• 한국농촌건축학회논문집
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• 제21권2호
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• pp.35-42
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• 2019

There are 17,427 reservoirs in Korea, of which about 96% were built before the mid 1980s. Therefore, aging is severe and reinforcement are necessary. In addition, aged reservoirs, which are more than 50 years old, account for 70% of the total. Therefore, there is a problem such as the collapse of the reservoir and the decrease of the storage capacity due to progress of aging with time. The grouting method using cement is mainly used as maintenance and reinforcement method of old reservoir. However, the grouting method using cement has engineering and environmental problems. In order to solve the engineering and environmental problems of cement grouting method, an eco-friendly grouting material was developed that mixes circular resource grouting binder, high molar ratio sodium silicate and colloidal silica. The engineering and environmental properties of the developed injection materials were evaluated by conducting gel time, homo-gel strength, sea water resistance test and environmental stability evaluation. Also, examined the possibility of replacing OPC existing aged reservoir reinforcement methods. As a result, it was found out that it was better than the conventional cement method in terms of engineering and environment. However, since this study is the result of laboratory test, it is necessary of verify the application at field of aged reservoir.

• 자원리싸이클링
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• 제25권4호
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• pp.23-31
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• 2016

양양철광산 선광 부산물(폐석, 광미)의 폐기물공정시험기준에 의한 중금속용출량은 환경기준값 보다 낮아 유해성이 없으므로 그 자체를 물질전환법에 의해 순환자원화 하는 데는 문제가 없다. 선광 광미를 시멘트 부원료로 사용할 경우에는 시멘트 품질안정성 차원에서 전 알카리($R_2O$)함량이 포틀랜드 시멘트(KS L 5201) 품질 기준치인 0.6%를 초과하지 않도록 광미 첨가량을 3%이하로 사용하는 것이 좋다고 판단된다. 재활용 점토벽돌(KS I 3013) 1종 규격에 부합되는 비소성 에코벽돌은 무기결합제의 15%를 광미로 그리고 일반잔골재의 100%를 철광산 폐석으로 대체하여 제조 가능하였다. 이처럼 선광 부산물을 시멘트 부원료 및 비소성 에코벽돌로 순환자원화함으로서 광미 적치장의 축소 및 유지관리비용 절감 그리고 에너지 사용 및 $CO_2$ 발생 절감으로 환경적 효과 및 경제적 효과를 동시에 얻을 수 있을 것이다.

• 한국농공학회논문집
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• 제55권2호
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• pp.59-64
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• 2013

The present study is to evaluate physical and mechanical properties of porous concrete having non cement that mainly causes carbon emission. This study aims to explore eco-friendly concrete technology capable of reducing the amount of carbon emission due to the use of normal cement by substituting it with non cement porous concrete to which alkali-activator and blast-furnace slag powder are impregnated. As experimental variables, 5 %, 6 %, 7 %, 8 %, 9 % and 10 % of alkali-activator were substituted as binders and applied. Testing evaluated in this study were pH value, void ratio, compressive strength and residual compressive strength shown after being immersed in $H_2SO_4$ solution and $Na_2SO_4$ solution. The test results were compared with those tested with the use of porous concrete to which 400 $kg/m^3$ of unit cement amount was applied as binder. In consequence, it was concluded that; as for pH value, it was decreased than was the case in which cement was used, but increased with the more the use of alkali activator; as for void ratio and compressive strength, the mix proportion in which 9 % and 10 % of alkali activator were applied in terms of substitution ratio showed the result similar to the mixture in which 400 $kg/m^3$ of unit cement ratio was applied; and, as for residual compressive strength in the case of being immersed in $H_2SO_4$ solution and $Na_2SO_4$ solution, the compressive strength was increased, thus leading to improved chemical resistance.

