• 제목/요약/키워드: doping material

검색결과 789건 처리시간 0.027초

Influence of the Fluorine-doping Concentration on Nanocrystalline ZnO Thin Films Deposited by Sol-gel Process

  • Yoon, Hyunsik;Kim, Ikhyun;Kang, Daeho;Kim, Soaram;Kim, Jin Soo;Son, Jeong-Sik;Leem, Jae-Young
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
    • /
    • pp.204.2-204.2
    • /
    • 2013
  • Wide band gap II-VI semiconductors have attracted the interest of many research groups during the past few years due to the possibility of their applications in light-emitting diodes and laser diodes. Among the II-VI semiconductors, ZnO is an important optoelectronic device material for use in the violet and blue regions because of its wide direct band gap (Eg ~3.37 eV) and large exciton binding energy (60 meV). F-doped ZnO (FZO) and undoped ZnO thin films were grown onto quartz substrate by the sol-gel spin-coating method. The doping level in the solution, designated by F/Zn atomic ratio of was varied from 0 to 5 in 1 steps. To investigate the effects of the structure and optical properties of FZO thin films were investigated using X-ray diffraction (XRD), UV-visible spectroscopy, and photoluminescence (PL). In the XRD, the residual stress, FWHM, bond length, and average grain size were changed with increasing the doping concentration. For the PL spectra, the high INBE/IDLE ratio of the FZO thin films doping concentration at 1 at.% than the other samples.

  • PDF

이차원 SnSe2 전자소재의 Cl 도핑에 따른 고온 전도 물성 고찰 (Study on the Change of Electrical Properties of two-dimensional SnSe2 Material via Cl doping under a High Temperature Condition)

  • 문승필;김성웅;손희상;김태완;이규형;이기문
    • 마이크로전자및패키징학회지
    • /
    • 제24권2호
    • /
    • pp.49-53
    • /
    • 2017
  • Cl 불순물 도핑에 따른 $SnSe_2$ 이차원 전자소재의 고온(300~450 K) 전도 물성 변화를 고찰하였다. 고상합성법을 통하여, 도핑이 없는 $SnSe_2$ 소재와 Cl이 도핑된 $SnSe_{1.994}Cl_{0.006}$ 소재를 합성하였으며, X선 회절 실험을 통하여, 두 재료 모두 불순물 없는 단일상이 형성되었음을 확인하였다. 비저항의 온도의존성 측정을 통하여, 전기 전도 mechanism이 Cl 도핑에 의해 hopping 전도에서 축퇴 전도로의 전이가 일어남을 관찰할 수 있었으며, 홀효과 측정을 통해 그러한 전도 mechanism의 전이가, Cl의 효과적인 donor 역할에 따른 자유전자의 농도 증가에서 기인한 것임을 확인하였다. 온도에 따른 전자이동도의 변화 분석을 통하여, 도핑이 없는 $SnSe_2$의 고온 전기 전도는 grain boundary 산란이 지배적인 영향을 미치는 반도체 전도 특성을 보이는 반면, Cl 도핑에 따라 grain boundary 산란 효과가 저하되는 금속 전도 특성을 보인다는 것을 알 수 있었다.

단일 호스트를 이용하여 선택적으로 도핑된 백색 OLED 제작 (Fabrication of White Organic light Emission Device Using Selective Doping in a Single Host)

  • 서유석;문대규
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
    • /
    • pp.74-75
    • /
    • 2009
  • White light emitting device based on a red fluorescence material (5,6,11,12)-Tetraphenylnaphthacene(Rubrene) has been fabricated. The white OLED consists of it and a blue phosphorescent material FIrPic (iridum-bis(4,6,-difluorophenylpyridinato-N,C2)-picolinate) The threshold voltage is 5.3V, and the brightness reaches $1000\;cd/m^2$ at 11V, $14.5\;mA/cm^2$. The color of the light corresponds to a CIE coordinate of (0.30, 0.38). The highest efficiency of the device can reach 9.5 cd/A or 5.5 1m/W at 6V, $0.1mA/cm^2$.

