• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1998년도 하계학술대회 논문집 D
• /
• pp.1346-1348
• /
• 1998

Tungsten oxide($WO_3$) thin films were prepared by reactive magnetron sputtering in an $Ar/O_2$ atmosphere from a compressed powder $WO_3$ target and their electrochromic(EC) phenomena were investigated. PEO-$LiClO_4$-PC polymer electrolyte can easely be formed into thin films and showed high transmittance. Such electrolyte have electrochromic properties suitable for large-scale electrochromic devices. For the devices using $WO_3$ thin films of 1500, 2500, $4000{\AA}$ thickness with glass/ITO/$WO_3$/PEO-$LiClO_4$-PC/ITO/glass structure, an optical modulation of $50{\sim}60%$ were obtained at a potential range of $1{\sim}2V$. It has shown that transmittance and reflectance of light could be electrically controlled by low applied voltage.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.365.1-365.1
• /
• 2014

Cobalt oxide has excellent various properties such as high catalytic activity, antiferromagnetism, and electrochromism. So cobalt oxides offer a great potential for their applications in the various areas such as optical gas sensor, catalysts for oxidation reaction, electrochromic devices, high temperature solar selective absorbers, magnetic materials, pigment for glasses and ceramics, and negative electrodes for lithium-ion batteries. We have synthesized novel cobalt complexes by simple reaction of cobalt bistrimethylsilylamide as a starting material with a lot of conventional ligands as potential cobalt oxide precursors. The studies include the facile preparation, structural characterization, and spectroscopic analysis of the new precursors. We are making efforts to grow cobalt oxide thin films using cobalt complexes newly synthesized in this study using deposition techniques.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1994년도 하계학술대회 논문집 C
• /
• pp.1308-1310
• /
• 1994

The electrochromism of $WO_3$ and $V_2O_5$ thin films have been studied. The $WO_3$ thin film is found to be cathodic coloration material and the coloration efficiency of this film is close to $60 [cm^2/C]$ in the near infrared region. The $V_2O_5$ thin film exhibits cathodic coloration in tile near infrared and anodic coloration in the blue and near UV region. The cathodic coloration in the $450{\sim}1100 nm$ wavelength range is relatively weak with a maximum coloration efficiency of $6 [cm^2/C]$).

• 한국인쇄학회:학술대회논문집
• /
• 한국인쇄학회 1995년도 학술발표회 논문초록집
• /
• pp.23-25
• /
• 1995

• 공업화학전망
• /
• 제23권2호
• /
• pp.12-22
• /
• 2020

전기변색 물질은 전압을 인가하였을 때 산화-환원 반응을 통해 흡수도나 투과도 같은 광학적 물성 변화를 보인다. 이러한 전기변색 물질에 기반한 전기변색 소자는 높은 투과도 변화, 낮은 구동 전압, 간단한 소자 구조 등 다양한 장점을 가지고 있어 차세대 투명 디스플레이로 각광받고 있다. 최근에는 이러한 전기변색 소자에 변색 특성 이외에 유연성 및 에너지 저장성 등 다양한 기능을 추가하는 연구가 활발하게 이루어지고 있다. 본 기고문에서는 전기변색 소자의 기본적인 구동 원리 및 다기능 개발 동향 등에 대해 알아보고자 한다.

• 한국표면공학회지
• /
• 제55권4호
• /
• pp.187-195
• /
• 2022

WO₃ thin films were synthesized by electrodeposition, and their electrochromic properties were investigated. The application of static voltage produced WO₃ films with a smooth, compact surface morphology, and the film thickness linearly increased with the application time. The thicker film showed a strong color contrast but a slow color-switching speed. High-temperature heat treatment exceeding 300 ℃ induced a phase transformation from an amorphous to a monoclinic structure and resulted in degraded electrochromic performance. Furthermore, the optimized WO₃ thin films demonstrated their potential application as electrochromic boards for writing and erasing letters using a simple modified 3D printer in a rapid, accurate process