• 한국건축시공학회지
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• 제22권1호
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• pp.35-43
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• 2022

High Sulfated Calcium Silicate cement(HSCSC) 콘크리트의 성능을 보통포틀랜드시멘트(OPC), 고로슬래그시멘트(S/C)와 비교 검토하고자 하였다. 콘크리트 압축강도 실험결과 초기 3일 재령에서의 High Sulfated Calcium Silicate cement 콘크리트 압축강도 발현율이 보통포틀랜드시멘트 콘크리트의 73.6% 수준으로 다소 적게 확인되었으나, 28일 재령에서 High Sulfated Calcium Silicate cement의 강도 발현율이 상승하여 보통포틀랜드시멘트 대비 약 107.0% 수준으로 소폭 상승하는 것을 확인할 수 있었다. 또한, 콘크리트의 염소이온침투저항성 실험결과 재령 28일의 경우 보통포틀랜드시멘트 대비 고로슬래그시멘트, High Sulfated Calcium Silicate cement 순서로 각각 73.4%, 93.0% 감소하였으며, 재령 56일의 경우 79.1%, 98.3% 감소하여, 우수한 염소이온 침투 저항성능을 확인하였다. 특이사항으로는 보통포틀랜드시멘트, 고로슬래그시멘트 보다 High Sulfated Calcium Silicate cement의 재령 경과에 따른 통과 전하량 감소율이 더 높은 것을 확인할 수 있었다.

• 한국재료학회지
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• 제20권1호
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• pp.1-6
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• 2010

Geopolymer materials are attractive as inorganic binders due to their superior mechanical and eco-friendly properties. In the current study, geopolymer-based cement was prepared using aluminosilicate minerals from fly-ash with KOH as an alkaline-activator and $Na_2SiO_3$ as liquid glass. Then, calcium carbonate powder from a clam shell was mixed with the geopolymer and the mixture was coated on a concrete surface to provide points of attachment for environmental organisms to grow on the geopolymers. We investigated the effect of the shell powder grain size on the microstructure and bonding property of the geopolymers. A homogeneous geopolymer layer coated well on the concrete surface via aluminosilicate bonding, but the adhesiveness of the shell powder on the geopolymer cement was dependent on the grain size of the shell powder. Superior adhesive characteristics were shown in the shell powder of large grain size due to the deep penetration into the geopolymer by their large weight. This kind of coating can be applied to the adhesiveness of eco-materials on the surface of seaside or riverside blocks.

• 자원리싸이클링
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• 제26권6호
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• pp.50-57
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• 2017

본 연구에서는 몽골 플라이애시의 기초물성 및 분쇄과정을 통한 시멘트 혼화재로의 사용가능성을 검토하였다. 몽골 플라이애시는 국내 플라이애시 보다 입자가 컸으며, 구형 입자도 적게 관찰되었다. 몽골 플라이애시의 CaO 함량은 높았으며, 이외 성분은 비슷한 수준이었다. 진동밀 분쇄 후 플라이애시는 $7.9{\mu}m$까지 작아졌으며, 분말도도 증가하였다. 분쇄 플라이애시를 시멘트와 혼합할 경우, 60분 분쇄시 가장 우수한 압축강도 값을 나타내었다. 또한 이들 강도값은 모든 재령에서 OPC 보다도 높은 수준이었다.

• 한국건축시공학회지
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• 제18권2호
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• pp.109-115
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• 2018

본 연구에서는 시멘트 생산에 의한 $CO_2$ 배출과 이로 인한 환경 부하를 감소시키기 위해 산업부산물인 고로슬래그 미분말을 활용하여 기존 SCW 공법에 사용되던 시멘트주입재를 친환경 무기결합재로 대체하여 모르타르를 제작하고 친환경 밀크주입재로써 적용이 가능한지를 파악하였다. 본 연구 결과 포틀랜드 시멘트를 사용하지 않은 비소성 시멘트를 이용한 NSB 경화체가 보통 포틀랜드 시멘트 경화체와 비교해 내산성, 내해수성, 압축강도 등이 우수한 것으로 나타나고 있다. 따라서 본 연구를 통해 만들어진 친환경 무기결합재 모르타르는 높은 내구성, 내화학성을 요구하는 SCW 공법과 같은 흙막이벽, 해양하부구조물 등의 지반재료용 결합재에 적용이 가능하다는 것을 알 수 있었다.

