• 제목/요약/키워드: effects of changing materials properties

검색결과 62건 처리시간 0.028초

기판 및 열처리 온도에 따른 SrWO4:Dy3+, Eu3+ 형광체 박막의 특성 (Effects of Substrate and Annealing Temperatures on the Properties of SrWO4:Dy3+, Eu3+ Phosphor Thin Films)

  • 김정윤;조신호
    • 한국재료학회지
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    • 제26권10호
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    • pp.577-582
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    • 2016
  • $Dy^{3+}$ and $Eu^{3+}$-codoped $SrWO_4$ phosphor thin films were deposited on sapphire substrates by radio frequency magnetron sputtering by changing the growth and thermal annealing temperatures. The results show that the structural and optical properties of the phosphor thin films depended on the growth and thermal annealing temperatures. All the phosphor thin films, irrespective of the growth or the thermal annealing temperatures, exhibited tetragonal structures with a dominant (112) diffraction peak. The thin films deposited at a growth temperature of $100^{\circ}C$ and a thermal annealing temperature of $650^{\circ}C$ showed average transmittances of 87.5% and 88.4% in the wavelength range of 500-1100 nm and band gap energy values of 4.00 and 4.20 eV, respectively. The excitation spectra of the phosphor thin films showed a broad charge transfer band that peaked at 234 nm, which is in the range of 200-270 nm. The emission spectra under ultraviolet excitation at 234 nm showed an intense emission peak at 572 nm and several weaker bands at 479, 612, 660, and 758 nm. These results suggest that the $SrWO_4$: $Dy^{3+}$, $Eu^{3+}$ thin films can be used as white light emitting materials suitable for applications in display and solid-state lighting.

Ultrasonic Vibration and Rheocasting for Refinement of Mg-Zn-Y Alloy Reinforced with LPSO Structure

  • Lu, Shulin;Yang, Xiong;Hao, Liangyan;Wu, Shusen;Fang, Xiaogang;Wang, Jing
    • Metals and materials international
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    • 제24권6호
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    • pp.1315-1326
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    • 2018
  • In this work, ultrasonic vibration (UV) and rheo-squeeze casting was first applied on the Mg alloy reinforced with long period stacking ordered (LPSO) structure. The semisolid slurry of Mg-Zn-Y alloy was prepared by UV and processed by rheosqueeze casting in succession. The effects of UV, Zr addition and squeeze pressure on microstructure of semisolid Mg-Zn-Y alloy were studied. The results revealed that the synergic effect of UV and Zr addition generated a finer microstructure than either one alone when preparing the slurries. Rheo-squeeze casting could significantly refine the LPSO structure and ${\alpha}-Mg$ matrix in $Mg_{96.9}Zn_1Y_2Zr_{0.1}$ alloy without changing the phase compositions or the type of LPSO structure. When the squeeze pressure increased from 0 to 400 MPa, the block LPSO structure was completely eliminated and the average thickness of LPSO structure decreased from 9.8 to $4.3{\mu}m$. Under 400 MPa squeeze pressure, the tensile strength and elongation of the rheocast $Mg_{96.9}Zn_1Y_2Zr_{0.1}$ alloy reached the maximum values, which were 234 MPa and 17.6%, respectively, due to its fine ${\alpha}-Mg$ matrix (${\alpha}1-Mg$ and ${\alpha}2-Mg$ grains) and LPSO structure.

용융드래그방법으로 제작한 마그네슘합금 박판의 특성에 미치는 기본적인 공정조건 확립 (Establishment of Fundamental Process Conditions on Properties of Magnesium Alloy Thin Plates Fabricated by the Melt Drag Method)

