• Journal of Korean Society for Atmospheric Environment
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• v.8 no.4
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• pp.269-276
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• 1992

Typical lebvels of heavy metal exposure for humans may be attributed to four components in the environment ; food, inhaled air, various types of dust, and drinking water. To assess the health risk of lead, it is necessary to estimate the blood lead levels in the populations of concern under various air lead concentrations. The blood lead levels of the population in Seoul and Yeoju are estimated by Biokinetic model for the risk assessment in this study. The differences in blood lead levels between areas of different land use are not dominant but some differences show among different age groups and sex. Blood lead levels of the population show log normal distribution. The geometric standard deviation values of blood lead levels are in the range of 1.25 ~ 1.39, it is somewhat smaller than the values in the general U.S pollution which are determined to be from 1.31 to 1.41 by the U.S. EPA.

• Journal of Environmental Science International
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• v.27 no.7
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• pp.477-488
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• 2018

In this study, heavy metal levels at the sediment monitoring network site upstream of the Gangjeong-Goryeong weir in the Nakdong River were surveyed from 2012 to 2016. We assessed the sediment pollution level using various pollution indexes based on ICP-MS analysis. The stream sediment pollution assessment standard, established through Regulation No. 687 of the National Institute of Environmental Research (2015), pollution load index (PLI), potential ecological risk index (RI), and mean PEL Quotient (mPELQ) were used to evaluate the sediment pollution level. We verified the representativeness of the monitoring point through the distribution of sedimentation and scour behavior by river bed surveying using anacousticDopplercurrentprofiler.

• Herbal Formula Science
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• v.19 no.1
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• pp.183-194
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• 2011

Objectives : To estimate the shelf-life by long-term storage test of Pyungwi-san. Methods : Experiments were conducted to evaluate the stability such as the selected physicochemical, heavy metal, microbilogical experiment under an acceleration test and long-term storage test of Pyungwi-san in different storage under room temperature, refrigeration and freezing. Futhermore, HPLC analysis was performed for the determinations of glycyrrhizin in the Pyungwi-san on an Inertsil ODS-3 column(250 mm ${\times}$ 4.6 mm, 5 um) using solvent 35% acetonitrile include 0.05% phosphoric acid at 254 nm. The flow rate was 1.0 mL/min. Results : The significant change was not showed in pH, heavy metal, microbiological, identification test and quantitative analysis based on acceleration test and long-term storage test. Retention time of glycyrrhizin in HPLC chromatogram was about 16.065 min and calibration curve showed good linearity($R^2$ = 0.9999). The contents of glycyrrhizin in acceleration test and long-term storage test were 0.068~0.076 mg/mL and 0.066~0.077 mg/mL, respectively. Shelf-lifes of room temperature, refrigeration and freezing by long-term storage test were predicted 41, 24 and 34 months, respectively. Conclusions : The suggested shelf-life would be helpful on the storage and distribution of herbal medicine.

• Analytical Science and Technology
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• v.14 no.5
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• pp.442-450
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• 2001

In this study, we collected PM10(particulate matter less than $10{\mu}m$) by using a high volume air sampler from March 2000 to September 2000 to investigate the contamination level and the distribution characteristics of heavy metals in the ambient air in Ulsan area. Samples were pretreated by the microwave extraction methods, and heaby metals (Cr, Cu, Zn, Cd, Ni, As, and Pb) were quantified by using and ICP-MS system. The highest PM10 concentrations in the ambient air were $85.6{\mu}g/m^3$ and the aberage value was $37.1{\mu}g/m^3$. The maximum levels of each heavy metal were as follows: $2.5{\mu}g/m^3$ for Fe(Yeocheon-dong), $0.41{\mu}g/m^3$ for Zn(Nammok-2-dong), $0.061{\mu}g/m^3$ for Cd(Yeocheon-dong), $0.20{\mu}g/m^3$ for Pb(Yeocheon-dong), $0.037{\mu}g/m^3$ for Ni(Yeoncheon-dong), $0.88{\mu}g/m^3$ for Cu(Yaeum-dong), $0.042{\mu}g/m^3$ for Cr(Yaeum-dong), and $0.015{\mu}g/m^3$ for As(Onsan). Among concentration of heavy metals, Ni and Zn compounds were highly correlated with a correlation coefficient of 0.87 at Nammok-2-dong.

