• Title/Summary/Keyword: effect of operating conditions

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A Study on the Effect of Coal Properties on the Electrochemical Reactions in the Direct Carbon Fuel Cell System (석탄 물성에 따른 직접탄소 연료전지의 전기화학 반응 특성 연구)

  • Ahn, Seong-Yool;Eom, Seong-Yong;Rhie, Young-Hoon;Moon, Cheor-Eon;Sung, Yon-Mo;Choi, Gyung-Min;Kim, Duck-Jool
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.10
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    • pp.1033-1041
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    • 2012
  • Performance evaluation of a direct carbon fuel cell (DCFC) was conducted according to coals and a graphite particle. Several fuel properties such as thermal reactivity, textural structure, gas adsorption characteristic, and functional groups on the surface of fuels were investigated and their effects on electrochemistry were discussed. The strong carbon structure inside of fuels led the rapid potential decreasing in high current density region, because it caused small surface area and low pore volume. The functional groups on the surface were related to the low current density region. The maximum current density and power density of fuels were affected by the total carbon content in fuels. The effect of operating conditions such as stirring rate and operating temperature was investigated in this study.

Quantitative Evaluation of Criticality According to the Major Influence of Applied with Burnup Credit on Dual-purpose Metal Cask (국내 금속겸용용기의 연소도 이득효과 적용 시 주요영향인자에 따른 정량적 핵임계 평가)

  • Dho, Ho-seog;Kim, Tae-man;Cho, Chun-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.2
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    • pp.141-154
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    • 2015
  • In general, conventional criticality analysis for spent fuel transport/storage systems have been performed based on the assumption of fresh fuel concerning the potential uncertainties from number density calculations of actinide nuclides and fission products in spent fuel. However, these evaluation methods cause financial losses due to an excessive criticality margin. In order to overcome this disadvantage, many studies have recently been conducted to design and commercialize a transportation and storage cask applied to the Burnup Credit (BUC). This study conducted an assessment to ensure criticality safety for reactor operating parameters, axial burn-up profiles and misload accident conditions, which are the factors that are likely to affect criticality safety when the BUC is applied to the dual-purpose cask under development at the KOrea RADioactive waste agency (KORAD). As a result, it was found that criticality resulting from specific power, changed substantially and relied on conditions of low enrichment and high burn-up. Considering the end effect in the case of high burn-up produced a positive-definite result. In particular, the increment of maximum effective multiplication factors due to misloading was 0.18467, confirming that misload is a factor that must be taken into account when applying the BUC. The results of this study may therefore be utilized as references in developing technologies to apply the BUC to domestic models and operational procedures or preventing any misload accidents during the process of spent fuel loading.

Rate Expression of Fischer-Tropsch Synthesis Over Co-Mn Nanocatalyst by Response Surface Methodology (RSM)

  • Mansouri, Mohsen;Atashi, Hossein;Khalilipour, Mir Mohammad;Setareshenas, Naimeh;Shahraki, Farhad
    • Journal of the Korean Chemical Society
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    • v.57 no.6
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    • pp.769-777
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    • 2013
  • The effect of operating conditions (temperature and the partial pressures of H2 and CO) on the reaction rate of Fischer-Tropsch synthesis (FTS) were investigated by carrying out experiments according to a Box-Behnken design (BBD), and were mathematically modeled by using response surface methodology (RSM). The catalyst used was a nano-structured cobalt/manganese oxide catalyst, which was prepared by thermal decomposition. The rate of synthesis was measured in a fixed-bed micro reactor with $H_2/CO$ molar feed ratio of 0.32-3.11 and reactor pressure in the range of 3-9.33 bar at space velocity of $3600h^{-1}$ and a temperature range of 463.15-503.15 K, under differential conditions (CO conversion below 2%). The results indicated that in the present experimental setup, the temperature and the partial pressure of CO were the most significant variables affecting reaction rate. Based on statistical analysis the quadratic model of reaction rate of FTS was highly significant as p-value 0.0002.