• 한국재료학회지
• /
• 제3권6호
• /
• pp.632-637
• /
• 1993

3000$\AA$~6000$\AA$의 두께로 진공 증착한 $WO_3$ 박막의 광특성 및 일렉트로크로미즘에 대하여 연구하였다. 증착된 $WO_3$ 박막은 모두 무색 투명 하였으며 X-선회절 분석결과 비정질 상태로 밝혀졌으며, 비정질 $WO_3$ 박막의 굴절율은 가시광선 영격에서 1.9-2.1로, 광에너지 gap은 3.25eV로 나타났다. ITO투명전극/$WO_3$박막/$LiCIO_4$ ~propylene carbonate/백금 대향전극 구조를 갖는 일렉트로크로믹소자를 구성하여 일렉트로크로믹 특성을 조사하였다. $WO_3$ 박막의 coloration/과 bleaching현상은 $LiCIO_{4}$~propylene carbonate유기전해질과 ITO투명전극으로 부터 $Li^{+}$이온과 전자의 이중주입에 의하여 청색으로 나타났으며, 가역적으로 전기 화학적인 산화반응에 의하여 bleaching현상이 일어났다. Coloration과 bleaching현상, 광학밀도, 구동전압 및 응답속도 등의 일렉트로크로믹 특성은 $WO_3$ 박막의 증착조건, 전해액 농도, 투명전극의 sheet resistance 인가전압에 크게 의존하는 것으로 밝혀졌다.

• 한국전기전자재료학회논문지
• /
• 제15권6호
• /
• pp.511-517
• /
• 2002

The complex 1 $([Cp*Fe(CO)_2]_2-(\mu-CH=CH-CH=CH))$ which have butadiene as a bridge were synthesized from $Cp*(CO)_2FeK$ and cis-3,4-dichlorocyclobutene. The derivatives of complex 1 where one or two carbonyl groups are replaced by phosphine ligands have been prepared by photochemical substitution. The new derivatives $([Cp*Fe(L)_2]_2-(\mu-CH=CH-CH=CH))$ where L = $(Ph_2PCH_2CH_2PPh_2)$ and $([Cp*Fe(CO)(L)]_2-(\mu-CH=CH-CH=CH))$ where L : $PPh_3$ have been characterized from $^^1H-$, $^^13C-$,$^^31P-NMR$ and elemental analysis. Obtained complexes have been studied in electrochemical experiment and UV/VIS-near-IR. The mixed-valence radical cation forms of complex 2, 3 species were found to be delocalized as the Class III. Based on the separation of the waves ($\triangle E$ : 0.470 ~ 0.605 V), the efficiency of electronic communication between two metal centers of cation species leading to stabilization relative to neutral species. The phosphine-substitute complexes (2, 3) displays two reversible oxidation waves and oxidation state of metal centers-dependent color change, electrochromism, was observed from yellow to orange and deep blue in methylene chloride.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
• /
• pp.128-128
• /
• 2003

Electrochromism (EC) is defined as a phenomenon in which a change in color takes place in the presence of an applied voltage. Because of their low power consumption, high coloration efficiency, EC devices have a variety of potential applications in smart windows, mirror, and optical switching devices. An EC devices generally consist of a transparent conducting layer, electrochromic cathodic and anodic coloring materials and an ion conducting electrolyte. EC has been widely studied in transition metal oxides(e.g., WO$_3$, NiO, V$_2$O$\sub$5/) Among these materials, WO$_3$ is a most interesting material for cathodic coloration materials due to its lush coloration efficiency (CE), large dynamic range, cyclic reversibility, and low cost material. WO$_3$ films have been prepared by a variety of methods including vacuum evaporation, chemical vapor deposition, electrodeposition process, sol-gel synthesis, sputtering, and laser ablation. Sol-gel process is widely used for oxide film at low temperature in atmosphere and requires lower capital investment to deposit large area coating compared to vacuum deposition process.

• 한국분말재료학회지
• /
• 제22권5호
• /
• pp.326-330
• /
• 2015

In this study, we demonstrate the photoelectrochromic devices composed of $TiO_2$ and $WO_3$ nanostructures prepared by anodization method. The morphology and the crystal structure of anodized $TiO_2$ nanotubes and $WO_3$ nanoporous layers are investigated by SEM and XRD. To fabricate a transparent photoelectrode on FTO substrate, a $TiO_2$ nanotube membrane, which has been detached from Ti substrate, is transferred to FTO substrate and annealed at $450^{\circ}C$ for 1 hr. The photoelectrode of $TiO_2$ nanotube and the counter electrode of $WO_3$ nanoporous layer are assembled and the inner space is filled with a liquid electrolyte containing 0.5 M LiI and 5 mM $I_2$ as a redox mediator. The properties of the photoelectrochromic devices is investigated and Pt-$WO_3$ electrode system shows better electrochromic performance compared to $WO_3$ electrode.