• Journal of environmental and Sanitary engineering
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• v.9 no.1
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• pp.53-61
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• 1994

Sungnam city, as a major satellite town, is located in the southeast of Seoul. Atmospheric conditions are so stable that air pollutants from various emissions are tend to resist change because Sungnam city is located in the Namhansansung valley. The industrial distribution of Sungnam city are composed of various manufactories such as foods, fibers, chemicals, machinery and electronics etc. The heavy metal concentrations and size distribution are the most important parameters influencing among the way in which respirable suspended particulate matter interact with the human respiratory system. Respirable suspended particulate matter was collected on glass fiber filters from April 1993 to February 1994 according to particle size using Anderson sampler during 10 days per month at Sungnam city. 6 heavy metals, Fe, Zn, Pb Mn, Cu and Cd, were analyzed by particle size with atomic absorption spectrophotometry . The results could be summarized as follows: 1. The annual arithmetic mean concentration of total suspended particulate was 116.3$\mu $g/m$^{3}$ m', seasonal variation was the highest in spring season(196.5$\mu $g/m$^{3}$) and the lowest in Summer Season(72.9$\mu $g/m$^{3}$). 2. The ratio of airborne particulate concentrations respirable to nonrepairable( Res/Non- Res) of annual arithmetic mean value was 5.8'1, seasonal variation was highest in the spring season(6.3 : 1) and lowest in the summer season(4.6 : 1). 3. During the spring season the shape of the size distribution was trimodal which showed peaks at 3 size groups, which were below of 0.43$\mu $m, 3.3∼4.7$\mu $m and above of 11.0$\mu $g/m$^{3}$ respectively. 4. Respirable suspended particulate matter concentrations of Zn, Pb Cu and Cd were the highest in below of 0.43$\mu $m as follows; 0.517$\mu $g/m$^{3}$, 0.411 $\mu $g/m$^{3}$, 0.062$\mu $g/m$^{3}$ and 0.0310$\mu $g/m$^{3}$ , respectively, Fe and Mn were the highest in the particle size range of 4.7 ∼ 7.0$\mu $m as follows; 2.504$\mu $g/m$^{3}$ and 0.095$\mu $g/m$^{3}$, respectively. 5. The Pt Cd, Zn, Cu, Fe and Mn concentrations of annual arithmetic mean value respirable to non- respirable( Res/Non- Res ) were 33.65, 19.27, 17.74, 10.54, 3.20 and 5.20, respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.2
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• pp.158-164
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• 1996

This survey was conducted to investigate the distribution of heavy metal contents in medicinal plants and soils. Plant and soil samples were collected at 254 sites(Angelica gigas : 81, Astragalus membranceus : 38, Platycodn glandiflorum : 36, Paeonia albilora : 34, Codonopsis lanoceolata : 32, Ligusticum chuanxiong : 17, Bupleurum falcatum : 16, respectively) over the country, Soil texture, pH values and heavy metal content of soils and medicinal plants were evaluated as major factors. Soil texture classification showed that sandy loam, loam, loamy sand and silt loam were 46.1%, 26.0%, 19.3% and 8.6% of the total, respectively. The contents of O.M, Ex.Ca. Ex.Mg and EC value were higher in loamy(sandy loam, loam and silt loam)soils than in sandy(loamy sand)soils, but available $P_2O_5$ contents of loamy sand soils were higher than those of sandy loam, loam, and silt loam. The contents of Cd, Cu, Pb, Zn and Ni in soil were high in loamy soils, while Cr content was high in loamy silt soils. The contents of Cu and Cr in Angelica gigas were high in loamy soils, and those of Pb in Astragalus membranceus, Paeonia albiflora and Codonopsis lanoceolata were high in sandy loam soils. Correlation coefficients between heavy metal contents in medicinal plants and their soils with soil texture were positively correlated in sandy loam and loam at Cu, loam at Zn, sandy loam, loam and loamy sand at Cr, respectively. Correlation coefficients between pH value of the soils and contents of Cd, Zn and Ni in medicinal plants were negatively correlated, but those of Cd, Pb, Zn and Ni in soils were positively correlated.

• The Korean Journal of Ecology
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• v.24 no.1
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• pp.35-43
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• 2001

Accumulation, elimination and subcellular distribution of heavy metals in Littorina brevicula exposed to cadmium and zinc separately and concurrently were investigated. When the winkles had been exposed to 400 ㎍/L CdCl₂ and 3000 ㎍/l ZnSO₄ separately for 90 days, each of the metal body burden in the whole sofl parts increased in proportion to time of exposure until 70 days. But it didn't increase after 70 days. But when the winkles had been exposed to cadmium and zinc simultaneously, cadmium body burden decreased but zinc body burden increased as compared to the winkles exposed to each of the metal. We also found that cadmium accumulated in the winkles was not depurated for 42 days, but zinc accumulated in them was depurated. Especially, zinc was depurated faster when they had been exposed to mixture of cadmium and zinc. After the winkles had been exposed to cadmium and zinc separately for 70 days, about 60% cadmium of the total body burden was associated with the soluble fraction, while about 75% zinc of the total body burden was associated with insoluble fraction. And these trends of metal partitioning did not alter when the winkles had been exposed to metal mixture. After the soluble fraction applied to gel-filtration chromatography column, the distribution patterns of cadmium and zinc associated with proteins or ligands were different each other. Most of cadmium (＞90%) in the soluble fraction was bound to MBP-1 (Metal-binding protein-1), about 6.5 kDa), while zinc was distributed evenly to HMW (High molecular weight fraction, >60 kDa), MBP-1, MBP-2 (about 5 kDa), LMW (Low molecular weight fraction, <1 kDa).

