• Electrical & Electronic Materials
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• v.5 no.3
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• pp.337-343
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• 1992

FeCl$_{3}$등 천이금속 halides를 촉매로 이용하여 poly(3-hexylthiophene) 등의 가용성 polythiophene 유도체를 합성하였다. casting에 의해 작성한 필림은 전해중합 법에 의한 polythiophene 필림과 같은 특성을 나타낸다. Poly(3-hexylthiophene)의 용액 상태의 에너지 밴드 갭은 2.42(eV)이며 이것은 필림상태 보다 고분자 쇄간의 상호작용이 약하므로 밴드 갭이 더 크다. 또한 I$_{2}$를 도우프하면 고차 구조가 달라지므로 poly(3-hexylthiophene)은 polythiophene 보다 도핑속도가 더욱 빠르다.

• Electrical & Electronic Materials
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• v.6 no.3
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• pp.214-219
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• 1993

고온에서 실리콘에 인을 확산시키기 위한 새로운 고체 판상 원료를 개발하였다. Source Wafer는 거품 형태의 골결을 지닌 불활성 재료에 Yttrium metaphosphate가 들어있는 구조로 되어있다. 새로운 고체 판상 원료를 사용하여 고온에서 인을 확산시켜서 재현 가능한 Sheet resistance와 깊은 Junction을 얻었다. 일련의 한 시간 도핑 결과들로부터 새로운 고체 판상 원료의 수명은 40시간 이상인 것으로 판명되었다. 1150.deg.C에서 인의 실리콘에로의 확산에 대한 유효 확산계수와 대응되는 활성화 에너지의 값을 구하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.156-156
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• 2010

A detailed investigation and structure of tested samples are clearly presented. As a reference, $Ge_1Se_1Te_2$/As only sample was also investigated. We used compound of Ge-Se-Te material for phase-change cell. Actually, the performance properties have been improved surprisingly then conventional Ge-Sb-Te. However, crystallization time was as long as ever for amorphization time. We conducted this esperiment in order to solve that problem by doping-As with Ag layer.

• Proceedings of the KIEE Conference
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• 2001.11b
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• pp.106-108
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• 2001

As 3V cathode material, a new doping spinel material, LiMn1.6Se0.4O4 powder with a phase-pure polycrystalline was synthesized by a sol-gel method. In spite of Jahn-teller distortion in 3V region($2.4{\sim}3.5V$), the LiMn1.6Se0.4O4 electrode shows no capacity loss. The material in the 3V region initially delivers a discharge capacity of 100mAh/g which increase with cycling to reach 105mAh/g after 90cycles. And 5V cathode material LiNi0.5-xMxMn1.5O4(M=Cr, V, Fe) compounds have been synthesized by sol-gel method. a series of electroactive spinel compounds, LiNi0.5-xMxMn1.5O4(M=Cr, V, Fe) has been studied by crystallographic and electrochemical methods. The material presents only one plateau at around 4.5 V vs. Li/Li+ with a large discharge capacity of 152mAh/g and fairly good cyclability.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.294-294
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• 2007

Spinel cathode material $LiMn_2O_4$ is currently studied as a promising cathode material for lithium ion secondary batteries for future applications because of it is low cost, easy to be prepared and capable to be operated in high voltage range. However as a cathode material, $LiMn_2O_4$ performs a poor capacity retention which leads to short cycle life. In this study, stoichiometric $LiMn_2O_4$ was synthesized with granulation method with ion substitution to stabilize its structure and niobium doping to improve its conductivity. These well-mixed powders were calcined at $850^{\circ}C$ for 6 hours and its properties were investigated. Correlations of dopant and electrochemical properties were examined as well.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.428-429
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• 2006

In this thesis, verifies electrical-optical characteristics of phosphorescent materials. basic structure of fabricating devices is glass/ITO/$\alpha$-NPD($300{\AA}$)/CBP:Guest($300{\AA}$)/BCP($80{\AA}$)/$Alq_3(100{\AA})$/Al($1000{\AA}$). In efficiency, fabrication of organic light emitting diodes using $Ir(btp)_2acac$ phosphorescent material is external quantum efficiency 0.268% as doping concentration 3%. At CIE coordinates, phosphorescent material $Ir(btp)_2acac$ following materials moves high purity red color(x=0.6686, y=0.3243). The brightness shows $285cd/cm^2$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.305-306
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• 2006

