• Journal of Soil and Groundwater Environment
• /
• v.16 no.1
• /
• pp.19-31
• /
• 2011

This study had been carried out to investigate spatial and temporal variations of the concentrations of trace metals for contaminated surface water in creek affected by leachate from the tailings impoundment of the Yeonhwa II mine for about 2 years. It was also to ascertain the metal removal efficiency for potentially deleterious metals by the artificial and natural attenuation processes such as retention ponds and hydrologic mixing of uncontaminated tributaries. The concentrations of As, Pb, Cd, and Cu for leachate in the rainy season were not detected. On the other hand, the concentrations of Zn, Fe, Mn, Al, and $SO_4^{2-}$ in the rainy season for leachate were 2-66 times higher than those in the dry season, due to the oxidation of the sulfide minerals and the dissolution of the secondary minerals. The concentrations of Zn and Cd for leachate and surface water of the upper creek in the rainy season exceeded the criteria of River Water Quality and Drinking Water Quality but in the dry season, those of analyzed all the metals (As, Pb, Cd, Cu, Zn, Cd, Fe, Mn, and Al) for surface water sampled at the study area were below the criteria of River Water Quality and Drinking Water Quality. In regard of the attenuation efficiency for the concentrations of metals, Fe, Mn, Al, Zn, Cd, As, and Cu were removed highly at retention ponds, while the removal efficiency for major cations and sulfate ($SO_4^{2-}$) were related to mixing of the uncontaminated tributaries. Therefore, the major attenuation processes of the metal and sulfate contents in creek affected by leachate from a tailing dump were precipitation (accompanied by metal co-precipitation and sorption), water dilution, and neutralization.

• Journal of Korean Society on Water Environment
• /
• v.27 no.2
• /
• pp.228-234
• /
• 2011

The goal of water quality management on stream and watershed is to focus not on discharged loads management but on a water quality management. Discharged loads management is not goal of water quality management but way for perform with total maximum daily loads management. It is necessary to estimate the relation between non-point source with stromwater runoff (NPSSR) and water quality to select a watershed where it is required to manage NPSSR for water quality improvement. To evaluate the effects of NPSSR on stream's water quality, we compare the aspects of water quality in dry and wet seasons using flow duration curve analysis based on flow rate variation data by actual surveying. In this study we attempt to quantify the variation characteristic of water quality and estimate the Inflow characteristic of pollution source with water quality and flow rate monitoring on 10 watersheds. We try to estimate water quality and flow rate by regression analysis and try again regression analysis with each high and low water quality data more than estimations. An analysis of relation between water quality and flow rate of 10 watersheds shows that the water quality of the Nonsan and the Ganggyeong streams had been polluted by NPSSR pollutants. Other eight streams were important point source more than NPSSR. It is wide variation range of $BOD_5$ also high average concentration of $BOD_5$. We have to quantify water quality variation by cv1 in wet season and cv365 in dry season with comparing the estimate of high water quality and low water quality. This method can be used to indicator for water quality variation according to flow rate.

• Journal of Korean Society on Water Environment
• /
• v.36 no.6
• /
• pp.489-499
• /
• 2020

Effective science-based management of the basin water resources requires an understanding of the characteristics of the streams, such as the baseflow discharge. In this study, the base flow was estimated in the two watersheds with the least artificial factors among the Nakdong River watersheds, as determined using the chemical hydrograph separation technique. The 16-year (2004-2019) discontinuous observed stream flow and electrical conductivity data in the Total Maximum Daily Load (TMDL) monitoring network were extended to continuous daily data using the TANK model and the 7-parameter log-linear model combined with the minimum variance unbiased estimator. The annual base flows at the upper Namgang Dam basin and the upper Nakdong River basin were both analyzed to be about 56% of the total annual flow. The monthly base flow ratio showed a high monthly deviation, as it was found to be higher than 0.9 in the dry season and about 0.46 in the rainy season. This is in line with the prevailing common sense notion that in winter, most of the stream flow is base flow, due to the characteristics of the dry season winter in Korea. It is expected that the chemical-based hydrological separation technique involving TANK and the 7-parameter log-linear models used in this study can help quantify the base flow required for systematic watershed water environment management.

