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Properties of Perovskite Materials and Devices Fabricated Using the Solvent Engineered One-Step Spin Coating Method (단일 스텝 스핀 코팅 방법에서 증발 제어 공정 변경에 따른 페로브스카이트 박막 물성 및 태양 전지 소자 특성 변화에 관한 연구)

  • Oh, Jungseock;Kwon, Namhee;Cha, DeokJoon;Yang, JungYup
    • New Physics: Sae Mulli
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    • v.68 no.11
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    • pp.1208-1214
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    • 2018
  • The one-step spin coating method is reported as an excellent thin film process because it can be easily used to fabricate high-quality methyl-ammonium lead tri-iodide ($MAPbI_3$) perovskite layers. One of the important things in the one-step spin coating method towards obtaining high-quality $MAPbI_3$ layers is the anti-solvent (AS) engineering, which consists of an one-step deposition of the $MAPbI_3$ film and dripping of the AS. The properties of the $MAPbI_3$ layer were found to be strongly influenced by the amount, dispensing speed, and spraying time of the AS solution. The $MAPbI_3$ solution was prepared by dissolving lead iodide and methyl-ammonium iodide in N,N-dimethylformamide and adding N,N-dimethyl sulfoxide. Diethyl ether (DE) was used for the AS solution. The results indicate that a $MAPbI_3$ layer appropriately sprayed with DE is beneficial for improving film quality and device efficiency because nucleation of $MAPbI_3$ layer is affected by the characteristics of DE, which affect the film's crystallinity, density, and surface morphology. The $MAPbI_3$ layer, which was optimized by using 0.7 mL of DE, a 3.03 mL/sec dispensing speed, and a 7 second time to spray after spinning showed the best efficiency of 13.74%, which was reproducible.

Fabrication of Porous Ceramic Materials for Biomedical and Environmental Applications

  • Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.18.2-18.2
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    • 2009
  • Ceramics have some properties that are unmatched by other kind of materials like metals or polymers. The ability of high thermal and chemical resistance and in case of being superior in specific mechanical properties makes the ceramic materials suitable for arange of applications. The microstructure and morphology of a material arguably permit the use of many advanced application otherwise difficult to achieve.Porous structures have some important applications in biomedical and environmental field. For human hard tissue reconstruction and augmentation procedure suitable biomaterials are used with a desirable porosity. A range of porous bioceramics were fabricated with tailored design to meet the demand of specific applications. Channeled and interconnected porosity was introduced in alumina, zirconia, and hydroxyapatite or tri calcium phosphate ceramics by different methods like multi-pass extrusion process, bubble formation in viscous slurry,slurry dripping in immiscible liquid, sponge replica method etc. The detailed microstructural and morphological investigations were carried out to establish the unique features of each method and the developed systems. For environmental filters the porous structures were also very important. We investigated a range of channeled and randomly porous silicon based ceramic composites to enhance the material stability and filtration efficiency by taking advantage of the material chemistry of the element. Detailed microstructural and mechanical characterizations were carried out for the fabricated porous filtration systems.

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Numerical Simulation of the Liquid Flow in the Lower Part of the Blast Furnace - A Cold Flow Case (고로하부 액체유동에 대한 수치해석 사례 - 냉간유동)

  • Jin, Hong-Jong;Choi, Sang-Min;Jung, Jin-Kyung
    • Journal of the Korean Society of Combustion
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    • v.13 no.2
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    • pp.33-41
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    • 2008
  • The high permeability of the gas in the molten iron of the dripping zone of the blast furnace is a major factor in achieving the stable operation of a furnace with high productivity. Basic studies of the liquid flow behavior in a packed bed are necessary to grasp the effect of various operational changes on conditions in the dropping zone. Molten iron and slag together playa critical role in the lower zone, transporting mass and energy, while impairing and redistributing the gas flow. In turn, molten iron and slag undergo physical and chemical changes, and are redistributed radially as they descend to the hearth. In this research, mathematical formulations are derived for the gas and the liquid. The solid phase is fixed with constant porosity. The information for the molten iron and slag includes the hold-up, velocity, pressure, and information related to the areas of interaction between the gas and the liquid, and the solid and the liquid. Predictable results include the velocity, pressure and temperature distribution. Additional parameters include the packed particle size and the air blast rate.

