• Title/Summary/Keyword: dry acid deposition

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The Effects of Sampling Flow Rate on the Concentrations of Dry Acid Deposition Components (산성 건성침적물 샘플링에 따른 유량변수가 그 대기중 농도측정에 미치는 영향)

  • 김조천
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.2
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    • pp.147-159
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    • 1997
  • One of the most critical problems associated with filter-pack data comparisons from various field networks is the use of different sampling flow rates. In this field study, the effects of various filter-pack(FP) sampling conditions were examined. Experiments were conducted to evaluate the effects of varying sampling flow rates (1.5 to 10 sLpm) on measured concentrations of dry acid deposition species. Collocated FP samples were also collected to determine sampling and analysis data reproducibility. Ambient air samples were collected simultaneously for the seven day durations at varous flow rate. The chemical species measured were sulfur dioxide ($SO_2$), particulate sulfate(P-$SO_{4}^{2+}$), nitric acid ($HNO_3$), and particulate nitrate (P-$NO_{3}^{-}$). The results indicated that the collocated samples can be measured reproducibly and that sampling bias for the species measured is not significant. It was concluded that variations in the flow rates (1.5 to 10 sLpm) did not significantly affect the concentration of the species of interest. Although the results were not significantly different between different flow rates, artifacts were more likely to occur at high flow conditions (>5 sLpm) (e.g., via volatilization of particulate nitrates) than at low flow conditions(<5 sLpm).

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A Study on the Behavior and Deposition of Acid Precipitation-Measurement of Dry Deposition in Chunchon and Seoul by Using Filter Pack Method (산성강하물의 침착량과 동태 해명에 관한 연구 - 필터팩을 이용한 춘천과 서울의 건성강하물의 농도 측정)

  • Kim, Man-Goo;Park, Ki-Jun;Kang, Mi-Hee;Hwang, Hoon;Lee, Bo-Kyung;Lee, Dong-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.1
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    • pp.53-61
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    • 1999
  • Acid aerosol and gas concentrations ($SO_4^{2-}$, $NO_3^-$, $HNO_3$, $SO_2$, and $NH_3$) were measured at Chunchon and Seoul, Korea using filter pack method during one year from October 1996 to september 1997. The samples were collected during 24 hours every Wednesday in a week from 10 A.M. with 10$\ell$/min of sample flow. Concentration of $HNO_3$, $SO_2$ and $NH_3$ gases showed typical seasonal variation. The $HNO_3$ showed the highest in summer and annual mean concentrations were 0.42 ppb and 0.57 ppb at Chunchon and Seoul, respectively. The $SO_2$ showed the highest in winter and annual mean concentration was 5.59 ppb at Chunchon. The $NH_3$ showed the highest in early summer and annual mean concentration were 5.15 ppb and 6.28 ppb at Chunchon and Seoul, respectively.

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A Study of The Photosensitive Characteristic and Fabrication of Polyimide Thin Film by Dry Processing (건식법을 이용한 폴리이미드 박막의 제조 및 광특성)

  • Lee, Boong-Joo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.1
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    • pp.139-141
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    • 2007
  • Thin films of polyimide (Pl) were fabricated by a vapor deposition polymerization method (VDPM) and studied for the photosensitive characteristic. Polyamic acid (PAA) thin films fabricated by vapor deposition polymerization (VDP) from 6FDA and 4-4' DDE were converted to PI thin films by thermal curing. From AFM and Ellipsometer experimental, the films thickness was decreased and the reflectance was increased as the curing temperature was increased. Those results implies that thin film is uniform. From UV-Vis spectra, PI thin films showed high absorbance in 225 $\sim$ 260 [nm] region.

Effects of Muscle and Finishing Diets Containing Distillers Grains with Low Moisture Levels on Fatty Acid Deposition in Two Novel Value-added Beef Cuts