• Journal of Environmental Science International
• /
• v.12 no.7
• /
• pp.735-744
• /
• 2003

The field observations on a seasonal characteristic of organic matter and its origin in the surface sediment were carried out at 35 stations in Deukryang bay, southern coast of Korean Peninsula from May 1995 to February 1996. The analytical parameters were mud temperature, ignition loss(IL), chemical oxygen demand(COD), pheopigment, sulfide and water content. The origin and seasonal dynamics of organic matter in Deukryang Bay were analyzed by COD/IL, COD/sulfide ratio and principal component analysis(PCA). As a results of the mud temperature fluctuated between 2.1$^{\circ}C$ with the lowest mean 4.6$^{\circ}C$ in winter and 27.6$^{\circ}C$ with the highest mean 25.5$^{\circ}C$ in summer. The range of ignition loss(IL) was from 3.1% in autumn to 21.5% in winter. Chemical oxygen demand(COD) showed the highest mean value of 8.45 mg/g dry in spring within the range of 2.90∼18.21 mg/g dry, while it showed the lowest value of 4.33 mg/g dry in autumn within the range of 0.67∼10.37 mg/g dry. Pheopigments showed the highest mean value of 9.04 $\mu\textrm{g}$/g dry in autumn within the range of 1.36∼20.44 $\mu\textrm{g}$/g dry, while it did the lowest mean value of 2.20 $\mu\textrm{g}$/g dry in summer within the range of 0.33∼11.36 $\mu\textrm{g}$/g dry. The range of total sulfide (H$_2$S) was from no detect(ND) to 3.30 mg/g dry in spring. And water content showed the annual mean value of 43.6% within the range of 23.6∼54.9%. The source of organic matter by COD/IL and COD/sulfide ratio in Deukryang Bay had been producted by primary producer in sea water areas except the areas effected by small stream, domestic and animal wastes. And the analytical results of PCA was able to be divided into three different regions. The former was characterized by the shallow depth and authigenic organic matter from phytoplankton in northwest area and northeastern inner bay, the secondary was done by deeper depth and allochthonous one from lands in southeast area and eastern entrance of bay, and the latter was done by authigenic one from the farm of seaweeds such as, sea cabbage, sea mustard etc in western entrance of bay. But a study on the relationship between sulfide and COD concentration in the northeastern inner bay which was characterized by the water stagnation will to take much more studying including major constituents of organic matter in the future.

• Economic and Environmental Geology
• /
• v.41 no.1
• /
• pp.63-79
• /
• 2008

Physicochemical characteristics of stream water, leachate, mine water and groundwater were investigated to estimate the influences of the tailing and waste rock from the abandoned Uljin mine area. Total extraction analysis and mineralogical studies were carried out to understand sulfide weathering and to determine the distributions of trace elements in the soil affected by mine waste (tailing, waste rock and leachate). The pH and EC value of the leachate from the tailing disposal ranged 2.9-6.0, $99{\sim}3,990{\mu}S/cm$, respectively, and the concentrations of dissolved major (up to 492 mg/l Ca; 83.8 mg/l Mg; 45.2 mg/l Na; 44.7 mg/l K, 50.8 mg/l Si) and trace elements (up to $826,060{\mu}g/l$ Fe; $131,230{\mu}g/l$ Mn; $333,600{\mu}g/l$ Al; $61,340{\mu}g/l$ Zn; $2,530{\mu}g/l$ Cu; $573{\mu}g/l$ Cd; $476{\mu}g/l$ Pb) were relatively high. The stream water showed the variation of dissolved metal concentrations in seasonally and spatially. The dissolved metal contents of the stream water increased by influx the leachate from the tailing disposal, but these of the down stream have been considerably decreased by mixing of dilute tributaries. The dissolved metal concentrations of the stream water at dry season (as February) were lower than these at rainy season (as May and July). These represent that the amounts of the leachate varied with season. However, stream water could not be effectively diluted by confluence with uncontaminated tributaries, because the flux of tributaries and streams reduced at dry season. Thus attenuations by dilution had been dominantly happened in rainy seasons. The order of accumulations of trace element in soils compared with background values revealed Mn>Fe>Pb>Cu>Zn. Sulfide minerals were mainly pyrrhotite, sphalerite and galena and chalcopyrite. Pyrrhotite was rapidly weathered along the edge and fractures, and results in the formation of Fe-(oxy)hydroxides, which absorbed a little amount of Zn.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.17-17
• /
• 2010

