• Title/Summary/Keyword: effective diffusion

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Nitrogen Removal in Fluidized Bed and Hybrid Reactor using Porous Media (다공성 담체를 이용한 유동상 및 하이브리드 반응기에서의 질소제거)

  • Jun, Byong-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.542-548
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    • 2005
  • A fluidized bed reactor containing porous media has been known to be effective for nitrogen and organic matters removal in wastewater. The porous media which attached microbes plays important roles in simultaneous nitrification/denitrification (SND) due to coexistence of oxic, anaerobic and anoxic zone. For SND reaction, oxygen and organic substrates should be effectively diffused from wastewater into the intra-carrier zone. However, the overgrowth heterotrophic microbes at the surface of porous media may restrict from substrates diffusion. From these viewpoints, the existence and effect of heterotrophic bacteria at surface of porous media might be the key point for nitrogen removal. A porous media-membrane hybrid process was found to have improved nitrogen removal efficiency, due to stimulated denitrification as well as nitrification. Microelectrode studies revealed that although intra-media denitrification rate in a conventional fluidized bed was limited by organic carbon, this limitation was reduced in the hybrid process, resulting in the increased denitrification rate from 0.5 to $4.2\; mgNO_3-N/L/hr$.

Electrochemical Characterization of Stainless Steel in Ethanolamine Solution Containing an Alkyl Group using Cyclic Voltammetry (순환전압전류법에 의한 알킬기를 함유한 에탄올아민용액에서 스테인리스의 전기화학적 특성)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.66-73
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    • 2014
  • In this work, the current-voltage curves for stainless steel in the ethanolamine solution containing alkyl group were measured using the conventional three electrodes of cyclic voltammetry. Stainless steel as working electrode, Ag/AgCl electrode as reference electrode and Pt wire as counter electrode were used respectively. As a result, the C-V characteristics of stainless steel were to be for an irreversible process due to the oxidation current from cyclic voltammogram, using N-ethylethanolamine and N,N-dimethylethanolamine solutions. Effective diffusivity of corrosion inhibitors was decreased with increasing concentration. It was found from SEM images of the metal that the electrolyte (specific name ?)(0.5 N) as corrosion inhibitor was added into a N, N-diethylethanolamine solution ($1.0{\times}10^{-3}M$) containing copper and nickel, the corrosion inhibiting effect was enhanced.

Joining and properties of electrode for CoSb3 thermoelectric materials prepared by a spark plasma sintering method (방전 플라즈마 소결법을 이용한 CoSb3계 열전재료의 전극 접합 및 특성)

  • Kim, K.H.;Park, J.S.;Ahn, J.P.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.30-34
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    • 2010
  • $CoSb_3$-based skutterudite compounds are promising candidates as thermoelectric (TE) materials used in intermediate temperature region. In this study, sintering of $CoSb_3$ powder and joining of $CoSb_3$ to copper-molybdenum electrode have been simultaneously performed by spark plasma sintering technique. The Ti foil was used for preventing the diffusion of copper into $CoSb_3$ and the Cu : Mo = 3 : 7 Vol. ratio composition was selected by the consideration of thermal expansion coefficients. The insertion of Ti interlayer between Cu-Mo and $CoSb_3$ was effective to join $CoSb_3$ to Cu-Mo by forming an intermediate layer of $TiSb_2$ at the Ti-$CoSb_3$ boundary. However, the formation of TiSb and TiCoSb intermediate layers deteriorated the joining properties by the generation of cracks in the interface of intermediate layer/$CoSb_3$ and intermediate/intermediate layers.

Reduction of Dynamic False Contours based on Gray Level Selection method in PDP (계조 수 감소를 이용한 PDP내에서 의사 윤곽 제거 기법)

  • Ahn Sang-Jun;Eo Yoon-Phil;Lee Sang-Uk
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.7C
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    • pp.716-725
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    • 2005
  • In this paper, we propose a new approach for the reduction of the dynamic false contours, which detects and compensates false contour artifacts adaptively. First, we develop a simple but effective method to select the pixels that are likely to cause the motion artifacts, based on the distribution of pixel values. Then, we merge the selected pixels into several regions using tree structure. Next, we reduce number of gray levels within the regions slightly to reduce the false contours. Note that reducing number of gray levels yield the distortion, thus it is applied only to the selected regions, instead of the whole picture. Intensive simulations on real moving image show that the proposed algorithm alleviates the dynamic false contours effectively with tolerable computational complexity.

