• 한국진공학회지
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• 제8권1호
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• pp.43-50
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• 1999

이온빔보조증착법으로 h-BN을 증착하여 이온에너지 및 기판온도에 따른 hexagonal ring의 배열 및 결정성의 변화를 연구하였다. 보론은 전자빔으로 1.5 $\AA$/sec 의 속도로 증발시켰으며, 질소는 둥-hall 형 이온건으로 60, 80, 100eV의 에너지로 공급하였다. 기판의 온도는 상온(no heating), 200, 400, 500, $800^{\circ}C$로 변화시켰다. 질소이온에너지가 증가할수록 hexagonal ring의 c축은 기판에 평행하게 배열하여 100 eV의 질소이온에너지에서 가장 좋은 배열을 나타내었다. 이는 이온에너지가 높을수록 합성 막에 큰 압축응력이 발생하기 때문으로 생각된다. 기판온도에 따라서는 온도가 증가함에 따라 배열이 증가하다가 약 $400^{\circ}C$에서 최대가 되고 그 보다 높은 온도에서는 배열이 감소하였다. 그리고 결정도는 온도가 증가할수록 향상되었다. 이러한 경향들은 온도가 증가함에 따라 원자 이동도는 증가하고 응력발생은 어려워지는 경향으로부터 잘 설명된다. 또한 nano-indentor로 측정한 h-BN막의 경도는 c-축의 배열정도와 같은 경향을 보였다. 이온빔보조증착법은 hexagonal ring의 배열을 통해 h-BN막 성질의 최적화에 효과적인 방법으로 판단된다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 A
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• pp.46-48
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• 1999

This paper treated the design and characteristics of high speed motor/generator with ring wound stator for the flywheel energy storage system. The most important advantages of the ring-wound motor is the slotless stator, i.e. no cogging torque, no space harmonic of air-gap flux density, etc. Because of these advantages, ring wound type motor is suitable to operate at the high speed.

• Bulletin of the Korean Chemical Society
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• 제25권9호
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• pp.1392-1396
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• 2004

The micellization of dodecylpyridinum chloride (DPC) assembled on aqueous gold nanoparticles has been studied as a function of concentration using Surface-Enhanced Raman Scattering (SERS). At the low concentration, the strong SERS band of the benzene ring moiety was observed at 1025 $cm^{-1}$, and assigned to “trigonal ring breathing”. According to high concentration of DPC, a new strong band was also appeared at 1012 $cm^{-1}$, which was assigned to “totally symmetry ring breathing”. The difference of two spectra seems to ascribe to the geometry of polar head group, i.e., pyridinium cation. These geometry exist flat-down at low concentration, whereas standing-up or tilted geometry at high concentration. The critical micelle concentration (CMC) was first obtained from the ratio of intensities of the two bands related to the benzene ring moiety by vibrational spectroscopy, and was about 28 mM. After the CMC, the benzene ring moiety in the micelle state was more restricted than in monomer state because there is no more change of intensities at 1012 $cm^{-1}$. In addition, the size of gold-assembled micelle was estimated using light scattering and it was about 328.3 nm.

• 소성∙가공
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• 제24권3호
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• pp.161-166
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• 2015

The finite element method has been widely used in the analysis of ring rolling. For ring rolling it requires a high computational expense due to the non-steady state material flow characteristics of the process. The high computational expense causes the finite element analysis to be impractical for industrial applications. In the current study, we aim to develop a practical implicit finite element modeling method for ring rolling. This method uses a step-wise steady state assumption and is called the “Stepped method”. The stepped method divides the whole process time of unsteady-state flow model into a finite number of steady-state models. It then solves the process at several specific time steps until convergence is reached. In order to confirm the performance and validity of the newly proposed stepped method, the result from the stepped method were compared to the results from a Lagrangian finite element method and to results from experiments reported in the literature.

• 대한수학회논문집
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• 제34권1호
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• pp.43-54
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• 2019

Let R be a ring with identity and J(R) denote the Jacobson radical of R, i.e., the intersection of all maximal left ideals of R. A ring R is called J-symmetric if for any $a,b,c{\in}R$, abc = 0 implies $bac{\in}J(R)$. We prove that some results of symmetric rings can be extended to the J-symmetric rings for this general setting. We give many characterizations of such rings. We show that the class of J-symmetric rings lies strictly between the class of symmetric rings and the class of directly finite rings.

