• Title/Summary/Keyword: electrochemical property.

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Study on Electrochemical Sensing Property of Harbor Pollutants using Viologen Derivative (Viologen 유도체를 이용한 항만오염물질의 전기화학적 센싱 특성 연구)

  • Park, Sang-Hyun;Lee, Dong-Yun;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.119-120
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    • 2008
  • In this paper, viologen derivative is used as charge transfer material to develop sensors for detecting the organic pollutants which are the main reason of harbor pollution. We fabricated self-assembled monolayers of viologen derivative on gold electrode of QCM and investigated an electrochemical behavior property. We also determined electrochemical sensing property about environmental pollution materials such as bezene, phosphate and surfactant through quantitative and qualitative analysis of charge transfer using intrinsic property of viologen derivative by temperature and concentration change. From the achieved results, we can apply and develope the detecting sensors for harbor pollutants.

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Evaluation of the Corrosion Protective Property in Steel applying Spray Metal by using High-frequency Arc Metal Spray Method (고주파 아크 금속용사공법을 이용한 용사금속의 방식성능 평가)

  • Choe, Hong-Bok;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.94-95
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    • 2014
  • The purpose of this study is to evaluate the corrosion protective property of Al-Mg high-freqeuncy arc metal spray method in comparison to Zn-Sn and Zn-Al alloys by electrochemical method and CASS test. As a result, it appeared that Al-Mg alloy had very higher corrosion protective property through the electrochemical characteristic and the CASS test comparing with the other alloys.

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Structural Effect of Conductive Carbons on the Adhesion and Electrochemical Behavior of LiNi0.4Mn0.4Co0.2O2 Cathode for Lithium Ion Batteries

  • Latifatu, Mohammed;Bon, Chris Yeajoon;Lee, Kwang Se;Hamenu, Louis;Kim, Yong Il;Lee, Yun Jung;Lee, Yong Min;Ko, Jang Myoun
    • Journal of Electrochemical Science and Technology
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    • v.9 no.4
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    • pp.330-338
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    • 2018
  • The adhesion strength as well as the electrochemical properties of $LiNi_{0.4}Mn_{0.4}Co_{0.2}O_2$ electrodes containing various conductive carbons (CC) such as fiber-like carbon, vapor-grown carbon fiber, carbon nanotubes, particle-like carbon, Super P, and Ketjen black is compared. The morphological properties is investigated using scanning electron microscope to reveal the interaction between the different CC and the active material. The surface and interfacial cutting analysis system is also used to measure the adhesion strength between the aluminum current collector and the composite film, and the adhesion strength between the active material and the CC of the electrodes. The results obtained from the measured adhesion strength points to the fact that the structure and the particle size of CC additives have tremendous influence on the binding property of the composite electrodes, and this in turn affects the electrochemical property of the configured electrodes.

Investigation on Electrochemical Property of CNT Fibers and its Non-enzymatic Sensing Performance for Glucose Detection (CNT Fibers의 전기화학적 특성 및 비효소적 글루코스 검출 성능 고찰)

  • Song, Min-Jung
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.159-164
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    • 2021
  • As the attachable-type wearable devices have received considerable interests, the need for the development of high-performance electrode materials of fabric or textiles type is emerging. In this study, we demonstrated the electrochemical property of CNT fibers electrode as a flexible electrode material and its non-enzymatic glucose sensing performance. Surface morphology of CNT fibers was observed by SEM. And the electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fibers based sensor exhibited improved sensing performances such as high sensitivity, a wide linear range, and low detection limit due to improved electrochemical properties such as low capacitive current, good electrochemical activity by efficient direct electron transfer between the redox species and the electrode interface. Therefore, this study is expected to be used as a basic research for the development of high performance flexible electrode materials based on CNT fibers.

