• Title/Summary/Keyword: dye solution

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Dye Penetration into Xylem of Pinus koraiensis and Larix leptolepis by Transpiration Method (증산법에 의한 잣나무와 일본잎갈나무의 목부내 염료침투)

  • 전수경
    • Journal of the Korea Furniture Society
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    • v.12 no.1
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    • pp.1-9
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    • 2001
  • This study was carried out to elucidate the relationship between wood anatomy and the water flow path in P. koraiensis and L. leptolepis. through the experiment of penetration of the dye solution. The experiment was performed by permeating 1% acid, alkali and direct solution into the xylem just after being cut. The results obtained were summarized as follows : 1. In P. koraiensis and L. leptolepis, the dye solution penetrated into sapwood and annual rings adjacent to cambial zone were only dyed according to ascent of tree height. 2. The penetrability of latewood was better than that of earlywood. 3. In P. koraiensis and L. leptolepis, the main water flow path in longitudinal direction was the trachied and that in transverse direction was ray trachied and ray parenchyma. Also, the dye solution was found in resin canal. 4. P. koraiensis was more permeable than L. leptolepis. 5. Among the acid, alkali and direct dye solution, the acid dye solution was the most permeable.

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Physical Property and Optimal Operating Condition in the Salting-out Dye Crystallization System (염료·염석결정화계에서 물성과 최적조업조건)

  • Pyun, Yu Ri;Han, Hyun Kak;Jung, Hyong Ki
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.157-162
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    • 2009
  • In this paper, the density, viscosity and solubility are measured to know the physical properties of dye. By changing the concentration of dye solution, the density change of the dye solution was very small and the viscosity of the dye solution was increased. Also, by changing the temperature of dye solution, the density change of the dye solution was increased but the viscosity of the dye solution was decreased. Solubility of dye conducts under the changing the salt and concentration of dye. In 20 wt% of dye and 15 wt% KCl, the amount of dye crystal is maximal. Also, batch salting-out experiments were performed with various conditions to know the optimal operating conditions of dye crystal. Under the various experiments, optimal operating condition was found based on amount of dye; added 15 wt% KCl, $25^{\circ}C$ temperature, 100 RPM, added at once.

Treatment of organic dye solutions by electrodialysis

  • Majewska-Nowak, Katarzyna M.
    • Membrane and Water Treatment
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    • v.4 no.3
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    • pp.203-214
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    • 2013
  • Laboratory tests were performed to determine the efficiency of dye solution desalination by electrodialysis. The study involved anionic dye and mineral salt recovery by obtaining two streams from a salt and dye mixture - dye-rich solution and salt solution. A standard anion-exchange and cation-exchange membranes or monovalent selective anion-exchange membranes were used in the ED stack. It was found that the separation efficiency was strongly dependent on the dye molecular weight. The best results for standard ion-exchange membranes were achieved for the desalination of Direct Black solution. Furthermore, the obtained results implied that the application of monovalent selective anion-exchange membranes improved the recovery of dye and salt solutions - the dye concentration in the diluate remained constant irrespective of the molecular weight of anionic dyes, whereas the salt recovery remained very high (99.5%).

The Effect of Acetophenone on the Dyeing of Silk (견섬유의 염색에 있어서 아세토페논의 영향)

  • 김태경;임용진;박태수
    • Textile Coloration and Finishing
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    • v.10 no.5
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    • pp.56-62
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    • 1998
  • In the prior study, the dyeing behaviors of Milling Cyanine 5R on silk fiber in aqueous dyeing liquor including small amount of organic compounds were investigated. The most effective compound was acetophenone which increased dye uptake as well as dyeing rate. In this study, the role of the acetophenone in dyeing of silk with Milling Cyanine 5R was studied. By addition of acetophenone into the dye solution, the molar absorptivity of Milling Cyanine 5R increased, and the wavelength of maximum absorption was shifted to longer wavelength, namely bathochromic shifted. This shows that the acetophenone prevents the dye to aggregate, and increases the number of monomeric dye molecule relative to the dye solution without acetophenone. This fact was also confirmed by the increase of the permeation rate of the dye through cellulose semipermeable membrane from the dye solution including the acetophenone. From these results, the acetophenone acts as a prohibitor of dye aggregation, increases the number of monomeric dye molecules even at relatively low temperature, and makes the dyes penetrate into the fiber easier.