An Experimental Study on the Improvement of Turbocharger Lag by Means of Air Injection in a Turbocharged Diesel Engine

  • Choi, Nag-Jung;Oh, Seong-Mo
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.7
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    • pp.951-962
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    • 2010
  • An experimental study was performed to investigate the improvement of response performance of a turbocharged diesel engine under the operating conditions of low speed and fast acceleration. In this study, the experiment for improving the low speed and acceleration performance is performed by means of injecting air into the intake manifold of compressor exit during the period of low speed and application of a fast acceleration from low speed. The effects of air injection into the intake manifold on the response performance were investigated at various applicant parameters such as air injection pressure, accelerating rate, accelerating time, engine speed and load. The experimental results show that air injection into the intake manifold at compressor exit is closely related to the improvement of turbocharger lag under low speed and accelerating conditions of a turbocharged diesel engine. During the rapid acceleration period, the air injection into the intake manifold of turbocharged diesel engine indicates the improvement of the combustion characteristics and gas pressure in the cylinder. At low speed range of the engine, the effect of air injection shows the improvement of the pressure distribution of turbocharger and combustion pressure during the period of gas exchange pressure.

Effect of Environmental Pre-treatment on Expression of Blister Rust Resistance in Pinus monticola (oral)

  • Woo, K.S.;Kim, Y.J.;Mcdonald, G.I.;Fins, L.
    • Proceedings of the Korean Society of Plant Pathology Conference
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    • 2003.10a
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    • pp.112.2-112
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    • 2003
  • Levels of blister rust infection (from Cronartium ribicola) varied in western white pine(Pinus monticola Dougl.) seedlings grown in two nurseries in northern Idaho. This observation suggested the potential importance of environmental components operating on the blister rust pathosystem. In an experiment designed to test the influence of environmental conditions at two nurseries, seedlings of a single genetic source were unintentionally held in cold storage for 6 months longer at one nursery than at the other. Subsequently, these seedlings, which had been growing under nursery conditions for 7 months or 1 month, were inoculated with blister rust spores on September 9th, 1999. Infection efficiency measured on the seedlings with only 1 month of growth was 70X greater than on the seedlings that had 7 months for their new growth to mature. Results from this nursery test and infection levels of northern Idaho resistant selections in mild climates suggest that expression of genes related to rust resistance in western white pine can be manipulated by regulation of phonology. If so, several new molecular tools may be employed to enhance our understanding of environmental regulation of genes for blister rust resistance.

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The Analysis of Energy Consumption for an Electric Vehicle under Various Driving Circumstance (준중형급 전기자동차의 주행특성에 따른 에너지 소모량 분석)

  • Lee, Dae-Heung;Seo, Ho-Won;Jeong, Jong-Ryeol;Park, Yeong-Il;Cha, Suk-Won
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.2
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    • pp.38-46
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    • 2012
  • This paper discusses the energy consumption for a mid-size electric vehicle(EV) under various conditions. In order to analyze which driving style is more efficient in terms of the system of the EV, we develop the electric vehicle model and apply several types of speed profiles such as different steady speeds, acceleration/deceleration, and a real world driving cycle including the elevation profile obtained from a GPS device. The results show that the energy consumption of the EV is affected by the operating efficiency of components when driving at low speed, while it depends on required power at wheels when driving at high speed. Also this paper investigates the effect of the elevation of a road and the rate of electrical braking on the energy consumption as well as the fuel economy of a conventional vehicle model under the same conditions.

Separation and Concentration of L-Phenylalanine using a Supported Liquid Membrane

  • Jeong Woo Choi;Kyu
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.3 no.1
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    • pp.24-31
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    • 1998
  • The separation and concentration of L-phenylalanine (L-Phe) using a supported liquid membrane (SLM) is investigated. A cation complex agent, di-2-ethylhexyl phosphoric acid (D2EHPA), is used as a carrier in the SLM with n-Heptane as a solvent. The reaction order and equilibrium constant in the formation reaction of L-phe-carrier complex are obtained from the extraction experiment. A mathematical model for a carrier mediated counter transport process is proposed to estimate the diffusion coefficient of L-phe-carrier complexly in the liquid membrant. Permeation experiments of L-phe using a SLM are performed under various operating conditions and optimum conditions for the transport of L-phe are obtained. Concentration of L-phe in the strip phase against its concentration is observed. Transport rate of glucose through liquid membrane is less than that of L-phe in the competitive transport of L-phe and glucose. And the existence of glucose reduced the transport rate of L-phe. The performance of separation with continuous strip phase is increased due to the dilution effect in the strip phase.

