• Journal of the Korean Electrochemical Society
• /
• v.17 no.2
• /
• pp.119-123
• /
• 2014

Here I report on how Fourier Transform Electrochemical Impedance Spectroscopy (FTEIS) overcomes the potential-current linearity problem encountered in the impedance calculation process. FTEIS was first invented to solve the time-related drawback of the conventional impedance technique. The dramatic time reduction of FTEIS enabled the real-time impedance measurement but brought about the linearity problem at the same time. While the conventional method circumvents the problem using the steady-state made by a sufficiently long measurement time, FTEIS cannot because of its real-time function. However, according to the mathematical development reported in this article, the potential step used in FTEIS is proved to avoid the linearity problem. During the step period, the potential and the current are linearized by the electrochemical impedance. Also, Fourier transform of the differentiated potential and current is proved to give the same result of the original ones.

• International Journal of Concrete Structures and Materials
• /
• v.2 no.2
• /
• pp.99-105
• /
• 2008

Southern exposure test specimens were used to evaluate corrosion performance of epoxy-coated reinforcing bars in chloride contaminated concrete by electrochemical impedance spectroscopy method. The test specimens with conventional bars, epoxy-coated bars and corrosion inhibitors were subjected 48 weekly cycles of ponding with sodium chloride solution and drying. The polarization resistance obtained from the Nyquist plot was the key parameter to characterize the degree of reinforcement corrosion. The impedance spectra of specimens with epoxy-coated bars are mainly governed by the arc of the interfacial film and the resistance against the charge transfer through the coating is an order of magnitude higher than that of the reference steel bars. Test results show good performance of epoxy-coated bars, although the coatings had holes simulating partial damage, and the effectiveness of corrosion-inhibiting additives. The corrosion rate obtained from the impedance spectroscopy method is equivalent to those determined by the linear polarization method for estimating the rate of corrosion of reinforcing steel in concrete structures.

• Journal of Electrochemical Science and Technology
• /
• v.12 no.4
• /
• pp.415-423
• /
• 2021

For a battery module where single cells are connected in series, the single cells should each have a similar state of charge (SOC) to prevent them from being exposed to an overcharge or over-discharge during charge-discharge cycling. To detect the existence of unbalanced SOC cells in a battery module, we propose a simple measurement method using a single-frequency response of electrochemical impedance spectroscopy (EIS). For a commercially available graphite/nickel-cobalt-aluminum-oxide lithium-ion cell, the cell impedance increases significantly below SOC20%, while the impedance in the medium SOC region (SOC20%-SOC80%) remains low with only minor changes. This impedance behavior is mostly due to the elementary processes of cathode reactions in the cell. Among the impedance values (Z, Z', Z"), the imaginary component of Z" regarding cathode reactions changes heavily as a function of SOC, in particular, when the EIS measurement is performed around 0.1 Hz. Thanks to the significant difference in the time constant of cathode reactions between ≤SOC10% and ≥SOC20%, a single-frequency EIS measurement enlarges the difference in impedance between balanced and unbalanced cells in the module and facilitates an ~80% improvement in the detection signal compared to results with conventional EIS measurements.

• Corrosion Science and Technology
• /
• v.2 no.6
• /
• pp.277-282
• /
• 2003

Holographic interferometry, an electromagnetic method, was used to study corrosion of carbon steel, aluminum and copper nickel alloys in NaOH, KCI and $H_2SO_4$ solutions respectively. The technique, called electrochemical emission spectroscopy, consisted of in-situ monitoring of changes in the number of fringe evolutions during the corrosion process. It allowed a detailed picture of anodic dissolution rate changes of alloys. The results were compared to common corrosion measurement methods such as linear polarization resistance measurements and electrochemical impedance spectroscopy. A good agreement between both data was found, thus indicating that holographic interferometry can be a very powerful technique for in-situ corrosion monitoring.

• Journal of Electrochemical Science and Technology
• /
• v.11 no.1
• /
• pp.1-13
• /
• 2020

As research on secondary batteries becomes important, interest in analytical methods to examine the condition of secondary batteries is also increasing. Among these methods, the electrochemical impedance spectroscopy (EIS) method is one of the most attractive diagnostic techniques due to its convenience, quickness, accuracy, and low cost. However, since the obtained spectra are complicated signals representing several impedance elements, it is necessary to understand the whole electrochemical environment for a meaningful analysis. Based on the understanding of the whole system, the circuit elements constituting the cell can be obtained through construction of a physically sound circuit model. Therefore, this mini-review will explain how to construct a physically sound circuit model according to the characteristics of the battery cell system and then introduce the relationship between the obtained resistances of the bulk (R_b), charge transfer reaction (R_ct), interface layer (R_SEI), diffusion process (W) and battery characteristics, such as the state of charge (SOC), temperature, and state of health (SOH).