Effect of Catalyst Type and Reaction Medium on Fischer-Tropsch Synthesis for Production of Hydrocarbon from Syngas (합성가스로부터 탄화수소제조를 위한 피서트롭스 반응에 관한 촉매 종류 및 반응매체의 영향)

  • Kim, Chul-Ung;Jeong, Soon-Yong;Jeong, Kwang-Eun;Koh, Jae-Cheon;Chae, Ho-Jeong;Kim, Tae-Wan;Park, Hyun-Joo;Lee, Sang-Bong;Han, Jeong-Sik;Jeong, Byung-Hun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.658-663
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    • 2010
  • With petroleum reserves dwindling, interest has been increasing worldwide in Fischer-Tropsch synthesis (FT) as a method of producing synthetic liquid fuels and chemicals from coal, natural gas or biomass. In general, FT synthesis is operated through the gas phase fixed-bed reaction system. Recently, there are lots of study in supercritical fluid due to unique characteristics such as the quick diffusion of reactant gas, effective removal of reaction heat, and the in-situ extraction of high molecular weight hydrocarbon, such as wax. In this study, our major aim is to obtain a deeper insight into the effect of the type of support on the reaction performance over a supported cobalt catalyst in a fixed bed reactor.

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Shape Optimization of an Active Micro-Mixer for Improving Mixing Efficiency (혼합 효율 향상을 위한 마이크로 동적 믹서의 형상최적화)

  • Park, Jae-Yong;Kim, Sang-Rak;Lee, Won-Gu;Yoo, Jin-Sik;Kim, Young-Dae;Maeng, Joo-Seung;Han, Seog-Young
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.146-152
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    • 2007
  • An active micro-mixer, which was composed of an oscillating micro-stirrer in the microchannel to provide rapid, effective mixing at high flow, rates was analyzed. The effects of molecular diffusion and disturbance by the stirrer were considered with regard to two types of mixer models: the simple straight microchannel and microchannel with an oscillating stirrer. Two types of mixer models were studied by analyzing mixing behaviors such as their interaction after the stirrer. The mixing was calculated by Lattice Boltzmann methods using the D2Q9 model. In this study, the time-averaged mixing index formula was used to estimate the mixing performance of time-dependent flow. The mixing indices of the two models compared. From the results, it was found that the mixer with an oscillating stirrer was much more enhanced and stabilized. Therefore, an optimum design for a dynamic micro-mixer with an oscillating stirrer was performed using Taguchi method in order to obtain a robust solution. The design parameters were established as the frequency, the length and the angle of the stirrer and the optimal values were determined to be 2, 0.8D and ${\pm}75^{\circ}$, respectively. It was found that the mixing index of the optimal design increased 80.72% compared with that of the original design.

Approximate Optimization of an Active Micro-Mixer (능동형 미소혼합기의 근사최적화)

  • Park, Jae-Yong;Kim, Sang-Rak;Yoo, Jin-Sik;Lim, Min-Gyu;Kim, Young-Dae;Han, Seog-Young;Maeng, Joo-Seung
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.17 no.5
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    • pp.95-100
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    • 2008
  • An active micro-mixer, which is composed of an oscillating micro-stirrer in the micro-channel to provide effective mixing was optimized. The effects of molecular diffusion and disturbance by the stirrer were considered with regard to two types of mixer models: the simple straight micro-channel and micro-channel with an oscillating stirrer. Two types of mixer models were studied by analyzing mixing behaviors such as their interaction after the stirrer. The mixing was calculated by Lattice Boltzmann methods using the D2Q9 model. In this study, the time-averaged mixing index formula was used to estimate the mixing performance of time-dependent flow. The mixing indices of the two models were compared. From the results, it was found that the mixer with an oscillating stirrer was much more enhanced and stabilized. Therefore, an approximate optimization of an active micro-mixer with an oscillating stirrer was performed using Kriging method with OLHD(Optimal Latin Hypercube Design) in order to determine the optimal design variables. The design parameters were established as the frequency, the length and the angle of the stirrer. The optimal values were obtained as 1.0346, 0.66D and $\pm45^{\circ}$, respectively. It was found that the mixing index of the optimal design increased by 88.72% compared with that of the original design.