  • 한창석;이찬우
    • 한국재료학회지
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    • 제32권7호
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    • pp.326-331
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    • 2022
  • AZ31 magnesium alloy was used to manufacture a thin plate using a melt drag method. The effects of roll speed, molten metal temperature, and molten metal height, which are the basic factors of the melt drag method, on the surface shape, the thickness of the thin plate, Vickers hardness, and microstructure of the thin plate were investigated. It was possible to manufacture AZ31 magnesium alloy thin plate at the roll speed range of 1 to 90 m/min. The thickness of the thin plate, manufactured while changing only the roll speed, was about 1.8 to 8.8 mm. The shape of the solidified roll surface was affected by two conditions, the roll speed and the molten metal height, and the Vickers hardness of the manufactured magnesium alloy thin plate value ranged from Hv38~Hv60. The microstructure of the thin plate produced by this process was an equiaxed crystal and showed a uniform grain size distribution. The grain size was greatly affected by the contact state between the molten metal and the solidification roll, and the amount of reactive solids and liquids scraped at the same time as the thin plate. The average grain size of the thin plate fabricated in the range of these experimental conditions changed to about 50-300 ㎛.

정보기술이 자원공유에 미치는 영향 (The impact of technology on resource sharing)

  • 이영자
    • 한국도서관정보학회지
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    • 제22권
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    • pp.205-244
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    • 1995
  • Originally the concept of the traditional resource sharing has been discussed in the context of bibliographic materials, and has been labor-intensive and high-cost activities. The technology has had a great impact on such pattern of the resource sharing, and has expanded the limited scope of the traditional concept into the sharing of library information in the levels of local, regional and national systems, and expertise, materials, facilities, equipments and personnels of the library system. While the traditional circulation service as a basic method to share library materials by users can provide the resource to a single person at a time, the electronic resource can be shared, by multi-users at a time anytime anywhere. The maximization of the electronic resource sharing requires that publishing process should be fundamentally changed and articles, books, chapters, speech manuscripts, music scores, maps, sound, and other formats of materials should be prepared in machine readable format. This study examined the positive effects of the technology on the resource sharing, but not investigate the concrete and complex problems as to the cost, guidelines, detailed procedures, design details, and intellectual properties and protection involved in the resource sharing. Some findings extracted from the study can be summarized as follows; (1) ILL will lose its meaning as a method to share the materials if they are all in the electronic format and the phrase 'networked information resource' becomes omnipresent. (2) The technology keeps on changing the concept of resource sharing. Today, the scope of resource sharing not only encompasses the sharing of the primary and secondary materials but also the sharing of the processings(eg. cataloging), expertise, user education, special facilities, and the integrated automated library systems. (3) The sharing of the networked resource will be a method to provide better services for library users in the low cost. (4) The a n.0, pplication of the technology to the resource sharing should be focus on the method which allows an end-users to do the direct access to the needed materials, and to be delivered the primary document as soon as possible.

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반경질 폴리우레탄 발포체의 물성에 대한 사슬 연장제와 무기 충전제의 영향 (Effects of Chain Extender and Inorganic Filler on the Properties of Semi-Rigid Polyurethane Foams)

  • 차국찬;송점식;이석민;문무성
    • 폴리머
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    • 제34권1호
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    • pp.8-13
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    • 2010
  • 발포체의 물성은 발포체의 밀도, 사용된 폴리머의 기계적 물성과 열린 셀의 함량, 셀 크기, 셀 크기 분포, 셀 형태, 스킨층의 두께 등을 포함하는 셀 구조에 의존하며, 이러한 발포체의 밀도는 사용된 폴리머의 종류와 가교제의 농도 그리고 가공 기술 및 가공 조건과 같은 다양한 원료 물질과 가교 조건에 영향을 받는다. 본 연구에서는 폴리에스터 폴리올, MDI, 아민계 촉매, 틴계 촉매, 실리콘 유화제, 물을 기본 폴리우레탄 발포체의 조성으로 설정하였으며, 발포체에 있어서 stiff-chain 요소인 사슬 연장제의 첨가에 의하여 가교 밀도를 증가시켰다. 또한, 폴리우레탄 발포체의 기계적 물성을 높이기 위해 무기 충전제로 입자 크기와 $SiO_2$ 함량이 다른 실리카와 탈크 각각 2종류를 사용하였다. 발포체의 제조시 사슬 연장제와 무기 충전제의 종류와 함량비를 달리하면서 모듈러스, 인장 강도, 압축 강도, 경도의 물성 변화를 알아보았고, 전자현미경을 통해 셀의 크기 변화와 무기 충전제의 분포도를 관찰하였다.

