• Elastomers and Composites
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• 제51권1호
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• pp.31-37
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• 2016

In this study, we studied the photocatalytic functionality such as deodorant, antibacterial, antistatic of polyester fabrics treated with visible-light responsive photocatalyst. According to UV/visible spectrometry result, the UV-visible peak of visible-light responsive photocatalyst was found to be red shift at 420 nm sensitive in the visible light region. Also, the deodorizing and antimicrobial performance were shown to be retained more than 99% both before washing and even after 25 times washing. According to washing durability of polyester fabrics treated with visible-light responsive photocatalyst, the reduction effects for gas such as ammonia, trimethylamine, formaldehyde and toluene after 25 times washing appeared to be retained as much as before washing. At both before washing and after 25 times washing, antistatic property showed frictional voltage of approximately 250V.

• Elastomers and Composites
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• 제49권4호
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• pp.336-340
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• 2014

본 연구에서는 광촉매 작용을 하는 이산화티타늄 광촉매를 polyester 섬유에 코팅하여 탈취, 항균 및 자외선 차폐에 대한 기능을 부여하고 그 특성을 알아보았다. 그 결과 탈취성능은 세탁 전과 반복 20회 세탁 후에도 97%이상 저감되는 것으로 나타났으며, 항균성은 균수가 99.9%이상 감소되는 것으로 나타났다. 그리고 Polyester 섬유를 20회 반복 세탁을 행하여도 이산화티타늄 광촉매의 이탈 없이 표면에 견고하게 부착되어 있음을 확인하였으며, 또한 가스분해성능도 세탁전과 20회 반복 세탁 후에도 유지하는 것으로 나타나 세탁내구성이 우수함을 확인하였다. 자외선 차폐성도 세탁 전과 비교하여 20회 반복 세탁 후에도 83%이상 차단되는 것으로 나타났다.

• 한국의류학회지
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• 제45권5호
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• pp.866-880
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• 2021

This study aimed to ex situ colorize laccase-entrapped bacterial cellulose (BC) with natural phenolic dyes, namely,madder, turmeric, and cochineal, and to determine the effect of laccase entrapment on the dyeability of BC using color strength (K/S) analysis. Results showed that laccase entrapment improved the dyeability of BC and that pre-entrapment was the most effective method, compared with meta-entrapment and post-entrapment methods. In addition, surface characterizations confirmed the successful entrapment of laccase inside the BC nanostructure and retention of the cellulosic and crystalline structures of BC. The washing durability test confirmed that the K/S value of BC had improved after laccase entrapment. Furthermore, laccase-entrapped BC colorized with cochineal dye had the highest washing durability due to the high molecular weight of cochineal dyerelative to the other dyes. This study suggests a novel method for enhancing the dyeability and washing durability of BC colorized ex situ with natural phenolic dyes by laccase entrapment.

• 한국가정과학회:학술대회논문집
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• 한국가정과학회 1997년도 가정과학회 총회 및 학술대회
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• pp.33-37
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• 1997

Cotton fabric was treated with chitosan solution by pad-dry(-cure) method to impart antimicrobial properties. Four chitosans of different degree of deacetylation(DAC: 65~95％) with similar molecular weight(ca. 50, 000) and one chitosan oligomer(MW 1, 800, DAC 86％) were used. Antimicribial activity against Staphylococcus aureus was evaluated by the Shake Flask Method. Treated fabrics were laundered up to 20 times according to AATCC Test Method 60-1986 and antimicrobial activity of laundered fabrics was evaluated. The antimicrobial activity was increased with the concentration and DAC of chitosan used. And the cured samples showed better durability to laundering than not-cured samples. Crosslinker and binder decreased the antimicrobial activity of fabrics treated with chitosan oligomer and were not effective to improve the durability to washing.

• 한국염색가공학회지
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• 제27권2호
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• pp.119-125
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• 2015

The effects of e-beam irradiation on water-repellency and washing durability of water-repellent finished chemically-recycled PET(CR-PET) fabrics were investigated. As results, more doses of e-beam irradiation damaged the fabric surface more severely. It was thought because the high densed energy was formed, where the more e-beam was converged. The contact angle measurement showed that as the dose of e-beam irradiation increased, water wettability of the CR-PET fabric increased slightly. It was thought to be due that the surface etching by e-beam irradiation let water droplet permeate into the fabric surface better. The concentration of the water-repellent finishing agent was more important factor than curing temperature as finishing parameter. It was considered because the water-repellent finishing agent used in this study got to cure sufficiently at low temperature. Consequently, e-beam irradiation improved the washing durability of water-repellent finishing on the CR-PET fabrics.