This paper address technical issues in calibrating discharge coefficients of sonic nozzles used to measure the volume flow rate of low vacuum dry pumps. The first challenging issue comes from the technical limit that their calibration results available from the flow measurement standard laboratories do not fully cover the low vacuum measurement range although the use of sonic nozzles for precision measurement of gas flow has been well established in NMIs. The second is to make an ultra low flow sonic nozzlesufficient to measure the throughput range of 0.01 mbar-l/s. Those small-sized sonic nozzles do not only achieve the noble stability and repeatability of gas flow but also minimize effects of the fluctuation of down stream pressures for the measurement of the volume flow rate of vacuum pumps. These distinctive properties of sonic nozzles are exploited to measure the pumping speed of low vacuum dry pumps widely used in the vacuum-related academic and industrial sectors. Sonic nozzles have been standard devices for measurement of steady state gas flow, as recommended in ISO 9300. This paper introduces two small-sized sonic nozzles of diameter 0.03 mm and 0.2 mm precisely machined according to ISO 9300. The constant volume flow meter (CVFM) readily set up in the Vacuum center of KRISS was used to calibrate the discharge coefficients of the machined nozzles. The calibration results were shown to determine them within the 3% measurement uncertainty. Calibrated sonic nozzles were found to be applicable for precision measurement of steady state gas flow in the vacuum process. Both calibrated sonic nozzles are demonstrated to provide the precision measurement of the volume flow rate of the dry vacuum pump within one percent difference in reference to CVFM. Calibrated sonic nozzles are applied to a new 'in-situ and in-field' equipment designed to measure the volume flow rate of low vacuum dry pumps in the semiconductor and flat display processes.

• Korean Journal of Ecology and Environment
• /
• v.34 no.1 s.93
• /
• pp.62-69
• /
• 2001

This study was investigated discharge and water quality for rainy days at the inflow streams (Gog-Kyo, Mu-Han, Sap-Kyo and Nam-Won) into Lake Sap-Kyo from June to November of 1999. The eventual aim of this study was to improve the water quality of Lake Sap-Kyo. Therefore, in order to reduce inflow pollutants loading into Lake Sap-Kyo, we investigated characteristics of stormwater runoff and estimated pollutant loading for the rainy season. The results of that Sap-Kyo stream is $5.75\;m^3/sec$ flow and influences water quantity of Lake Sap-Kyo greatly during the dry weather. Gog-Kyo stream influence to quantity of Lake Sap-Kyo greatly for the rainy days. Gog-Kyo stream and Sap-Kyo stream are $12.13\;m^3/sec$ and $8.49\;m^3/sec$, respectively. The reason is that the watershed area of Gog-Kyo stream is larger than other streams. When we prepare to plan management to improve the water quality of Lake Sap-Kyo, we have to consider that runoff characteristics by land use. Among the annual total pollutants loading inflow Lake Sap-Kyo, the ratio of non-point pollutants loading estimated that SS, BOD, T-N and T-P are 62%, 43%, 41% and 27%, respectively. Therefore, in order to improve water quality of Lake Sap-Kyo, we have to reduce non-point pollutants loading.

