• Corrosion Science and Technology
• /
• 제21권1호
• /
• pp.21-31
• /
• 2022

Potentiodynamic polarization, EIS measurements, quantum chemical calculations, and molecular dynamic simulations were used to investigate the corrosion behavior of mild steel in 0.5 M aqueous hydrochloric acid medium in the presence or absence of nystatin drug. Potentiodynamic tests suggested that this molecule could act as a mixed inhibitor due to its adsorption on the mild steel surface. The objective of this study was to exploit theoretical calculations to gain a better understanding mechanism of inhibition. Calculating the adsorption behavior of the investigated molecule on Fe (1 1 0) surface was accomplished using Monte Carlo simulation. Molecules were also investigated using Density Functional Theory (DFT), specifically PBE functional, in order to identify the link between molecular structure and corrosion inhibition behavior of the compound under investigation. Adsorption energies between nystatin and iron were estimated more accurately by utilizing Molecular Mechanics calculation with Periodic Boundary Conditions (PBC). Estimated theoretical parameters significantly assisted our understanding of the corrosion inhibition mechanism exhibited by this molecule. They were found to be in accord with experimental results.

• 한국산림과학회지
• /
• 제90권6호
• /
• pp.725-733
• /
• 2001

본 연구에서는 안면도 소나무 임지에 대해 임분 내 생장인자들간의 상관관계를 구명하고 이를 기초로 동적 임분생장모델을 구축하였다. 이를 위해 영급이 고루 분포되도록 96개의 표본점을 선정하였고, 각 표본점에서 입목의 흉고직경, 수고를 측정한 후 이를 분석하여 평균흉고직경, 평균수고, 우세목수고, ha당 본수, ha당 단면적, ha당 재적 등을 추정하였다. SAS의 비선형 회귀분석(NLIN) 및 단순선형분석(REG)을 통해 생장인자간의 함수식을 유도하였으며, 이 함수들을 이용하여 관리방법에 따라 임분의 생장 및 수확이 다양하게 예측될 수 있는 동적 임분생장모델을 구축하였다. 다양한 시업주기 및 강도를 적용해 임분의 생장을 예측한 결과, 본 연구에서 구축된 동적 임분생장모델은 일반적인 생장법칙을 잘 나타내고 있어 안면도 소나무임분의 생장 및 수확량 예측에 적합한 것으로 판단되었다. 이러한 동적 임분생장모델은 실제 산림경영에서 다양한 관리방법에 따른 임분의 생장예측을 위하여 이용될 수 있을 것이며, 산림경영계획에 있어 의사결정을 위한 도구로서 이용될 수 있을 것이다.

• 한국식품영양학회지
• /
• 제17권2호
• /
• pp.220-228
• /
• 2004

Tenax-TA와 동적 headspace 향 포집방법을 이용하여 볶음들기름의 향기성분을 농축하였다. 이때 반응표면분석법을 이용하여 Tenax-TA에 결합한 향기성분의 탈착에 의한 손실을 최소화하고 휘발성이 낮은 화합물의 포집 효율을 극대화시키는 최적조건을 결정하였다. 독립변수로 향 포집 온도와 시간 및 시료량을 설정하였고 총 peak 면적, 탈착율, 휘발성이 가장 낮은 화합물인 perilla ketone의 면적을 종속변수로 하였다. 등고선 그림을 겹친 결과 0.6 g의 볶음들기름을 48$^{\circ}C$에서 12분 동안 포집시키는 것이 최적조건이었으며 Tenax-TA에서 탈착되는 주요한 휘발성 화합물은 2-propanone, 2-butanone, acetic acid 및 2-methyl propanal이었다.