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Decoloration in Dyebath by Dye Absorption of Chitin(Part I) (키틴의 염료 흡착에 의한 염액의 색소제거에 관한 연구(제1보))

  • 유혜자;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.3
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    • pp.385-392
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    • 2000
  • The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous HCI solution and deproteination in dilute aqueous NaOH solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chitin were measured in varieties of dye concentration and dipping periods. Four kinds of dyestuffs were used, C.I.Acid Blue 29. C.I.Direct Blue 6, C.I.Reactive Orange 12 and C.I.Basic Red 18. When chtin 1g was dipped in 0.05% of dyebath with stirring, maximum adsorption ratio of each kind of dyes was exhibited as 91.6% for C.I.Acid Blue 29, 95% for C.I.Direct Blue 6, 58.2% for C.I.Reactive Orange 13 and 75.8% for C.I.Basic Red 19. It shows that chitin has better adsorption abilities of ionic dyes of acid, direct and basic dye than non-ionic reactive dye. And chitin has better adsorption abilities of anionic acid direct dyes than cationic basic dye because of the presence of nitrogen atoms. All kinds of dyestuffs used showed speedy absorption effects by chitin, so chitin can absorb much amount of dyes in 5 mimutes reach to equilibrium of adsorption in 2 hours after dipping. Basic dye was absorbed the most speedily in 5 minutes, although maximum adsorption ratio is not high. That reason can be thought that chitin surface is essentially negatively charged due to polar funtional groups.

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A Study on Dosimetric Characterization of Direct Yellow 12 Dye at High Radiation γ-Dose

  • Batool, Javaria;Shahid, Shaukat Ali;Ramiza, Ramiza;Akhtar, Nasim;Naz, Afshan;Yaseen, Maria;Ullah, Inam;Nadeem, Muhammad;Shakir, Imran
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2265-2268
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    • 2012
  • Aqueous solution of oxygenated Direct yellow 12 dye has been evaluated spectrophotometrically as a possible gamma rays dosimeter. The neutral (pH-7), alkaline (pH-12.5) and acidic (pH-5.5) aqueous solution of the dye were prepared and exposed to various gamma doses. Absorption spectra of unirradiated and irradiated solutions were recorded at 400 nm peak. The increase in absorbance with the increase in irradiation dose was observed from 1 to 6 kGy. The stability response of the dye solution for different environmental conditions such as temperature (low & high), light and darkness were investigated during post irradiation storage for ten days. The dye solution showed high stability in darkness for the studied period. The optical density of the dye solution was found to be decreased at high temperature storage.

A Study of the Dyeability and Physical Properties of Mordanted and Finished Fabrics Dyed with Natural Dye of Safflower (홍화를 이용한 매염 및 가공처리 직물의 염색성에 관한 연구)

  • 안경조;김정희
    • Textile Coloration and Finishing
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    • v.13 no.1
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    • pp.23-31
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    • 2001
  • To improve the dyeability and colorfastness of cotton and silk fabric dyed with natural dye of safflower, cotton and silk fabrics were pre-treated with different mordants such as halliic-acid, alum, brine and tannic-acid. Also, to investigate the effect of finishing treatment of fabrics on dyeability, cotton was treated with chitosan and mercerized before dyeing. L, a, b, ΔE and colorfastness(light, Laundry, sweat) of each samples were measured and compared. Mordant treatment didn't improved significantly dyeability and colorfastness on cotton and silk. But, on cotton mercerization and chitosan treatment improved dyeability and colorfastness. To compare the efficiency of extracted dye and Powered dye, extracted red dye of safflower prepared as powder. Cotton and silk were dyed with dyeing solution which made with powdered dye according to different concentration. Efficiency of powdered dye was found out lower than extracted dye solution.