  • Giotto, Francine M.;Fruet, Ana Paula B.;Nornberg, Jose L.;Calkins, Chris R.;de Mello, Amilton S.
    • Food Science of Animal Resources
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    • v.40 no.3
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    • pp.484-494
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    • 2020
  • This study evaluated the effects of muscle and dietary treatments including CORN, dry distillers grains (DDGS), and modified distillers grains (MDGS) on fatty acid (FA) deposition in two novel value-added beef cuts (Petite Tender - M. teres major - TM, and Flat Iron - M. infraspinatus - INF). Crossbred steers were randomly assigned to one of three dietary treatments (CORN, 40% of DDGS with 8%-12% of moisture, and 40% of MDGS with 45%-55% of moisture - DM basis) and fed for 190 days. The TM muscle had higher concentrations of ω6 FAs and polyunsaturated fatty acids (PUFA) when compared to INF. Beef fed CORN showed greater C16:0 and lower C18:0 values when compared to beef fed distillers grains (DGS). Beef fed DDGS had higher concentrations of ω6 FAs when compared to MDGS. Different moisture levels only affected FAs containing 14, 16, and 17 carbons. Different muscles, diets, and moisture levels of DGS affected the deposition of FAs in the lean.

Characteristics of Wet and Dry Deposition at Chunchon, 2000~2001 (2000~2001년 춘천의 습성.건성강하물의 특성)

  • 홍영민;이보경;정지영;윤민경;김만구
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.43-44
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    • 2001
  • 산업의 발달과 함께 화석연료의 소비가 증가하면서 산성강하물(Acid precipitation)에 대한 관심이 증가하여 왔다. 산성강하물은 주로 화석연료의 연소를 통해 대기로 배출된 질소와 황 산화물들로, 산화ㆍ환원, 산ㆍ염기 중화반응 등 다양한 변환과정을 거쳐 비나 눈과 같은 습성과정이나 가스나 입자상 물질과 같은 건성과정을 통해 다시 토양과 호수 등에 침적되어 이들을 산성화시키는 원인이 된다. 따라서 산성강하물에 대한 이해를 위해서는 강수의 화학조성과 아울러 가스와 입자상으로 존재하는 질소와 황화합물에 대한 관측이 필수적이다. (중략)

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Chemical Characteristics of Precipitation in Quercus Forests in Korea and Japan

  • Kim, Min Sik;Takenaka, Chisato;Park, Ho Taek;Chun, Kun Woo
    • Journal of Korean Society of Forest Science
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    • v.96 no.5
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    • pp.503-509
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    • 2007
  • The major objective of this study was to analyze the difference of the chemical characteristics of acid deposition in Quercus forests in Korea and Japan. The pH values of rainfall at the experimental forest of Kangwon National University (KS site) were higher than those at the Foresta Hills in Japan (JP site), and all chemical contents of throughfall and stemflow were much higher than those of rainfall in Quercus forest stands at the KS and JP site. The pH values, $Ca^{2+}$, $NO_3{^-}$ and $SO{_4}^{2-}$ concentration of throughfall and stemflow at the KS site showed seasonal variation. While at the JP site, the same pattern was shown in the pH values of throughfall and stemflow, however, did not show any difference among seasons. Also, the annual input of all nutrients in these two contrasting forests varied seasonally. These results can be used to predict the amounts of air pollutant that are washed off and leached by the rainfall and Yellow Sand (Asian dust), including NOx and SOx acid pollutants transported easterly from China in the spring. Therefore, it is necessary to quantify the inputs of dry and wet deposition throughout a full year to gain a more complete understanding of the effects of acid deposition on the nutrient cycles in these forest ecosystems.

Characteristics of Atmospheric Dry Deposition of Nitrogen-containing Compounds (대기 중 질소산화물의 건식침적 특성)

  • Yi, Seung-Muk;Han, Young-Ji;Cheong, Jang-Pyo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.775-784
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    • 2000
  • Nitrate dry deposition fluxes were directly measured using knife-leading-edge surrogate surface (KSS) covered with greased strips and a water surface sampler (WSS). The average gaseous flux ($8.3mg/m^2/day$) was much higher than the average particulate one ($3.0mg/m^2/day$). The best fit gas phase mass transfer coefficient (MTC) of $HNO_3$ was obtained by linear regression analysis between measured gaseous flux containing nitrogen compounds and measured ambient $HNO_3$ concentration. The result showed that the MTCs of $HNO_3$ were approximately two times higher than those of $SO_2$. Especially, during the ozone action day, measured gaseous fluxes containing nitrogen compounds were much higher than those ones calculated as the product of measured ambient $HNO_3$ concentration and gas phase MTC of $HNO_3$, which is calculated from MTC of $SO_2$ using Graham's diffusion law. This result indicated that other nitrogen compounds except $HNO_3$ contributed to gaseous flux containing nitrogen compounds into the water surface sampler. The theoretical calculations suggest the contributions of nitrous acid ($HNO_2$) and PAN to the gaseous dry deposition flux of nitrogen containing compounds to the WSS.