  • PDF

단일 호스트를 이용하여 선택적으로 도핑된 OLEDs의 전기 및 광학적 특성 (Electrical and Optical Properties of Organic Light Emission Devices using Selective Doping in a Single Host)

  • 서유석;문대규
    • 한국전기전자재료학회논문지
    • /
    • 제23권2호
    • /
    • pp.124-127
    • /
    • 2010
  • We have fabricated organic white light emitting device by two colors from yellow fluorescence material (5,6,11,12)-Tetraphenylnaphthacene(Rubrene) and blue phosphorescent material (iridum-bis(4,6-difluorophenylpyridinato-N,C2)-picolinate(FIrpic). The threshold voltage is 5.3 V, and the brightness reaches 1000 cd/$m^2$ at 11 V, 14.5 mA/$m^2$. The color of the light corresponds to a CIE coordinate of (0.30, 0.38). The highest efficiency of the device can reach 9.5 cd/A or 5.5 lm/W at 6 V, 0.1 mA/$m^2$.

Examination of Diffusion Process for High-speed Avalanche Photodiode Fabrication

  • Ilgu Yun;Hyun, Kyujg-Sook;Kwon, Yong-Hwan;Pyun, Kwang-Eui
    • 한국전기전자재료학회논문지
    • /
    • 제13권11호
    • /
    • pp.954-958
    • /
    • 2000
  • The characterization of zinc diffusion processes applied for high-speed avalanche photodiodes has been examined. The different diffusion process conditions for InP test structures were explored. The zinc diffusion profiles, such as the diffusion depth and the zinc dopant concentration, were examined using secondary ion mass spectrometry with varying the process variables and material parameters. It is observed that the diffusion profiles are severly impacted on the process parameters, such as the amount of Zn$_3$P$_2$ source and the diffusion time, as well as material parameters, such as doping concentration of diffusion layer. These results can be utilized for the high-speed avalanche photodiode fabrication.

  • PDF

Study of Zinc Diffusion Process for High-speed Avalanche Photodiode Fabrication

  • Ilgu Yun;Hyun, Kyung-Sook;Pyun, Kwang-Eui
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.731-734
    • /
    • 2000
  • The characterization of Zinc diffusion processes applied fur high-speed avalanche photodiodes has been examined. The different diffusion process conditions for InP test structures were explored. The Zinc diffusion profiles, such as the diffusion depth and the Zinc dopant concentration, were examined using secondary ion mass spectrometry with varying the process variables and material parameters. It is observed that the diffusion profiles are severely impacted on the process parameters, such as the amount of Zn$_3$P$_2$source and the diffusion time, as well as material parameters, such as doping concentration of diffusion layer. These results can be utilized for the high-speed avalanche photodiode fabrication.

  • PDF

미분의 구형 형광체 제초에 있어서 융제의 영향 (The Effect of Flux on the Preparation of Spherical Fine Phosphor Particles)

  • 노현숙;강윤찬;서대종
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
    • /
    • pp.570-573
    • /
    • 1999
  • High brightness (Y$_{x}$/Gd$_{1-x}$ )$_2$O$_3$:Eu Phosphor Particles were directly Prepared in the spray Pyrolysis by adding flux materials such as LiCl and HBO$_3$. The (Y$_{x}$/Gd$_{1-x}$ )$_2$O$_3$:Eu particles prepared from solution with flux material had higher PL (photoluminescence) intensities than those prepared from solution without flux. In the spray pyrolysis, the flux acts as promoter of the growth of crystallite and activation of doping material as in the solid state reaction method. Additionally, the flux improved PL intensity of (Y$_{x}$/Gd$_{1-x}$ )$_2$O$_3$:Eu phosphor particles by densifying the internal structure and eliminating the defect existing inside and surface of (Y$_{x}$/Gd$_{1-x}$ )$_2$O$_3$:Eu phosphor particles.r particles.

  • PDF

솔벤트 도핑과 후처리 공정에 따른 전도성 고분자 PEDOT : PSS의 특성 변화 (Effect of Solvent Doping and Post-Treatment on the Characteristics of PEDOT : PSS Conducting Polymer)