• Elastomers and Composites
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• 제49권1호
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• pp.53-58
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• 2014

가시광촉매의 특성 및 가시광촉매가 코팅처리된 자동차내장재 nylon/polyester 복합섬유에 대한 VOCs의 저감에 대해 알아보았다. 가시광촉매 Weltouch의 결정구조는 아나타제상과 루타일상이 복합된 것으로 약 420nm이상의 파장을 갖는 빛에너지에서도 활성을 나타냈다. 또한 가시광촉매가 처리된 자동차내장재 nylon/polyester 복합 섬유에서 발생하는 VOCs 및 포름알데히드는 현저한 저감효과를 나타냈으며, 섬유를 25회 세탁을 행하여도 가시광촉매의 탈락없이 표면에 견고하게 부착되어 가스분해성능을 유지하는 것으로 나타나서 세탁내구성이 우수한 것을 확인하였다.

• 한국산학기술학회논문지
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• 제20권10호
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• pp.366-373
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• 2019

전투복은 인장 및 인열 강도적인 특성에 있어서 고강도를 요구하며, 최근 발전하고 있는 야간투시 장비로부터 야간에 전투원 생존을 보장하기 위한 적외선 반사율을 적용하고 있다. 다만 전투복은 민수에 다른 옷들과는 다르게 처음 지급된 옷을 다회 세탁하여 사용하며 다시 보급 받는 경우가 드물기 때문에 세탁에 대한 내구성이 필요한 제품이다. 따라서 본 연구에서는 전투복 원단의 다회 세탁 후 강도변화와 적외선 반사율 변화를 알아보고자 시험을 진행하였다. 실험결과 전투복 원단 15회 세탁 이후 강도 변화는 5회 세탁 이후 경/위사 방향 모두 인장, 인열 강도가 거의 일정하게 유지됨을 확인할 수 있었다. 그리고 적외선 반사율의 경우 세탁 처리 하지 않은 것과 세탁 처리 후 반사율 차이가 세탁횟수가 반복됨에 따라 커짐을 확인할 수 있었다. 이를 통해 전투복의 경우 강도적인 측면에서의 세탁 내구성은 있지만, 적외선 반사율은 소재 개발 또는 염료 개발을 통해 일정 수준 이상의 반사율을 유지하는 것이 필요함을 알 수 있었다.

• 패션비즈니스
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• 제13권6호
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• pp.147-156
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• 2009

In this study, one of disadvantages is to improve the durability of natural dyeing. In order to enhance linkage of Chitosan or Linkage of between Chitosan and cotton fabrics, effect of increasing amount of Silane on Chitosan durability and possibility of using Chitosan as natural mordant were reviewed. After treatment of chitosan with silane, color effect is similar to dyeability used metal mordant. And the durability's washing fastness and air permeability as using chitosan with silane is better than treatment of metal mordant. Chitosan with silane can perform the natural mordant.

• 대한가정학회지
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• 제33권3호
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• pp.243-253
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• 1995

This study has been carried out for the antimicrobial effects of organic silicon quaternary ammonium salt with which cotton, polyester, and wool were treated respectively, using Esherichia coli and Proteus bulgaris which are experimental bacteria for clothing materials. As a results, the best antimicrobial effects of organic silicon quaternary ammonium salt came out from cotton ; the next form wool ; and lower from polyester. With the changes of the temperature, the antimicrobial effect with soaking time, there was no changes with cotton after 10 minutes passed. It seemed to have reacted entirely in the early stage. The longer the soaking duration was, the higher the effect from polyester was. The effect from wool was increased until 20 minutes, but decreased after 30 minutes. The optimal processing condition of cotton was in the condition of liquor ratio 40:1, concentration 0.5%, soaking time 5 minutes, and temperature 3$0^{\circ}C$ ; wool was 1.5%, 20 minutes, and 6$0^{\circ}C$ ; polyester was 2.0%, 30 minutes, and 3$0^{\circ}C$ respectively. The changes of the effect by washing was as followings : The processing effect on cotton and wool appeared to be everlasting, since they had no changes by washing 10 times ; while, it was remarkablely decreased with polyester by washing only once, and was almost disappeared after washing 10 times, which means that polyester has no durability to washing.

• Korean Chemical Engineering Research
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• 제60권1호
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• pp.20-24
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• 2022

고분자전해질연료전지 (PEMFC) 장기사용과정에서스택요소의부식및공급가스의오염에의해막전극합체 (MEA)의 화학적 열화가 발생한다. 본 연구에서는 화학적으로 열화된 MEA를 산 세척해서 성능을 회복시킬 수 있는지 연구하였다. 철 이온을 오염시키고 황산 수용액으로 세척하여 PEMFC 셀에서 성능을 측정해 비교했다. 0.5 ppm의 철 이온 오염에 의해 약 25%의 성능 감소가 있었고 0.15 M 황산 세척에 의해 97.1% 성능회복이 가능했다. 고분자 막의 철 이온 오염에 의해 막 저항이 증가했고, 저농도 황산 수용액 세척에 의해 전극 촉매의 손실을 최소화하면서 막에서 철 이온을 세척함으로써 이온전도도가 회복되었다. PEMFC MEA의 화학적 오염에 의한 내구성 감소를 산 세척에 의해 해결할 수 있는 가능성을 확인하였다.