Effects on the Qualities of Proteolysis to Beef by Non-coating and Coating Protease Treatment

  • Kim, Kwang-Il;Lee, Sang-Yoon;Kim, Soo-Jin;Seo, Jae-Hee;Lee, Joong-Kyu;Shin, Jung-Kue;Cho, Hyung-Yong;Choi, Mi-Jung
    • 한국축산식품학회지
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    • 제36권1호
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    • pp.114-121
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    • 2016
  • This study was performed to improve the techniques used for tenderizing red meat as elderly food. Beef meat was immersed in liposome encapsulated enzyme solution and the effect of protease encapsulation on the beef properties was analyzed. The protease encapsulation properties were analyzed according to the size distribution and enzymatic activity. After enzyme reaction on the beef, the chemical properties of the meat such as pH, water holding capacity, shear rate, lipid oxidation and total volatile basic nitrogen (TVB-N) were analyzed. The pH of the beef increased during the reaction and coating protease (CP) was higher than non-coating protease (NCP). Total color differences were increased remarkably after 36 h and generally, the difference in CP was relatively lower than in NCP. WHC was significantly decreased within 24 h, and no effect from the protease coating was observed. Protease activity was significantly increased within 48 h and no differences in the enzyme coating were observed. The TVB-N value of NCP was increased within 24 h while CP was sustained for up to 36 h. The TVB-N value of protease treated meat increased after 36 h and no effect from the protease coating was detected. Consequently, liposome encapsulated protease was found to have similar properties as non-coated protease. Application of liposome seems to be an interesting option for injecting various functional materials without changing the properties of meat.

Eu3+ 함량비가 Y1-xPO4:Eux3+ 적색 형광체의 발광 특성에 미치는 영향 (Effects of Eu3+ Concentration on the Photoluminescence Properties of Y1-xPO4:Eux3+ Red Phosphor)

  • 조선욱;조신호
    • 한국진공학회지
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    • 제20권6호
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    • pp.430-435
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    • 2011
  • 고상 반응법을 사용하여 $Eu^{3+}$ 이온의 함량비를 변화시키면서 $Y_{1-x}PO_4:{Eu_x}^{3+}$ 적색 형광체를 합성하였다. 모든 적색 형광체의 결정 구조는 $25.88^{\circ}$에 중심을 갖는 (200) 주 회절 피크로 구성되는 정방정계이었으며, 결정 입자의 형상은 $Eu^{3+}$ 이온의 함량비가 증가함에 따라 구형에 근접하고 균일한 크기 분포를 나타내었다. 형광 특성의 경우에, $Eu^{3+}$ 이온의 함량비에 관계없이 모든 세라믹은 파장 593.0과 619.2 nm에 피크를 갖는 각각 적주황색과 적색 형광을 나타내었다. $Eu^{3+}$ 이온의 함량비가 증가함에 따라 여기 스펙트럼의 파장은 약간씩 장파장 쪽으로 이동하면서 흡수 세기는 증가하는 경향을 보였으며, $Eu^{3+}$ 이온의 함량비가 0.15 mol일 때 최대 흡수 및 발광 스펙트럼이 관측되었다.

Modal testing and finite element model calibration of an arch type steel footbridge