• 대한수학회지
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• 제51권3호
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• pp.463-472
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• 2014

Let R be a ring with identity 1, I(R) be the set of all nonunit idempotents in R and $S_{\ell}$(R) (resp. $S_r$(R)) be the set of all left (resp. right) semicentral idempotents in R. In this paper, the following are investigated: (1) $e{\in}S_{\ell}(R)$ (resp. $e{\in}S_r(R)$) if and only if re=ere (resp. er=ere) for all nilpotent elements $r{\in}R$ if and only if $fe{\in}I(R)$ (resp. $ef{\in}I(R)$) for all $f{\in}I(R)$ if and only if fe=efe (resp. ef=efe) for all $f{\in}I(R)$ if and only if fe=efe (resp. ef=efe) for all $f{\in}I(R)$ which are isomorphic to e if and only if $(fe)^n=(efe)^n$ (resp. $(ef)^n=(efe)^n$) for all $f{\in}I(R)$ which are isomorphic to e where n is some positive integer; (2) For a ring R having a complete set of centrally primitive idempotents, every nonzero left (resp. right) semicentral idempotent is a finite sum of orthogonal left (resp. right) semicentral primitive idempotents, and eRe has also a complete set of primitive idempotents for any $0{\neq}e{\in}S_{\ell}(R)$ (resp. 0$0{\neq}e{\in}S_r(R)$).

• East Asian mathematical journal
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• 제16권1호
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• pp.111-123
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• 2000

Northcott and McKerrow proved that if R is a left noetherian ring and E is an injective left R-module, then $E[x^{-1}]$ is an injective left R[xl-module. Park generalize Northcott and McKerrow's result so that if R is a left noetherian ring and E is an injective left R-module, then $E[x^{-S}]$ is an injective left $R[x^s]$-module, where S is a submonoid of N(N is the set of all natural numbers). In this paper we show $$Hom_{R[x^S]}(M[x^{-S}],\;N[x^{-S}]){\cong}Hom_R(M,\;N)[[x^S]]$$ and using the above result and this isomorphism, finally we show that $$Ext^i_{R[x^S]}(M[x^{-S}],\;N[x^{-S}]){\cong}Ext^i_R(M,\;N)[[x^S]]$$.

• Bulletin of the Korean Chemical Society
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• 제23권9호
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• pp.1309-1338
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• 2002

The fluorescence and photoisomerization quantum yields of trans-1-(9-anthryl)-2-(4-pyridyl)ethene (t-4-APyE), 1-(10-methyl-9-anthryl)-2-(4-pyridyl)ethene (t-4-MeAPyE), and 1-(10-chloro-9-anthryl)-2-(4- pyridyl)ethene (t-4-ClAPyE) were measured in cyclohexane, acetonitrile, and methanol at room temperature.Polar solvents result in the drastic reduction of fluorescence quantum yield and increase of photoisomerization quantum yield for all three compounds. These results are probably due to the stabilization of intramolecular charge transfer (ICT) excited state in polar solvent. The higher contribution of ICT in the presence of more electron-donating methyl substituent, manifested by largest positive fluorescence solvatochromism, indicates that the pyridine ring acts as an electron acceptor. Protonation or methylation makes pyridine ring stronger electron acceptor and causes long-wavelength ground state charge transfer absorption band and complete quenching of fluorescence. The fluorescence from t-4-APyE derivatives can be switched off responding external stimuli viz. medium polarity, protonation, or methylation.

• 한국염색가공학회지
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• 제6권1호
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• pp.28-32
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• 1994

The synthesis and absorption spectra of squarvlium(SQ) dyes and croconium(CR) dyes were .studied. Absorption spectra of SQ dye in various solvents exhibited a negative solvatochrornism. Thus, it was suggested that the structure of SQ dye may be a highly polar structure. The λ$_{max}$ of CR dyes undergoes a bathochromic shift of about 100nm compared with the corresponding SQ dyes. This shift can be calculated by the Pariser-Parr-Pople molecular orbital method. From the PPP MO calculation results, we found that SQ dye and CR dye have a almost same Highest Occupied Molecular Orbital(HOMO) level(SQ : -8.0eV, CR : -8.09eV). On the other hand, energy levels of Lowest Unoccupied Molecular Orbital(LUMO) of SQ and CR dyes are -4.09eV and -4.13eV respectively. Thus, replacement of five membered ring by four membered ring in SQ dye causes a large bathochromic shift.t.

• Journal of Photoscience
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• 제7권2호
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• pp.67-71
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• 2000

A quantum-chemical investigation on the conformations and electronic properties of trans(diphenyl-diheterocyclic) ethenes(t-PHEs) as building block for fully $\pi$-conjuated polymer are performed in order to display the effects of heterocyclic ring substitution. Structures for the molecules, t-PHEs were fully optimized by using semiempirical AM1, PM3 methods, and ab initio HF methods, with 6-31G basic set. The potential energy curves with respect to the change of single are obtained by using ab initio HF/6-31G basic set. The curves are not similar shapes in the molecules with respect to heterocyclic rings. It is shown that the steric repulsion interactions between phenyl ring and heterocyclic ring are subjected to different type with the respect to each heterocyclic ring. Electronic properties of the molecules were molecules were obtained by applying the optimized structures and selected geometries to the extended Huckel method. To investigate the change of HOMO-LUMO gap with respedt to the torsion angle, we select the optimized structures. By using the results, the dependency of conjugation for the energy gaps is analyzed. For t-PHE the energy gap increase up to 0.52 eV compared with its planar structure. In the cases of t-PHE and t-PHE, the energy gap increase by 1.29 and 1.15 eV, respectively, compared with its planar structure.