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Melorheostosis with Synovial Chondromatosis of the Foot: A Report of Two Cases (족부에 발생한 활막 연골종증을 동반한 유선상 과오종: 2예 보고)

  • Lee, Chae Chil;Kim, Sang Woo;Choi, Hye Jeong;Hwang, Il Yeong;Kim, Min Seok
    • Journal of Korean Foot and Ankle Society
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    • v.19 no.4
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    • pp.193-196
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    • 2015
  • Melorheostosis is a rare disease, belonging to the sclerotic bone dysplasia group. Initially described by Leri and Joanny in 1922, its etiology remains unknown. Onset is usually insidious, with deformity of the extremity, pain, limb stiffness, and limitation of motion in the joints. The typical radiographic appearance consists of irregular hyperostotic changes of the cortex, resembling melted wax dripping down one side of a candle. Treatment is usually symptomatic and conservative; however, conservative treatment is unsatisfactory due to functional issues when involving the distal extremity. We report on two cases of melorheostosis with synovial chondromatosis of the foot treated by mass excision.

Field Performance of a New Fungicide Ethaboxam Against Cucumber Downy Mildew, Potato Late Blight and Pepper Phytophthora Blight in Korea

  • Kim, Dal-Soo;Prak, Hyun-Cheol;Chun, Sam-Jae;Yu, Seung-Hun;Park, Kyong-Ju;Oh, Jeung-Haing;Shin, Kwang-Hoon;Koh, Young-Jin;Kim, Byung-Sup;Hahm, Young-Il;Chung, Bong-Koo
    • The Plant Pathology Journal
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    • v.15 no.1
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    • pp.48-52
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    • 1999
  • Ethaboxam is the first proprietary fungicide developed in Korea, registered in 1998 and commercialized in 1999 by LG Chemical Ltd., Korea. It is a derivative of aminothiazole carboxamide and formulated into 25% wettable powder for practical application in fields. Ethaboxam effectively controlled cucumber downy mildew caused by Pseudoperonospora cubensis, potato late blight caused by Phytophthora infestans, and pepper Phytophthora blight caused by P. capsici, and was superior or comparable to the commercial standards, when foliarly sprayed 3∼5 times until dripping off at approximately 7-day intervals during the growing season. Ethaboxam was required at least 125 mg/liter and 250 mg/liter for effective control of cucumber downy mildew, and potato late blight and pepper Phytophthora blight, respectively. There was not phytotoxicity observed o leaves, stems or fruits of cucumber, potato and pepper from any trial.

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Electrohydrodynamic Water Droplet Ejection Characteristics from a Micro-Water-Nozzle (미세 수관 노즐의 전기유체역학적 수적 분사특성)

  • Moon, Jae-Duk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.9
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    • pp.1632-1637
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    • 2010
  • A micro-water-nozzle, as one of a cooling means of micro-electronic devices, has been proposed and investigated. The I-V characteristics of the micro-water-nozzle and effect of applied voltage on the meniscus formation and deformation and ejection processes of de-ionized water on the micro-water-nozzle tip have been investigated. The water ejection processes, such as a drop formation, a drop deformation, a dripping, a cone jet, and an atomization, were taken place on the micro-water-nozzle tip by the electrohydrodynamic forces acted by the DC and AC high voltages applied on the meniscus of the micro-water-nozzle tip. The I-V characteristics of the micro-water-nozzle-to-plate electrode system were different from that of the same metal-point electrode system, due to the meniscus formation and water droplet ejection at the nozzle tip. The positive and negative DC and AC high voltages showed the water droplets ejection, the ejection rates of 1.8, 1.5 and 1.2 g/h respectively, which, however, showed that the proposed micro-water-nozzle-to-plate electrode system could be used as one of an effective pumping means.