• Ecology and Resilient Infrastructure
• /
• v.4 no.1
• /
• pp.12-23
• /
• 2017

The Naeseong Stream is a meandering sand-bed stream flowing through mountains and has so long maintained its geomorphological uniqueness characterized by extensive braided bare bars. Recently, its long-lasting landscape has been changed due to encroachment of vegetation. In this study being a part of long-term monitoring research morphological changes of the 56.8 km long study reach of the Naeseong Stream, which occurred during the period of 2012 - 2016 were analyzed. Airborne LiDAR and terrestrial cross-section surveys were carried out. Hydrological and on-site investigation data were also collected. Among the main four sites, two bend reaches showed point bars enlarged, while along the other two straight reaches mid-channel bars were either newly formed or increased in area and height. At the highest deposition point of each bar, vertical changes which were caused by one or two times of sediment deposition amounted to 0.6 - 1.4 m. On the contrary channel bed degradation was not obvious. Overall morphological changes in the study reach were attributed to deposition of sediment which occurred during the flood in July 2016 on the bar surfaces vegetated during the precedent dry seasons. These kind of geomorphological processes are thought to be the same as those related to the existing mid-channel islands along the mid- and downstream reach of the Naeseong Stream.

• Journal of Korean Society of Environmental Engineers
• /
• v.34 no.6
• /
• pp.421-429
• /
• 2012

This study was aimed to analyze the water quality characteristics of the Hwapocheon Stream and to be utilized in the further related research. Water in the upper stream became a dammed pool due to the existence of 14 weirs, and pollutants such as both sewage and irrigation water were introduced into the mainstream passing through farming settlements and agricultural land. For these reasons, filamentous cyanobacteria (Oscillatoria sp.) bloomed at the bottom of the dammed pool. Also in the midstream and downstream, tributaries with high pollutant concentrations [e.g., Comocheon (T3) and Yongdeokcheon (T8)] were inflowed, and had a negative impact on water quality of the mainstream, especially nitrogen and phosphorus. In the Hwapocheon Stream, dissolved oxygen (DO) decreased, and suspended solid (SS) increased toward the downstream. The result showed that hydraulic retention time, SS, COD, and concentration of $NH_4{^+}$ were important water quality factors of the Hwapocheon Stream. The high concentration of benthic organic matter and rich in attached algae in the core of Hwapo-wetland were expected to give impact on the water quality of the mainstream. In the spatial manner, water quality showed increasing trend in the weir zone, and it was constant or decreased trend in wetland. In the seasonal manner, the nutrient concentrations were high in the winter dry season, however, the organic matter concentrations were high in spring and summer. Generally, the concentrations of phytoplankton value were $40{\mu}g\;chl-{\alpha}/L$ or less in all reaches except for the high concentrations in the weir and wetland area in June.

• The Korean Journal of Ecology
• /
• v.22 no.2
• /
• pp.95-100
• /
• 1999

The heavy metal concentrations in seawater and winkles (Littorina brevicula) collected from the Onsan bay area in southeast of Korea were analyzed. The heavy metal concentrations in the seawater obtained from the most polluted site showed approximately 189. 205. and 110 fold higher cadmium, copper. and zinc concentrations, respectively. than the uncontaminated control site. The contamination levels of these metals in winkles were 11.08 - 2.35, 334.5 - 212.5, and 426.0 - 499.2$\mu\textrm{g}$ per gram dry body weight. respectively. The concentrations of all three metals in both the seawater and winkles decreased gradually with increasing distance from Daejeong stream, suggesting the stream being the major source of heavy metal input into the bay. Among the four body parts of digestive gland and gonad. gill. kidney, and remaining tissue in contaminated winkles, kidney showed the highest accumulation level of cadmium: copper and zinc, however. were more or less distributed among the four body parts. Upon gel filtration chromatography of the cytosol from the kidney of cadmium induced winkles, one cadmium peak corresponded to the elution peak of horse kidney metallothionein.