  • 김진희;서윤경;한주원;오지윤;김용현
    • 공업화학
    • /
    • 제26권3호
    • /
    • pp.275-279
    • /
    • 2015
  • 전도성 고분자인 poly(3,4-ethylenedioxythiophene) : poly(styrenesulfonate) (PEDOT : PSS)는 우수한 전기 전도도와 광투과도, 유연성을 가지고 있기 때문에 유기태양전지와 유기발광소자의 투명전극으로서 많은 각광을 받고 있다. PEDOT : PSS의 전기 전도도는 솔벤트를 도핑함에 따라 큰 폭으로 증가한다는 사실은 잘 알려져 있다. 본 연구에서는 다양한 솔벤트의 도핑과 솔벤트 후처리 공정에 따른 PEDOT : PSS 박막의 전기 전도도와 구조적 특성 변화를 연구하였다. 솔벤트 도핑으로 PEDOT : PSS의 전도도는 884 S/cm까지 증가하였고, 후처리 공정을 통해서 1131 S/cm의 전도도 값을 얻을 수 있었다. 이러한 전도도의 증가는 PSS 물질이 빠져나가거나 구조적인 재배열에 따른 전도성 PEDOT 입자의 접촉 면적이 증가함에 따른 것으로 사료되고, 광학적인 방법으로 PSS의 추출을 관찰하였다. 솔벤트 후처리 공정은 PEDOT : PSS 박막의 전도도를 향상하는 매우 효과적인 방법으로 확인되었고, 저가형 플렉서블 유기전자소자의 투명전극으로써의 사용이 적합할 것으로 예상된다.

비스무스계 무연 압전 세라믹스의 상전이 거동 및 전기 기계적 변형 특성에 대한 La2O3 도핑 효과 연구 (Effects of La2O3 Doping on Phase Transition Behavior and Electromechanical Strain Properties in Bismuth-Based Lead-Free Piezoelectric Ceramics)

  • 강은서;형성재;강유빈;박민성;즈엉 짱 안;이재신;한형수
    • 한국전기전자재료학회논문지
    • /
    • 제37권4호
    • /
    • pp.457-463
    • /
    • 2024
  • (Bi1/2Na1/2)TiO3(BNT) piezoelectric ceramics are one of the promising materials that can replace Pb(Zr, Ti)O3(PZT) piezoelectric ceramics due to the high electromechanical strain properties. However, it is still difficult to use practical applications because the required electric field for inducing electromechanical strain is relatively higher than that of PZT ceramics. To overcome this problem, it has been intensively studied on doping impurity or modifying other ABO3 for BNT-based piezoelectric ceramics. Therefore, this study investigated the effects of La2O3 doping on the phase transition behavior and electromechanical strain properties in BNT-SrTiO3 (BNT-ST) lead-free piezoelectric ceramics. In the case of the temperature-dependent dielectric properties, it was confirmed that a phase transition from ferroelectrics to relaxors is induced with increasing La2O3 content. As a result, the electromechanical strain properties of BNT-ST ceramics were improved. The highest Smax/Emax value corresponding to 300 pm/V was obtained at 2 mol% La2O3-dopped BNT-ST ceramics. Accordingly, this study successfully demonstrated that La2O3 doping is effective on the inducing phase transition from ferroelectrics to relaxors and the improving electromechanical strain properties of BNT-ST lead-free piezoelectric ceramics.

Spark Plasma Sintering 법으로 제조한 CoSb3 Skutterudite계 열전소재의 n형 첨가제 효과 (Effect of n-type Dopants on CoSb3 Skutterudite Thermoelectrics Sintered by Spark Plasma Sintering)

  • 이재기;최순목;이홍림;서원선
    • 한국재료학회지
    • /
    • 제20권6호
    • /
    • pp.326-330
    • /
    • 2010
  • $CoSb_3$ Skutterudites materials have high potential for thermoelectric application at mid-temperature range because of their superior thermoelectric properties via control of charge carrier density and substitution of foreign atoms. Improvement of thermoelectric properties is expected for the ternary solid solution developed by substitution of foreign atoms having different valances into the $CoSb_3$ matrix. In this study, ternary solid solutions with a stoichiometry of $Co_{1-x}Ni_xSb_3$ x = 0.01, 0.05, 0.1, 0.2, $CoSb_{3-y}Te_y$, y = 0.1, 0.2, 0.3 were prepared by the Spark Plasma Sintering (SPS) system. Before the SPS synthesis, the ingots were synthesized by vacuum induction melting and followed by annealing. For phase analysis X-ray powder diffraction patterns were checked. All the samples were confirmed as single phase; however, with samples that were more doped than the solubility limit some secondary phases were detected. All the samples doped with Ni and Te atoms showed a negative Seebeck coefficient and their electrical conductivities increased with the doping amount up to the solubility limit. For the samples prepared by SPS the maximum value for dimensionless figure of merit reached 0.26, 0.42 for $Co_{0.9}Ni_{0.1}Sb_3$, $CoSb_{2.8}Te_{0.2}$ at 690 K, respectively. These results show that the SPS method is effective in this system and Ni/Te dopants are also effective for increasing thermoelectric properties of this system.