• 한국건설순환자원학회논문집
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• 제6권1호
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• pp.80-87
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• 2011

본 연구는 콘크리트에 사용되는 시멘트를 대체할 수 있는 혼화재에 관한 것으로 산업부산물인 고로슬래그 미분말 및 석회석 미분말 등을 결합재로 하여 일반 포틀랜드시멘트에 비하여 이산화탄소 배출량이 적은 결합재이다. 또한 기존 고로슬래그 미분말의 보통 포틀랜드 시멘트 치환시 발생되는 초기강도 저하현상 및 한랭기 및 동절기 저온 환경에서 발생하는 강도 저하 현상을 개선한 탄소배출 저감형 결합재이다. 보통포틀랜드 시멘트와 비교하여 양생 재령에 상관없이 동등 이상의 강도 발현이 가능하므로 계절별 기후에 상관없이 현장에 적용할 수 있으며, 경제성 측면에서도 보통포틀랜드시멘트보다 저렴하여 이점이 있다. 또한 이산화탄소 배출량을 비교하였을 때 EM은 보통포틀랜드시멘트에 비하여 약 38%, EM를 사용한 콘크리트의 경우 약 8%의 저감효과가 있는 것으로 확인되었다.

• Geomechanics and Engineering
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• 제25권1호
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• pp.41-48
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• 2021

In cold regions, the integrity of the infrastructures built on weak soils can be extensively damaged by weathering actions due to the cyclic freezing and thawing. This damage can be mitigated by exploiting soil stabilization techniques. Generally, ordinary Portland cement (OPC) is the most commonly used binding material for investigating the chemo-hydromechanical behavior. However, due to the environmental issue of OPC producing a significant amount of carbon dioxide emission, calcium sulfoaluminate (CSA) cement can be used as one of the eco-sustainable alternatives. Although recently several studies have examined the strength development of CSA treated sand, no research has been concerned about CSA cement-stabilized sand affected by cyclic freeze and thaw. This study aims to conduct a comprehensive laboratory work to assess the effect of the cyclic freeze-thaw action on strength and durability of CSA cement-treated sand. For this purpose, unconfined compressive strength (UCS) and ultrasonic pulse velocity (UPV) tests were performed on the stabilized soil specimens cured for 7 and 14 days which are subjected to 0, 1, 3, 5, and 7 freeze-thaw cycles. The test results show that the strength and durability index of the samples decrease with the increase of the freeze-thaw cycles. The loss of the strength and durability considerably decreases for all soil samples subjected to the freeze-thaw cycles. Overall, the use of CSA as a stabilizer for sandy soils would be an eco-friendly option to achieve sufficient strength and durability against the freeze-thaw action in cold regions.

• Geomechanics and Engineering
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• 제31권4호
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• pp.409-422
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• 2022

The use of calcium sulfoaluminate (CSA) cement as a rapid-hardening cement admixture or eco-friendly alternate for ordinary Portland cement (OPC) has been attempted over the years, but the cost of CSA cement and availability of suitable aluminium resource prevent its wide practical application. To propose an effective ground improvement design in sandy soil, this study aims at blending a certain percentage of CSA with OPC to find an optimum blend that would have fast-setting behavior with a lower carbon footprint than OPC without compromising the mechanical properties of the cemented sand. Compared to the 100% CSA case, initial speed of strength development of blended cement is relatively low as it is mixed with OPC. It is found that 80% OPC and 20% CSA blend has low initial strength but eventually produces equivalent ultimate strength (28 days curing) to that of CSA treated sand. The specific OPC-CSA blend (80:20) exhibits significantly higher strength gain than using pure OPC, thus allowing effective geotechnical designs for sustainable and controlled ground improvement. Further parametric studies were conducted for the blended cement under various curing conditions, cement contents, and curing times. Wet-cured cement treated sand had 33% lower strength than that of dry-cured samples, while the stiffness of wet-cured samples was 25% lower than that of dry-cured samples.