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2016.10a
• /
• pp.134-135
• /
• 2016

To evaluate anti-corrosion performance of rebar in concrete according to the amount of chloride and inhibitor, electrochemical impedance spectroscopy(EIS) method was conducted in this study. For the anti-corrosion performance evaluation according to time, Impedance of rebar in concrete was measured before and after 5 cycle of corrosion acceleration. As a results, The impedance of rebar in concrete added chloride decreased than before corrosion acceleration. However impedance of other specimens was maintained or increased than before corrosion acceleration.

• Journal of Power Electronics
• /
• v.11 no.2
• /
• pp.237-243
• /
• 2011

Lithium batteries are widely used in mobile electronic devices due to their higher voltage and energy density, lighter weight and longer life cycle when compared to other secondary batteries. In particular, a high demand for lithium batteries is expected for electric cars. In the case of the lithium batteries used in electric cars, driving distance must be calculated accurately and discharging should not be done below a level that makes it impossible to crank. Therefore, accurate information on the state-of-charge (SOC) becomes an essential element for reliable driving. In this paper, a novel method for estimating the SOC of lithium polymer batteries using AC impedance is proposed. In the proposed method, the parameters are extracted by fitting the measured impedance spectrum on an equivalent impedance model and the variation in the parameter values at each SOC is used to estimate the SOC. Also to shorten the long length of time required for the measurement of the impedance spectrum, a novel method is proposed that can extract the equivalent impedance model parameters of lithium polymer batteries with the impedance measured at only two specific frequencies. Experiments are conducted on lithium polymer batteries, with similar capacities, made by different manufacturers to prove the validity of the proposed method.

• Journal of Electrochemical Science and Technology
• /
• v.15 no.2
• /
• pp.242-252
• /
• 2024

To date, methods used to assess the interfacial transition zone (ITZ), which represents the boundary between the aggregate and paste inside concretes, have primarily relied on destructive tests, and non-destructive tests has received little attention until recently. This study assessed the interfaces of concretes with lightweight aggregates based on electrochemical impedance spectroscopy (EIS) for high-strength concretes and examined the possibility of estimating the compressive strength of concretes through non-destructive testing using EIS. The experimental results revealed that the impedance of the hardened cement increased with increasing compressive strength and aggregate density. In particular, when the results of impedance measurement were displayed as a Nyquist plot, the intercept of the x-axis depicting the effective conductivity was proportional to the compressive strength. Furthermore, an equivalent circuit was selected to interpret the correlation between cement aggregates and impedance. Consequently, the compressive strength was found to increase with the value of the resistances of the electrolyte filled in continuous pores in the cement aggregate. And, the pores formed in the ITZ affect this value. The resistance at the ITZ for different aggregates was also obtained, and it was found that the resistance was consistent with the results predicted by SEM images of the ITZ and correlated with the strength of the concretes. The proposed method can be used as a way to easily determine the strength of cement according to differences in aggregate.

• Journal of Electrochemical Science and Technology
• /
• v.6 no.4
• /
• pp.146-151
• /
• 2015

Here I report an electrochemical simulation work that compares voltammetric current and resistance of a complex electrochemical reaction over a potential scan. For this work, the finite element method is employed which are frequently used for voltammetry but rarely for impedance spectroscopy. Specifically, this method is used for simulation of a complex reaction where a heterogeneous faradaic reaction is followed by a homogeneous chemical reaction. By tracing the current and its polarization resistance, I learn that their relationship can be explained in terms of rate constants of charge transfer and chemical change. An unexpected observation is that even though the resistance is increased by the rate of the following chemical reaction, the current can be increased due to the potential shift of the resistance made by the proceeding faradaic reaction. This report envisions a possibility of the FEM-based resistance simulation to be applied to understand a complex electrochemical reaction. Until now, resistance simulations are mostly based on equivalent circuits or complete mathematical equations and have limitations to find proper models. However, this method is based on the first-principles, and is expected to be complementary to the other simulation methods.

• Journal of Electrochemical Science and Technology
• /
• v.11 no.3
• /
• pp.318-321
• /
• 2020

Here I present a formula which converts a constant phase element (CPE) to its equivalent capacitor. Electrochemical impedance spectroscopy is capable of resolving a complex electrochemical processes into its faradaic and non-faradaic elements, and the non-faradaic process is frequently described as a CPE in place of a capacitor due to the non-ideality. Being described as a capacitor, the non-faradaic element provides information by its capacitance, but a CPE cannot provide a physical meaning. In order to solve the problem, the CPE has been dealt with as an equivalent capacitor of which the capacitance provides practical information. Succeeding the two methods previously suggested, a new conversion method is suggested in this report. While the previous ones manipulate only the CPE, the new method takes both the CPE and its related resistor into account for conversion. By comparing the results obtained by the three methods, we learn that the results are nearly the same within tolerable ranges, and conclude that any of the method choices is acceptable depending on the conditions of the system of interest.