• Macromolecular Research
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• 제14권6호
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• pp.596-602
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• 2006

The effect of high-temperature spinning and poly(vinyl pyrrolidone) (PVP) additive on poly(vinylidene fluoride) (PVDF) hollow fiber membranes was investigated using differential scanning calorimetry, X-ray diffraction measurement, and scanning electron microscopy, together with the corresponding microfiltration performances such as water flux, rejection rate, and elongational strength. Using high-temperature spinning, porous hollow fiber membranes with particulate morphology were prepared through PVDF crystallization. The particulate structure of the membranes was further modified by the addition of miscible PVP with PVDF. Due to these effects, the rejection rate and strength of the fibers were increased at the expense of reduced water flux and mean pore size, which indicates that high-temperature spinning and PVP addition are vary effective to control the morphology of PVDF hollow fiber membranes for microfiltration.

• 상하수도학회지
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• 제23권4호
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• pp.407-416
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• 2009

The objective of this study was to evaluate the variation of physical properties and adsorption capacity after regeneration of Granular Activated Carbon (GAC). It was found that the loss rate of regenerated carbon was related to the usage time of GAC. The correlations between iodide number and loss rate also determined. Effective size and uniformity coefficient for regenerated GAC were within a similar range compared to virgin GAC. This result indicated that the function as media is recovered. Although iodide number and specific surface area for regenerated GAC were not completely recovered compared to that of virgin GAC, cumulative pore volumes of regenerated GAC were increased. Removal efficiency of organic matter in regenerated GAC was resulted the same or slightly higher than that of virgin GAC. This result indicates that the number of mesopore responsible for removal of organic matter was increased after regeneration.

• Journal of Mechanical Science and Technology
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• 제20권10호
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• pp.1680-1690
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• 2006

As a promising and novel manufacturing technology, laser aided direct metal deposition (DMD) process produces near-net-shape functional metal parts directly from 3-D CAD models by repeating laser cladding layer by layer. The key of the build-up mechanism is the effective control of powder delivery and laser power to be irradiated into the melt-pool. A feedback control system using two sets of optical height sensors is designed for monitoring the melt-pool and real-time control of deposition dimension. With the feedback height control system, the dimensions of part can be controlled within designed tolerance maintaining real time control of each layer thickness. Clad nugget shapes reveal that the feedback control can affect the nugget size and morphology of microstructure. The pore/void level can be controlled by utilizing pulsed-mode laser and proper design of deposition tool-path. With the present configuration of the control system, it is believed that more innovation of the DMD process is possible to the deposition of layers in 3-D slice.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2004년도 추계학술대회
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• pp.272-273
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• 2004

Filter media are one of themost important choices when bilfiltration is applied. Filter media provide adsorbing microbes with available sites for residence and the residential cells grow to degrade or decompose target waste gases. Up to date, filter media were only qualitatively analyzed. As a quantitative approach to filter material for biofiltration, a simple model based on reaction kinetics and mass action law (Ottengraf's Model in 1983) was presented. Cork, zeolite, and granulated activated carbon were tested in terms of effective surface area, cell covered fraction of adsorbing sites, surface roughness, and pore size distribution. The cell covered fraction, surface roughness and hydrophilicity was found to be closely related to the efficiency of gas degradation in biofiltration. The cork was the best candidate for cell residence and growth in this work.

• Korean Chemical Engineering Research
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• 제53권5호
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• pp.632-637
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• 2015

Mesoporous $TiO_2$ granules were prepared by spray pyrolysis using nano-sized titania particles which were synthesized by a hydrothermal method, and they were evaluated as the photoanode of dye-sensitized solar cells. To enhance the cell efficiency, nanoparticles within granules were chemically interconnected by adding titanium ethoxide (TEOT) to colloidal spray solution. The resulting titania particles had anatase phase without forming rutile. $TiO_2$ granules obtained showed about 400 nm in size, the specific surface area of $74-77m^2/g$, and average pore size of 13-17 nm. The chemical modification of $TiO_2$ granules by adding TEOT initially to the colloidal spray solution was proved to be an effective way in terms of increasing both the light scattering within photoanode and the lifetimes of photo-excited electrons. Consequently, the light-harvesting efficiency of TEOT-modified granules (${\eta}=6.72%$) was enhanced about 14% higher than primitive nanoparticles.

• Geomechanics and Engineering
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• 제13권2호
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• pp.319-331
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• 2017

This vacuum preloading combined with polyacrylamide (PAM) flocculation was proposed to separating solid-liquid in waste slurry and to improving bearing capacity of soft soil ground. By using waste slurry taken from drilled shaft construction site in Shanghai, China, a series of settling column tests with four typical flocculants and one normal for waste slurry were carried out for comparative analysis. The optimal amounts for each flocculant were obtained from the column tests. Then, model tests on vacuum preloading with anionic polyacrylamide (APAM) flocculation and without flocculants were carried out. The out of water and the settlement of slurry surface ground were monitored during the model tests, and the changes in water content, particle-size and pore-size distributions in different positions after the model tests were measured and discussed. It is found that water content of the waste slurry without APAM flocculation changed from 204 to 195% by 24 hours standing and 15 hours vacuum preloading, while the water content of the waste slurry with APAM flocculation was declined from 163 to 96% by 24 hours standing, and was further reduced into 37% by 136 hours vacuum preloading, which shows that the combined method is feasible and effective.