ROLE OF REACTIVE OXYGEN SPECIES IN MALE INFERTILITY

  • Sharma, Rakesh K.;Agarwal, Ashok
    • 대한생식의학회:학술대회논문집
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    • 2000.06a
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    • pp.13-28
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    • 2000
  • Human spermatozoa exhibit a capacity to generate ROS and initiate peroxidation of the unsaturated fatty acids in the sperm plasma membrane, which plays a key role in the etiology of male infertility. The short half-life and limited diffusion of these molecules is consistent with their physiologic role in key biological events such as acrosome reaction and hyperactivation. The intrinsic reactivity of these metabolites in peroxidative damage induced by ROS, particularly $H_2O_2$ and the superoxide anion, has been proposed as a major cause of defective sperm function in cases of male infertility. The number of antioxidants known to attack different stages of peroxidative damage is growing, and it will be of interest to compare alpha-tocopherol and ascorbic acid with these for their therapeutic potential in vitro and in vivo. Both spermatozoa and leukocytes generate ROS, although leukocytes produce much higher levels. The clinical significance of leukocyte presence in semen is controversial. Seminal plasma confers some protection against ROS damage because it contains enzymes that scavenge ROS, such as catalase and superoxide dismutase. A variety of defense mechanisms comprising a number of antioxidants can be employed to reduce or overcome oxidative stress caused by excessive ROS. Determination of male infertility etiology is important, as it will help us develop effective therapies to overcome excessive ROS generation. ROS can have both beneficial and detrimental effects on the spermatozoa and the balancing between the amounts of ROS produced and the amounts scavenged at any moment will determine whether a given sperm function will be promoted or jeopardized. Accurate assessment of ROS levels and, subsequently, OS is Vital, as this will help clinicians both elucidate the fertility status and identify the subgroups of patients that respond or do not respond to these therapeutic strategies. The overt commercial claims of antioxidant benefits and supplements for fertility purposes must be cautiously looked into, until proper multicentered clinical trials are studied. From the current data it appears that no Single adjuvant will be able to enhance the fertilizing capacity of sperm in infertile men, and a combination of the possible strategies that are not toxic at the dosage used would be a feasible approach.

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A Parametric Study on the Reason and Control of Crack during the Construction of Pier in Urban Transit (도시철도 교각의 시공중 균열발생 원인과 제어방안을 위한 매개변수 연구)

  • Park, Seong-Kyu
    • Journal of the Korean Society for Railway
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    • v.14 no.6
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    • pp.555-561
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    • 2011
  • This paper is designed to propose methods to both analyze and control the reasons for cracks appearing during the construction of piers. For this aim, a numerical analysis was performed to identify the properties of crack which resulted from heat of hydration and differential drying shrinkage with the key influence factors considered. The results show that the thermal cracks occurred within a few days, and the drying shrinkage cracks within a few weeks. Meanwhile, settlement shrinkage cracks occurred within a few hours. Discussing the control methods based on the time of the cracks appearing, quality control, reduction of the unit quantity of cement, and the preservation of moisture on the surface are proposed as the realistic and effective methods for preventing settlement cracks, thermal cracks, and drying shrinkage cracks respectively.

Phenol-Rich Compounds Sweet Gel: A Statistically More Effective Antibiotic than Cloxacillin Against Pseudomonas Aeruginosa

  • Dashtdar, Mehrab;Dashtdar, Mohammad Reza;Dashtdar, Babak;Khan, Gazala Afreen;Kardi, Karima
    • Journal of Pharmacopuncture
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    • v.19 no.3
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    • pp.246-252
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    • 2016
  • Objectives: The purpose of this study was to obtain a natural antibiotic from Phenol-rich compounds; for the dressing and the treatment of chronic wounds. Methods: The Phenol-rich compound sweet gel was prepared by blending four natural herbal extracts, Acacia catechu (L.F.), Momia (Shilajit), Castanea sativa, and Ephedra sinica stapf, with combination of a sweet gel medium, including honey, maple saps, Phoenix dactylifera L. (date), pomegranate extract and Azadirachta indica gum as a stabilizer. The combinations were screened by using a well-diffusion assay with cloxacillin as a control. Pseudomonas spp. was tested with our novel antimicrobial compound. The zones of inhibition in agar culture were measured for each individual component and for the compound, and the results were compared with those of the control group which had been treated with cloxacillin. Data were expressed as means ${\pm}$ standard deviations. Quantitative analyses were performed using the paired t-test. Results: The antibiotic effect of the Phenol-rich compound sweet gel was statistically shown to be more significant than that of cloxacillin against Pseudomonas aeruginosa (P < 0.05). Conclusion: Our novel approach to fighting the antibiotic resistance of Pseudomonas proved to be successful. The Phenol-rich compound sweet gel was found to be suitable for use as an alternative medicine and bioactive dressing material, for the treatment of patients with various types of wounds, including burns, venous leg ulcers, ulcers of various etiologies, leg ulcers on the feet of diabetic, unhealed graft sampling sites, abscesses, boils, surgical wounds, necrotic process, post-operative and neonatal wound infection, and should be considered as an alternative to the usual methods of cure.