• 대한조선학회논문집
• /
• 제53권2호
• /
• pp.135-143
• /
• 2016

In this study, an embedded system composed of equipment setting, block importing, scenario setting and output reporting is developed in multi-body dynamics program, ADAMS, for conducting dynamic structural analysis of block lifting process. First, equipment used for block lifting process is set in the simulation environment and the shapes and functions of two lifting beams, and six block loaders are provided as the equipment. Second, the modal analysis result of the lifting block is imported from the static structural analysis system, NASTRAN. Third, the lifting scenarios, such as hoisting, waiting, trolley moving, and wire connecting, are set in the system. Finally, output results in the forms of plots, texts and tables, are reported after the dynamic structural analysis. The test examples conducted in a shipyard are applied into the developed system in various condition and scenarios. The loads at the lug points, the stress contours, and the hot spot tables of the developed system are compared with the result of the static analysis system.

• Food Science and Biotechnology
• /
• 제15권1호
• /
• pp.33-38
• /
• 2006

This study was performed to provide basic rheological data of dandelion root concentrates in order to predict their processing aptitude and usefulness as functional foods material. The hot water and 70% ethanol extracts of dandelion root were concentrated at 5, 20, and 50 Brix, and their static viscosity, dynamic viscosity, and Arrhenius plots were investigated. Almost all hot water concentrates showed the typical flow properties of a pseudoplastic fluid, but evaluation using the power law model indicated that the 70% ethanol concentrates showed a flow behavior close to a Newtonian fluid. The apparent viscosity of hot water and 70% ethanol concentrates decreased with increasing temperature. Yield stresses of hot water and 70% ethanol concentrates by Herschel-Bulkley model application were in the range of 0.026 - 1.368 Pa and 0.022 - 0.238 Pa, respectively. The effect of temperature and concentration on the apparent viscosity was examined by Arrhenius equation. The activation energies of hot water and 70% ethanol concentrates were in the range of $8.762-23.778{\times}10^3\;J/mol{\cdot}kg$ and $3.217-20.384{\times}10^3\;J/mol{\cdot}kg$ with increasing concentration, respectively. Storage (G') and loss (G") moduli were generally increased with increasing frequency. For the 70% ethanol concentrates, G" predominated over G' at all applied frequencies and so they showed the typical flow behavior of a low molecular solution. However, for the hot water concentrates, G' predominated over G" at more than 1.9 rad/sec (cross-over point) and so they showed the typical flow behavior of a macromolecular solution.

• Journal of Biosystems Engineering
• /
• 제41권4호
• /
• pp.342-356
• /
• 2016

Purpose: The drying of a thin layer of native cassava starch in a tray dryer was modeled to establish an equation for predicting the drying behavior under given conditions. Methods: Drying tests were performed using samples of native cassava starch over a temperature range of $40-60^{\circ}C$. We investigated the variation in the drying time, dynamic equilibrium moisture content, drying rate period, critical moisture content, and effective diffusivity of the starch with temperature. The starch diffusion coefficient and drying activation energy were determined. A modification of the model developed by Hii et al. was devised and tested alongside fourteen other models. Results: For starch with an initial moisture content of 82% (db), the drying time and dynamic equilibrium moisture content decreased as the temperature increased. The constant drying rate phase preceded the falling rate phase between $40-55^{\circ}C$. Drying at $60^{\circ}C$ occurred only in the falling rate phase. The critical moisture content was observed in the $40-55^{\circ}C$ range and increased with the temperature. The effective diffusivity of the starch increased as the drying temperature increased from 40 to $60^{\circ}C$. The modified Hii et al. model produced randomized residual plots, the highest $R^2$, and the lowest standard error of estimates. Conclusions: Drying time decreased linearly with an increase in the temperature, while the decrease in the moisture content was linear between $40-55^{\circ}C$. The constant drying rate phase occurred without any period of induction over a temperature range of $40-55^{\circ}C$ prior to the falling rate period, while drying at $60^{\circ}C$ took place only in the falling rate phase. The effective diffusivity had an Arrhenius relationship with the temperature. The modified Hii et al. model proved to be optimum for predicting the drying behavior of the starch in the tray dryer.