자동차의 난방 열원은 HVAC(Heating, Ventilating & Air Conditioning)에 내장되어 있는 히터코어 (Heater Core) 에서 공급하게 되며, 이 히터코어는 엔진에서 가열된 냉각수 열원을 이용하게 된다. 그러나 최근 디젤 엔진의 경우 연소효율의 개선과 CEGR(Cooled Exhaust Gas Recirculation) 시스템의 적용으로 냉각부하가 증가하여 냉각수가 가지는 가용 열원이 기종보다 약 30~40% 정도 저하되고 있다. 따라서 디젤 자동차 및 하이브리드용 자동차의 난방 보조 히터의 국산화 개발이 시급해진 상황이며 초정밀, 고효율 보조 히터의 개발이 요구되고 있다. 현재 적용되고 있는 보조 히터 중에서 PTC 히터는 PTC 소자의 발열을 이용하여 공기를 직접 가열하기 때문에 추가적인 연료소비가 없고 소형 및 저가라는 장점이 있다. PTC 세라믹 소자는 $BaTiO_3$를 모체로 하며, 이의 특성 항상 및 제어를 위해서는 적절한 dopant를 선택하여 균일하게 doping 해야 한다. 지금까지 dopant에 따른 구성 요소 및 역할은 비교적 잘 알려져 있다. 하지만, 자동차용으로 사용되기 위해서는 12V의 저전압에서 동작해야 하며, 또한 소자의 두께가 얇아지게 됨에 따라서 발생하는 전기적 short와 같은 문제점들을 해결하여야 한다. 따라서 본 연구에서는 PTC 세라믹 소자에서 도펀트 종류와 양 조절을 통한 저저항을 확보하고, PTC 세라믹 소자의 박막화를 달성하고자 하였다.

• Journal of the Korean Ceramic Society
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• v.53 no.4
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• pp.400-405
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• 2016

Ferric oxide (${\alpha}-Fe_2O_3$, hematite) is an n-type semiconductor; due to its narrow band gap ($E_g=2.1eV$), it is a highly attractive and desirable material for use in solar hydrogenation by water oxidation. However, the actual conversion efficiency achieved with $Fe_2O_3$ is considerably lower than the theoretical values because the considerably short diffusion length (2-4 nm) of holes in $Fe_2O_3$ induces excessive charge recombination and low absorption. This is a significant hurdle that must be overcome in order to obtain high solar-to-hydrogen conversion efficiency. In consideration of this, it is thought that elemental doping, which may make it possible to enhance the charge transfer at the interface, will have a marked effect in terms of improving the photoactivities of ${\alpha}-Fe_2O_3$ photoanodes. Herein, we report on the synthesis by pulsed electrodeposition of ${\alpha}-Fe_2O_3$-based anodes; we also report on the resulting photoelectrochemical (PEC) properties. We attempted Ti-doping to enhance the PEC properties of ${\alpha}-Fe_2O_3$ anodes. It is revealed that the photocurrent density of a bare ${\alpha}-Fe_2O_3$ anode can be dramatically changed by controlling the condition of the electrodeposition and the concentration of $TiCl_3$. Under optimum conditions, a modified ${\alpha}-Fe_2O_3$ anode exhibits a maximum photocurrent density of $0.4mA/cm^2$ at 1.23 V vs. reversible hydrogen electrode (RHE) under 1.5 G simulated sunlight illumination; this photocurrent density value is about 3 times greater than that of unmodified ${\alpha}-Fe_2O_3$ anodes.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2011.05a
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• pp.702-705
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• 2011

Poly-Si wafers with resistivity of 1 [${\Omega}$-cm[ and thickness of 50 [${\mu}m$] were used as a starting material. Various efficiency influencing parameters such as rear surface recombination velocity and minority carrier diffusion length in the base region, front surface recombination velocity, junction depth and doping concentration in the Emitter layer, BSF thickness and doping concentration were investigated. Optimized cell parameters were given as rear surface recombination of 1000 [cm/sec], minority carrier diffusion length in the base region 50 [${\mu}m$], front surface recombination velocity 100 [cm/sec], sheet resistivity of emitter layer 100 [${\Omega}/{\Box}$], BSF thickness 0.5 [${\mu}m$], doping concentration $5{\times}10^{19}\;cm^{-3}$. Among the investigated variables, we learn that a diffusion length of base layer acts as a key factor to achieve conversion efficiency higher than 19.8 %. Further details of simulation parameters and their effects to cell characteristics are discussed in this paper.

• Journal of the Korean Ceramic Society
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• v.56 no.4
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• pp.412-420
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• 2019

In this study, the dielectric and polarization properties of manganese (Mn% = 0.0, 0.1, 0.2, 0.5) doped (Pb_0.93La_0.07)(Zr_0.82Ti_0.18)O₃ (PLZT 7/82/18) anti-ferroelectric ceramics were studied for energy storage capacitor and pyroelectric applications. A systematic investigation demonstrated that the electric properties of PLZT 7/82/18 ceramics are affected significantly by the Mn-doping content. A maximum dielectric constant of ~ 2,128 at 1 kHz was found for 0.1% Mn-doped PLZT ceramics with a low dielectric loss of 0.018. The bipolar polarization versus electric field (P-E) hysteresis loops were traced for all compositions showing a typical anti-ferroelectric nature. The breakdown field was found to decrease with Mn-doping. The energy storage density and efficiency were found to be 460 J/㎤ and ~ 63%, respectively, for 0.2% Mn-doped PLZT ceramics. The pyroelectric coefficient of PLZT ceramics shows an increase based on the amount of Mn-doping.