl and NaNO2, Iron plate was immersed in boiling solution ($130^{\circ}C$) contained above mentioned additives for 1 hour. There are some microcracks and these cracks proved to be the sites for the initiation of corrosion when immersed in 3% NaCl solution. To improve corrosion resistance of the coated steel plate, chromating was done as a post treatment. Chromate film was formed on magnetite oxide film potentiostatically at-918mV/SCE for five minutes at temperature of $70^{\circ}C$ in the alkaline solution containing 5g/l Na2Cr2O7.2H2O.Cr3O4 was electrodeposited on magnetite oxide film and Cr2O3 was electrodeposited on iron surface which was assumed as surface revealed due to microcracks. Increased corrosion resistance of chromated magnetite oxide film was proved in salt spray test & immersion test.

  • PDF