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Chemical Precipitation Treatment for the Disperse Dyes Removal (분산성 염료의 제거를 위한 응집처리)

  • 한명호;박종득;허만우
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.40-50
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    • 2002
  • In order to remove the pollutants effectively in the dye wastewater by chemical precipitation process, coagulation arid flocculation test were carried out using several coagulants on various reaction conditions. It was found that the Ferrous sulfate was the most effective coagulant for the removal of disperse dye(B79), and we could get the best result lot the removal of disperse dye(B56) in the aspects of TOC removal efficiency and sludge field. When the Ferrous sulfate dosage was $800mg/\ell$, the sludge settling velocity was very fast>, and the color was effectively removed in the disperse dye(B79) solution. Although the color removal was ineffective when the Alum was used as a coagulant, the sludge field was decreased in comparison with the Ferrous sulfate or the Ferric sulfate was used in the disperse dye(B56) solution. The general color removal effect for the disperse dye(B56 and B79) solutions, the Ferric sulfate was more proper coagulant than the Alum. It was showed that TOC removal was improved 5% and over by the addition of Calcium hydroxide, and $30mg/\ell$ of sludge yield was decreased(B79). When Alum or Ferric sulfate was used as a coagulant, pH condition for most effective color removal was 5 in B56 solution. In case of Ferrous sulfate as a coagulant, most effective pH condition for color removal was 9. When Ferric sulfate or Ferrous sulfate was used as a coagulant, pH condition for most effective color removal was 9 in B79 solution.

Photocatalytic Reaction of Sensitizer, Rose Bengal and Supersensitizer, Thiourea (감응제 Rose Bengal과 초감응제 Thiourea의 광촉매 반응)

  • Yoon, Kil-Joong
    • Analytical Science and Technology
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    • v.9 no.1
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    • pp.62-71
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    • 1996
  • The enhancement of the solar energy conversion efficiency into the electrical energy by the dye sensitization with a photoelectrochemical cell was studied. The magnitude of the rose bengal sensitized photocurrent containing the supersensitizer, thiourea was five times greater than that in the absence of thiourea. It was observed, however, that the long time span of irradiation causes the decrease in the photocurrent. Spectroscopic analysis of the dye solution showed that the dye molecule was photobleached and the insoluble aggregate which settles down in the solution, was formed as a result of the possible photocatalytic reaction and the disappearance of dye from the solution was the cause of the decreased photocurrent in the sensitization run.

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A Study on the Physical Properties of Sappan Wood Dyeing Fabrics Treated by Rice Straw Ash Solution (잿물로 매염처리된 소방염포의 물성에 관한 연구)

  • 주영주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.6
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    • pp.609-609
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    • 1998
  • This paper surveys the effect of rice straw ash solution to the physical properties of Sappan Wood dyeing fabrics. In the quantitative analysis of rice straw ash solution, the quantities of absorbed ingredients in fabrics were increased by bath pull treatment but the amount of absorption(K/S value) was increased by bath pH4.5 treatment. This is related to the metal ion. Among the metal ion, effect of Fe iou and Al ion were related. In case added extracted dye solution to mordants, the color dye solution became dark and increased reddish. The changes of mechanical properties of fabrics tensile resilience, bending rigidity(B), compressional resilience(RC) were increased. Generally mechanical properties were increased by rice straw ash solution treatment, specially bath pH9 treatment. Rice straw ash solution treatment of dyeing fabrics made the improvement in tensile strength and elongation and in the amount of absorption, dye ability, color fastness, mechanical properties, tensile strength, elongation.