Accidental Total Spinal Anesthesia Following Thoracic Epidural Block -A case report- (흉부 경막외 차단 시 발생된 우발적 전척추마취 -증례 보고-)

  • Yang, Se-Ho;Jang, Young-Ho;Cheun, Jae-Kyu
    • The Korean Journal of Pain
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    • v.14 no.2
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    • pp.249-252
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    • 2001
  • Total spinal anesthesia is a serious life threatening complication of spinal and epidural anesthesia. We report an accidental total spinal anesthesia developed during a thoracic epidural block in a practitioner's pain clinic. A 69-year-old female with post-herpetic neuralgia was treated by a thoracic epidural block. A thoracic tapping for the epidural block was performed in the right lateral position at a level between $T_{5-6}$, using a 23 gauge Tuohy needle. After the epidural space was identified, a mixed solution of 10 ml of 0.3% lidocaine and 20 mg of triamcinolone was injected into the epidural space. After removal of the syringe, fluid was dripping through the needle. The patient subsequently complained of dyspnea and dizziness, and she became unconscious. She was intubated immediately and cardiopulmonary resuscitation was performed because there was no pulse palpable. The patient recovered an hour after transfer to a general hospital and was discharged without any further complication 19 days later.

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Effects of shirodhara in generalized anxiety disorder

  • Rastogi, Sanjeev;Baiswar, Antriksha;Nischal, Anil;Srivastava, Prem Swarup;Nischal, Anuradha
    • CELLMED
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    • v.6 no.4
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    • pp.27.1-27.4
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    • 2016
  • Anxiety is a common clinical presentation. Primary anxiety poses a significant problem in its management. Many among the current treatment options of anxiety are habit forming causing significant withdrawal symptoms. There are dose dependent responses often associated with drug adversities. Day time sedation is an undesired effect of many drugs used for anxiety management limiting its usage. Ayurveda recommends a bio- physical procedure to manage anxiety. Shirodhara, a dripping procedure is utilized as a front line therapy for anxiety in Ayurveda. Seeing the limitations of conventional biomedical management of anxiety requiring an improvement upon the existing protocols of managements, and also seeing the use of shirodhara for anxiety management in ayurvedic clinics, a pragmatic study to evaluate the effect of shirodhara in generalized anxiety disorder was done. This was a pragmatic study consisting of shirodhara with ksheer bala oil as an intervention upon generalized anxiety disorder patients. The study was conducted upon 13 patients and observations were done for six weeks. The responses observed through the changes in Hamilton Anxiety Scale were evaluated using paired t test to observe the pre-post significance.

A Survey on the Droplet Generators and Principle of Droplet Generation (액적 발생기의 종류 및 액적 발생 원리에 대한 고찰)

  • Park, Bong-Yeop;Han, Jae-Seob;Kim, Seon-Jin;Kim, Yoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.2
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    • pp.54-60
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    • 2000
  • Most droplet generators are based on the Rayleigh's theory of droplet breakup, and various kind of droplet generation devices have been designed in accordance with vibrating method of capillary liquid column. At present, VOAG(Vibrating Orifice Monodisperse Aerosol Generator) is used to generate primary aerosol standards. For the combustion experiments with isolated single droplet, it is found that dripping method or separating method of suspended drop at an end of filament are more effective. Single drops can be separated from continuous streams of droplets by controlling electric charge.

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Development of an Electrostatic Drop-On-Demand inkjet Device for Display Fabrication Process

  • Son, Sang-Uk;Choi, Jae-Yong;Lee, Suk-Han;Kim, Yong-Jae;Ko, Han-Seo;Kim, Hyun-Cheol;Byun, Do-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.655-659
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    • 2006
  • This paper presents a novel electrostatic drop-on-demand inkjet device featured by a MEMS fabricated pole-type and hole-type nozzle with tube shaped orifice and investigates the feasibility of applying the inkjet device to display fabrication process. The electric voltage signal applied to the ring shaped upper electrode plate, against the hole-shaped ground or pole-shaped ground, referred here pole-type and hole-type nozzle respectively, allows ejection of small droplet to take place: That is, a tiny droplet is taken away from the peak of the mountain shaped liquid meniscus formed at the nozzle orifice. It is verified experimentally that the use of the pole type nozzle allows a stable and sustainable micro-dripping mode of droplet ejection for a wider range of applied voltages and of liquid viscosities. This demonstrates a feasibility of electrostatic drop-on-demand inkjet device as a disruptive alternative to conventional print heads such as thermal bubble or piezoelectric inkjet heads.

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