Effect of Tantalum and Lanthanum Addition on Electrochemical Property of Austenitic Stainless Steel in a Simulated PEMFC Environment

  • Kim, Kwang-Min;Koh, Seong-Ung;Kim, Kyoo-Young
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.338-343
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    • 2008
  • The electrochemical properties of W-modified austenitic stainless steels containing Ta and La were evaluated in a $H_{3}PO_{4}$ type PEMFC environment. Electrochemical test was conducted in 0.05 M $H_{3}PO_{4}$ solution at $80^{\circ}C$ and electrical property was conducted by contact resistance test. XPS was conducted to analyze the chemical elements consisting of passive film. Addition of La and Ta in W-modified austenitic stainless steel shows not only better corrosion resistance but also better electrical property.

Pore Structure and Electrochemical Properties of Carbon Aerogels as an EDLC-Electrode with Different Preparation Conditions (EDLC 전극용 카본에어로젤의 합성조건에 따른 기공구조 및 전기화학적 특성)

  • Seo, Hye Inn;Jung, Ji Chul;Kim, Myung-Soo
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.50-61
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    • 2018
  • Various carbon aerogels (CAs) were prepared from polymerization of resorcinol and formaldehyde and applied as the electrode materials of an electric double layer capacitor (EDLC) with the aim of controlling the textural and electrochemical properties of CAs by the type of base catalyst and the ratio of resorcinol to catalyst (R/C). The CAs from $NaHCO_3$ and $KHCO_3$ with $H^+$ ions had higher specific surface areas but exhibited lower electrochemical properties than those from $K_2CO_3$ and $Na_2CO_3$, which had more uniform pore size distributions. The electrochemical properties of $Na_2CO_3$ were superior to those of $K_2CO_3$ probably because the polarizing power of $Na^+$ ions was higher than $K^+$ ions. With an increasing R/C ratio, the pore sizes of CA showed a tendency to increase but the uniformity of the pore size distribution got worse. For the four base catalysts, the highest electrochemical property was obtained at the R/C ratio of 500.

Electrochemical Sensing Property of Harbor Pollutants using Viologen Derivative (Viologen 유도체를 이용한 항만오염물질의 전기화학적 특성)

  • Choi, Yong-Sung;Ji, Yoo-Kang;Park, Soo-Bong;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.05a
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    • pp.997-999
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    • 2008
  • In this paper, viologen derivative is used as charge transfer material to develop sensors for detecting the organic pollutants which are the main reason of harbor pollution. We fabricated self-assembled monolayers of viologen derivative on gold electrode of QCM and investigated an electrochemical behavior property. We also determined electrochemical sensing property about environmental pollution materials such as bezene, phosphate and surfactant through quantitative and qualitative analysis of charge transfer using intrinsic property of viologen derivative by temperature and concentration change. From the achieved results, we can apply and develope the detecting sensors for harbor pollutants.

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Electrochemical Sensor for Non-Enzymatic Glucose Detection Based on Flexible CNT Fiber Electrode Dispersed with CuO Nanoparticles (산화구리 나노입자가 분산된 CNT fiber 유연 전극 기반의 글루코스 검출용 비효소적 전기화학센서)

  • Min-Jung Song
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.52-57
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    • 2023
  • This study is a basic research for the development of high performance flexible electrode material. To enhance its electrochemical property, CuO nanoparticles (CuO NPs) were introduced and dispersed on surface of CNT fiber through electrochemical deposition method. The CNT fiber/CuO NPs electrode was fabricated and applied to electrochemical non-enzymatic glucose sensor. Surface morphology and elemental composition of the CNT fiber/CuO NPs electrode was characterized by scanning electron microscope (SEM) with energy dispersive X-ray spectrometry (EDS). And its electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fiber/CuO NPs electrode exhibited the good sensing performance for glucose detection such as high sensitivity, wide linear range, low detection limit and good selectivity due to synergetic effect of CNT fiber and CuO NPs. Based on the unique property of CNT fiber, CuO NPs were provide large surface area, enhanced electrocatalytic activity, efficient electron transport property. Therefore, it is expected to develop high performance flexible electrode materials using various nanomaterials.