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Effects of Soil Acidification on Growth of Impatiens balsamina L. and Tagetes patula L. Plants (토양산성화가 봉선화(Impatiens balsamina L.) 및 만수국(Tagetes patula L.)의 생장에 미치는 영향)

  • 김학윤
    • Journal of Life Science
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    • v.11 no.2
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    • pp.153-158
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    • 2001
  • To investigate the effects of soil acidification on growth of Impatiens balsamina L. plants were transplanted to acidified soils with H$_2$SO$_4$ solution. The concentrations of soluble Ca, Mg, K, Al and Mn in the acidified soils increased with increment of H$^{+}$ addition to the soil. In both species, the plant height and root length were inhibited by soil acidification, showing much severer inhibition in Impatiens balsamina L. than in Tagetes patula L., As the soil pH decreases, the growth of underground parts decreased greatly than that of above ground parts in both species. Total dry weight decreased with increased Al concentration as well as lowered soil pH in both plants. There was a strong positive correlation between relative total dry weight and molar (Ca+Mg+K) / Al ratio of the soil. The results suggest that molar(Ca+Mg+K)/ Al ratio of the soil may be useful indicator for assessing the critical load of acid deposition in herb species.s.

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Effects of Artificially Acidified Soils on the Growth and Nutrient Status of Pinus densiflora and Quercus acutissima Seedlings (토양산성화가 소나무, 상수리나무 묘목의 생장 및 영양상태에 미치는 영향)

  • Jin, Hyun-O;Bang, Sun-Hee;Lee, Choong-Hwa;Kim, Se-young
    • Journal of Korean Society of Forest Science
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    • v.97 no.3
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    • pp.266-273
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    • 2008
  • The effects of soil acidification on the seedling growth and nutrition of Pinus densiflora and Quercus acutissima were investigated. The relationship between the seedling growth and molar (Ca+Mg+K)/Al ratio of in soil solution was examined. The results suggested that growth inhibition of seedling Pinus densiflora and Quercus acutissima was due to the low pH of soil solution, which was followed by leach of Al into soil solution, and decrease of essential elements, such as Ca in aerial pant of the seeding caused by the increase of Al concentration in subterranean pant of the seedlings. The level of growth inhibition was determined not only by Al concentration, but also by the balance of inorganic elements, Al, Ca, Mg and K. The growths of two species in total dry weight were clearly inhibited when molar (Ca+Mg+K)/Al ratio of the soil was lower than 6.0. The growth in dry weight, in the condition of the molar ratio was 0.8, was decreased 60% or 50% for the seedling of Pinus densiflora or Quercus acutissima respectively. It was concluded that the molar (Ca+Mg+K)/ Al ratio could be an important index for evaluation of the effects of soil acidification, due to acid deposition such as acid rain, on growth of trees and nutrition. And it might be a more useful indicator for evaluation of critical load of acid deposition on forest ecosystems.

Electrocatalytic Oxidation of HCOOH on an Electrodeposited AuPt Electrode: its Possible Application in Fuel Cells

  • Uhm, Sung-Hyun;Jeon, Hong-Rae;Lee, Jae-Young
    • Journal of Electrochemical Science and Technology
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    • v.1 no.1
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    • pp.10-18
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    • 2010
  • Controlled electrodeposition of dendritic nano-structured gold-platinum (AuPt) alloy onto an electrochemically pretreated carbon paper substrate was conducted in an attempt to improve catalyst utilization and to secure an electronic percolation network toward formic acid (FA) fuel cell application. The AuPt catalysts were obtained by potentiostatic deposition. AuPt catalysts synthesized as bimetallic alloys with 60% Au content exhibited the highest catalytic activity towards formic acid electro-oxidation. The origin of this high activity and the role of Au were evaluated, in particular, by XPS analysis. Polarization and stability measurements with 1 mg $cm^{-2}$ AuPt catalyst (only 0.4 mg $cm^{-2}$ Pt) showed 52 mW $cm^{-2}$ and sustainable performance using 3M formic acid and dry air at $40^{\circ}C$.