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.4
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• pp.283-296
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• 2014

The distribution of heavy metals in the stormwater runoffs from industrial sites around Shihwa Lake that implements the total pollutant load management system (TPLMS) was studied to characterize the temporal changes of metal concentrations and to assess the ecological risk in dissolved and particulate phases of the selected metals. The dissolved Co and Ni concentration demonstrated first flush and tended to decrease with increasing of the duration of rainfall. The intensity of precipitation was found to be the main controlling factor of particulate metals in the stromwater runoffs. The particulate concentration of Pb accounted for 97.2% so the particulate phase was its main form. Other metals followed the sequence: Pb>Cu>Cd>Co>Zn>Ni. The particulate-dissolved partitioning coefficient ($K_d$) indicated that the $K_d$ of Pb were bigger than that of other metals because the metal Pb in the stormwater runoffs is quickly removed into the particulate phase. In a single day rainfall event, total runoff fluxes for total metals as the sum of dissolved and particulate forms through only two sewer outlets were 2.21 kg for Co, 30.5 kg for Ni, 278.3 kg for Cu, 398.3 kg for Zn, 0.39 kg for Cd and 40.0 kg for Pb, respectively. Given the annual rainfall, the number of rain days and the basin area for total pollutant load management system (TPLMS) of Shihwa area, enormous amount of non-point metal pollutants were entered into Lake with any treatment. The dissolved metals (e.g., Ni, Cu and Zn) in the stormwater runoffs exceeded the acute water quality criteria. Additionally, all metals were significantly enriched in the particulate phase and exceeded the PEL criteria of sediment quality guidelines (SQGs). These results indicated that the heavy metals in the stormwater runoffs may pose a very high ecological risk to the coastal environments and ecosystem.

• Analytical Science and Technology
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• v.25 no.6
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• pp.441-446
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• 2012

In this study, mercury, methylmercury and heavy metals in sediment from the lake Andong were analyzed, along with the estimation of mercury flux between sediments and water in the lake Andong. Average mercury concentrations in sediments sampled in 2009~2011 were $155.0{\pm}71.9$ ng/g, $211{\pm}62$ ng/g and $198{\pm}6.88$ ng/g, respectively. The average methylmercury concentration were $1.85{\pm}1.09$ ng/g (2009) and $3.49{\pm}1.79$ ng/g (2011), and %methylmercury, the fraction of methylmercury in total mercury were $1.17{\pm}0.39%$ and $1.77{\pm}0.94%$, respectively. Heavy metal (Zn, Cd, Pb, Cu) concentrations of the sediments exceeded ERL (Effect Range Low) level of US NOAA (National Oceanic and Atmospheric Administration)'s sediment quality criteria. Estimated mercury sedimentation flux was found to be 83.7 $ng/cm^2{\cdot}yr$ and mercury diffusion flux was estimated as 1.24 $ng/cm^2{\cdot}yr$.

• Journal of the Korean earth science society
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• v.24 no.7
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• pp.635-649
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• 2003

Heavy metal concentrations and benthic foraminiferal distributions were investigated in three short sediment cores in order to understand the pollution history in Masan Bay. Sedimentation rates were 0.33 cm/yr, 0.20 cm/yr and 0.33 cm/yr in the inner bay, the out fall of Dugdong sewage disposal plant, and bay mouth, respectively. The rapid increases of copper, zinc and lead concentrations at the core depth of 10 cm the upper part indicated that Masan Bay has been polluted with industrial wastes since the 1940s. Benthic foraminifera in core sediments show that the variations in their distribution were followed by industrial pollution in the bay. The number of individuals and species diversity decreased, whereas agglutinated tests increased upward in the cores with increased heavy metal pollution. These shifts effectd the abundance of few tolerant forms and consequently decreased the species diversity. The opportunistic species Eggerella advena and Trochammina pacifica increased in polluted sediments. These species can be used as an indicator for assessments of environmental quality in Masan Bay.