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Gas Pemeation of pure $CO_{2}$ and $N_{2}$ through plasma-Treated Polypropylene Membranes

  • Lee, Woo-Sup;Rew, Dae-Sun;Bae, Seong-Youl;Kumazawa, Hidehiro
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.65-72
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    • 1999
  • The surface of polypropylene membrane was modified by plasma treatment using Ar,$N_{2}$, $NH_{2}$ and $O_{2}$ Permeabilities for $CO_{2}$, $N_{2}$ and separation factor for $CO_{2}$ relative to $N_{2}$ were measured. The permeation experiments were performed by a variable volume method at $25^{\circ}C$ and 0.303MPa. The effects of the plasma conditions such as treatement time power input gas flow rate and pressure in the reactor on the transport properties of modified membrane were investigated. The surface of the plasma treated membrane was analyzed by means of FTIR-ATR XPS and AFM. The surface structure of the plasma treated membrane was fairly different from that of the untreated membrane. Although the permeation rates for both $CO_{2}$ and $N_{2}$ decreased with increasing plasma treatement time the separation factor was found to be improved by the plasma treatement. The operating conditions of plasma treatement imposed on membranes had notable effect on the permeability and separation factor.

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Changes in Phytochemical Stability and Food Functionality during Cooking and Processing (식품의 조리.가공 공정 중 phytochemical 및 기능성의 변화)

  • Kim, Hyun-Jung;Chun, Hyang-Sook
    • Korean journal of food and cookery science
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    • v.22 no.3 s.93
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    • pp.402-417
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    • 2006
  • Research interest on functional food and phytochemicals has mainly focused on their health effects, mechanism of action and structure-activity relationship for the development of nutraceuticals. Considering the intake of phytochemicals via the normal diet, further information is required on changes in food functionality or individual phytochemicals that occur during the cooking or processing of foods, in order to increase the intake of these bioactive compounds, because many of the unit-operating procedures involved in cooking or food processing may result in physicochemical changes of food constituents. This study reviews the changes of selected phytochemicals, i.e. flavonoids, organosulfur compounds and carotenoids, or food functionality by major cooking or processing procedures such as heating, fermentation, and pH changes. In general, heating has a negative effect on food functionality, although in some cases, mild heating increases bioactive phytochemical contents. Some phytochemicals, including anthocyanins and catechins, are stabilized in lower pH conditions. The structures of phytochemicals, including isoflavones and catechins, are changed by fermentation. The loss of bioactive compounds may be decreased by recently developed cooking or processing methods such as microwave cooking or use of high hydrostatic pressure. However, the effects of cooking and processing procedures on food functionality and phytochemicals are so diverse and dependent on test conditions that further research efforts are needed to form accurate conclusions on the effects of cooking and processing of foods.

Cause of Fatigue Failure of the First Blade of 100-MW Gas Turbine (100 MW급 가스터빈 1단 블레이드의 피로파괴 발생 원인)

  • Youn, Hee-Chul;Woo, Chang-Ki
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.6
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    • pp.632-638
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    • 2015
  • Many failures have been reported in gas turbine facilities owing to repeated startups and prolonged use of the turbines. In this study, the causes and mechanism of fatigue failure in the first blade of a gas turbine were analyzed using a finite element method to calculate the centrifugal force, bending force, and a modal analysis based on the stress-stiffening effect and harmonic response under the operating conditions. The results show that, fatigue damage was caused by the resonance conditions encountered, in which the first natural frequency declined along with an increase in the metal temperature of the blade. The position of the expected fatigue damage was shown to match the actual position of the cracking at the root area of the blade, which was on the concave side. In addition, the equivalence fatigue stress was observed to approach the fatigue limit.