• 한국물환경학회지
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• 제30권5호
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• pp.532-538
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• 2014

A cylinder-shaped filter was developed to manage the runoff from construction sites. Compressed air was used for back-washing and pore sizes of filter were $23{\mu}m$ and $46{\mu}m$. The turbid water was prepared using sediments in construction sites. The grain size analysis showed that grains smaller than $38{\mu}m$ and larger than $335{\mu}m$ in size constituted 34.4 % and 37.6 %, respectively. Removal efficiency of the filter on turbidity, SS, COD, TN and TP showed 25~37%, 20~40%, 50~55%, 23~27% and 14~20%, respectively, whereas their removal efficiecy by using coagulant PAC showed 77~84%, 70~83%, 53~60%, 27~36%, and 59~75%, respectively. The filtration time was determined to be around 10 to 20 minutes. Back-washing for 10 seconds by pressurized air resulted in a satisfactory regeneration efficiency. According to the aforementioned test results, the cylinder-shaped filter is effective in reducing turbidity and would be suitable for practical application in construction sites and farms.

• 한국지하수토양환경학회지:지하수토양환경
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• 제19권3호
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• pp.39-46
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• 2014

Hydraulic conductivity is an important parameter, representing permeable property of the groundwater in aquifers, in the issues of groundwater development, groundwater contamination, and groundwater flow, etc. We estimated a relationship between hydraulic conductivity and electrical properties (formation factor, chargeability, and time constant) of silty sand in the laboratory. For this study, we conducted grain size analysis, constant head permeameter test, and measured electrical resistivity and spectral induced polarization of silty sand samples collected from the riverside alluvium of the Nakdong River in Nogok-ri area, Dasan-myeon, Goryeong-gun in Gyeongbook Province, Korea. In the laboratory test, we used soil samples of approximately uniform porosity with 0.5% error range, and kept the electrical resistivity of pore water with 100 ohm-m. As a result, the relationship between effective particle size and hydraulic conductivity agrees fairly well with the existing empirical formulas. Hydraulic conductivity was correlated with formation factor, chargeability, and time constant: hydraulic conductivity increased with increasing formation factor and time constant as well as with decreasing chargeability.

• 센서학회지
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• 제15권3호
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• pp.173-178
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• 2006

Silica aerogel with ultra low density and high porosity has been focused on versatile application due to its fascinating properties. Ambient drying process of waterglass, in this study was researched to fabricate a crack-free monolith body in the point view of cost effective way. Wet gel was obtained by removing of $Na^{+}$ ions in waterglass, which contains 8 wt% of $SiO_{2}$. Xylene, which has a low vapor pressure, was used as a solution substitutor to prevent the formation a cracks during drying. Various surface modifiers like as hexamethyldisilazane (HMDSZ), trimethylchlorosilane (TMCS), methyltriethoxylsilane (MTES), methyltrimethoxysilane (MTMS) and phenyltriethoxysilane (PTES) were used in order to improve hydrophobicity of the waterglass Silica aerogel. Some physical properties of the surface modified aerogels were investigated by FT-IR, TGA, BET and SEM. Hydrophobicity and hydrophilicity of Silica aerogel is attributed to the Si-OH bond and the non-polar C-H bond groups on the surface of aerogel. Crack-free waterglass aerogel with >90 % of porosity, 17 nm of pore size and <0.15 $g/cm^{3}$ of density was prepared. HMDSZ and TMCS are effective as a surface modifier

• 대한토목학회논문집
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• 제28권6C호
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• pp.339-347
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• 2008

현장 관입 실험은 프로브 관입에 따라 주변 지반을 의도적으로 파괴시켜 지반특성을 파악할 수 있다. 본 논문의 목적은 현장 점토지반에 서로 다른 크기의 프로브 관입으로 인한 간극 수압 소산 특성을 이용하여 파괴에 따른 교란 효과를 분석하는 것이다. 현장 실험을 수행하기 위해 콘관입 시험(CPT), 딜라토미터 시험(DMT) 그리고 현장 속도 프로브 장비(FVP: Field Velocity Probe)가 사용되었다. 샌드 매트(sand mat), PBD 그리고 사석을 이용한 지반 개량 중인 부산 북컨테이너 현장에서 실험이 진행 되었으며, 샌드 매트(sand mat)공법 이후 실내 실험을 수행하기 위해 시료가 채취 되었다. 실내에서는 물성치 실험 및 압밀 실험을 수행하여 지반 특성과 수평압밀계수 값을 도출하였다. 현장 실험은 지반 개량 후 압밀도 90% 시점에서 사석 제거 후 케이싱을 통해 CPT, DMT 그리고 FVP 순서대로 실험이 수행 되었다. 관입에 따른 영향 범위를 최소화 시키기 위해 각각의 실험은 3m 간격을 유지 하였으며, 매 심도 24m에서 관입을 멈추고 시간에 따른 간극 수압 변화 양상을 측정하였다. 실내 압밀 실험을 통해 수평 압밀 계수$(C_h)$를 산정하였으며, 현장 실험을 통해 각 프로브에 따른 $t_{50}$ 값을 계산 하였다. $t_{50}$값을 이용하여 산정된 등가 유효 반경은 FVP가 가장 작게 그리고 DMT가 가장 크게 산정되었다.