• Journal of Photoscience
• /
• 제11권1호
• /
• pp.11-17
• /
• 2004

Fluorescence quenching of l,4-bis [2-(2-methylphenyl) ethenyl]-benzene (Bis-MSB) by carbon tetrachloride in five different solvents namely hexane, cyclohexane, toluene, benzene and dioxane has been carried out at room temperature with a view to understand the quenching mechanisms. The Stern-Volmer plot has been found to be non-linear with a positive deviation for all the solvents studied. In order to interpret these results we have invoked the Ground state complex and Sphere of action static quenching models. Using these models various rate parameters have been determined. The magnitudes of these parameters imply that sphere of action static quenching model agrees well with the experimental results. Hence the positive deviation in the Stem-Volmer plots is attributed to the static and dynamic quenching. Further, with the use of Finite Sink approximation model, it was possible to check whether these bimolecular reactions as diffusion limited and to estimate independently distance parameter R' and mutual diffusion coefficient D. Finally an effort has been made to correlate the values of R'and D with the values of the encounter distance R and the mutual diffusion coefficient D determined using the Edwardis empirical relation and Stokes-Einstein relation.

• 조명전기설비학회논문지
• /
• 제19권6호
• /
• pp.100-108
• /
• 2005

본 논문은 제주-해남 HVDC 시스템의 주파수 제어를 다루었다. 논문의 주된 목적은 현재 사용되고 있는 동기조상기로부터의 주파수 입력원을 배제한 새로운 주파수 제어시스템을 개발하여 대체를 검증하는 것이다. 과도상태의 검토는 PSCAD/EMTDC를 이용하여 상세 모델링으로 구현하였으며, 개발된 HVDC 모델을 통하여 동기조상기의 운전정지와 계통변화에 대한 사고를 검토하였다. 결론적으로 본 논문에서는 모의실험을 통하여 현재의 동기조상기로부터 HVDC 주파수 신호원을 검출하는 것에 비하여 새로운 주파수 제어 알고리즘을 적용한 154[kV] 모선으로 변경이 제주 AC 계통의 변화에 좀더 능동적으로 대처할 수 있음을 확인하였다.

• International Journal of Automotive Technology
• /
• 제8권6호
• /
• pp.745-752
• /
• 2007

In this study, the effects of flexible bodies in vehicle suspension components were investigated to enhance the accuracy of multibody dynamic simulation results. Front and rear suspension components were investigated. Subframes, a stabilizer bar, a tie rod, a front lower control arm, a front knuckle, and front struts were selected. Reverse engineering techniques were used to construct a virtual vehicle model. Hard points and inertia data of the components were measured with surface scanning equipment. The mechanical characteristics of bushings and dampers were obtained from experiments. Reaction forces calculated from the multibody dynamics simulations were compared with test results at the ball joint of the lower control arm in both time-history and range-pair counting plots. Simulation results showed that the flexibility of the strut component had considerable influence on the lateral reaction force. Among the suspension components, the flexibility of the sub-frame, steering knuckle and upper strut resulted in better correlations with test results while the other flexible bodies could be neglected.

• 전력전자학회논문지
• /
• 제10권5호
• /
• pp.457-467
• /
• 2005

본 논문은 해남에서 제주로 연결되어 운전중인 HVDC 시스템의 새로운 주파수 제어기에 대하여 연구하였다. 연구의 첫 번째 목적은 현재의 동기조상기를 제거하기 위하여 새로운 주파수 제어기를 개발하고, 평가를 수행하는 것이다. 모의실험 케이스를 만들기 위하여 PSCAD/EMTDC와 PSS/E를 혼합하여 사용하였고 주 시스템 연구는 과도상태 분석을 위하여 PSCAD/EMTDC을 사용하였다. 연구 케이스는 3상과 1상 지락 그리고 부하탈락에 대한 사고를 모의하였고 연구결과를 나타내었다. 결론적으로 AC 네트워크로부터 검출되는 새로운 주파수 측정 방법은 유효한 주파수 제어와 동적 성능을 나타냄을 알 수 있었다.