  • Bayraktar, Alemdar;Altunisk, Ahmet Can;Sevim, Baris;Turker, Temel
    • Steel and Composite Structures
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    • 제7권6호
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    • pp.487-502
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    • 2007
  • In recent decades there has been a trend towards improved mechanical characteristics of materials used in footbridge construction. It has enabled engineers to design lighter, slender and more aesthetic structures. As a result of these construction trends, many footbridges have become more susceptible to vibrations when subjected to dynamic loads. In addition to this, some inherit modelling uncertainties related to a lack of information on the as-built structure, such as boundary conditions, material properties, and the effects of non-structural elements make difficult to evaluate modal properties of footbridges, analytically. For these purposes, modal testing of footbridges is used to rectify these problems after construction. This paper describes an arch type steel footbridge, its analytical modelling, modal testing and finite element model calibration. A modern steel footbridge which has arch type structural system and located on the Karadeniz coast road in Trabzon, Turkey is selected as an application. An analytical modal analysis is performed on the developed 3D finite element model of footbridge to provide the analytical frequencies and mode shapes. The field ambient vibration tests on the footbridge deck under natural excitation such as human walking and traffic loads are conducted. The output-only modal parameter identification is carried out by using the peak picking of the average normalized power spectral densities in the frequency domain and stochastic subspace identification in the time domain, and dynamic characteristics such as natural frequencies mode shapes and damping ratios are determined. The finite element model of footbridge is calibrated to minimize the differences between analytically and experimentally estimated modal properties by changing some uncertain modelling parameters such as material properties. At the end of the study, maximum differences in the natural frequencies are reduced from 22% to only %5 and good agreement is found between analytical and experimental dynamic characteristics such as natural frequencies, mode shapes by model calibration.

입자 내 조성 변화가 수분산성 아크릴 에멀젼 점착제의 점착 물성과 수분산성에 미치는 영향 (Effects of Intra-particle Composition on the Adhesive Properties and Water Dispersity of Water Dispersible Acrylic Emulsion Pressure Sensitive Adhesive)

  • 서인선;이명천
    • 공업화학
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    • 제18권5호
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    • pp.444-448
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    • 2007
  • 수분산성 점착제의 점착 물성과 수분산성에 미치는 입자 내 조성의 영향을 알아보기 위하여 다양한 입자 내 조성을 갖는 아크릴계 에멀젼형 점착제를 제조하여 각각의 점착 물성과 수분산성을 조사하였다. 입자 내 단일 조성을 갖는 경우 유지력과 수분산성을 동시에 만족시키기 어려웠으나 입자 내 조성을 hard core/soft shell 형태를 갖게 함으로써 수분산성은 적게 희생하고 유지력을 높일 수 있었다. 또한 메타크릴산/아크릴산(MAA/AA)의 중량비가 4/1인 경우에는 친수성 물질인(AA+MAA) 함량이 core로 갈수록 많은 경우와 shell로 갈수록 많은 경우 모두 유지력은 크게 상승했으나 초기점착력은 크게 낮아졌으며 수분산성은 거의 관찰되지 않았다. 그러나 MAA/AA 중량비가 1/4인 경우는 shell 부분에 (AA+MAA) 함량이 많은 경우에 수분산성이 더 컸으나 유지력은 상대적으로 적게 나타났다.

비균일 조직에 따른 불균일 변형 해석을 위한 미시역학적 초소성 모텔 (Micromechanical Superplastic Model for the Analysis of Inhomogeneous Deformation in Heterogeneous Microstructure)

  • 김태원
    • 대한기계학회논문집A
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    • 제25권12호
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    • pp.1933-1943
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    • 2001
  • A micromechanical model is presented for superplasticity in which heterogeneous microstructures are coupled with deformation behavior. The effects of initial distributions of grain size, and their evolutions on the mechanical properties can be predicted by the model. Alternative stress rate models such as Jaumann rate and rotation incremental rate have been employed to analyze uniaxial loading and simple shear problems and the appropriate modeling was studied on the basis of hypoelasticity and elasto-viscoplasticity. The model has been implemented into finite element software so that full process simulation can be carried out. Tests have been conducted on Ti-6Al-4V alloy and the microstructural features such as grain size, distributions of grain size, and volume fraction of each phase were examined for the materials that were tested at different strain rates. The experimentally observed stress-strain behavior on a range of initial grain size distributions has been shown to be correctly predicted. In addition, the effect of volume fraction of the phases and concurrent grain growth were analyzed. The dependence of failure strain on strain rate has been explained in terms of the change in mechanism of grain growth that occurs with changing strain rate.