• Title/Summary/Keyword: distribution of chemical species

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Aerosol Characteristics at Tokchok Island in the Yellow Sea (황해상 덕적도의 대기 에어로졸 특성)

  • 이승복;배귀남;김용표;진현철;윤용석;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.305-316
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    • 2002
  • Various air pollutants were measured at Tokchok Island in the Yellow Sea that is about 50 km distant from Incheon since April 1999. This study was undertaken to help understanding the level of air pollution and its distribution characteristics over the Yellow Sea. The geographical characteristics of the air pollution monitoring station and emission inventories of Tokchok Island are introduced. The mass concentrations and chemical compositions of TSP and P $M_{2.5}$ measured until March 2000 are discussed in this paper. The overall average mass concentrations are about 37.2 $\mu\textrm{g}$/㎥ for TSP and 18.7 $\mu\textrm{g}$/㎥ for P $M_{2.5}$ , respectively, which are similar to or a little lower than the values observed in other background sites at Kangwha and Taean. However, they are much lower than those observed at Qingdao in China. The low mass concentration and major anthropogenic ion concentrations in aerosols collected at Tokchok Island show that local sources are not dominant at Tokchok Island. The estimated average fractions of anthropogenic non-sea-salt sulfate to the total sulfate concentration of TSP and P $M_{2.5}$ are greater than 80% for both sizes. It hence suggests that the sulfate be mainly affected by anthropogenic sources. If we consider the average mass ratio of P $M_{2.5}$ to TSP, the mass fractions of anthropogenic species to P $M_{2.5}$ , and the molar ratio of nss S $O_4$$^{2-}$ to total N $O_{3-}$, it may be possible to infer that a part of anthropogenic species measured at Tokchok Island be transported from China. The characteristics of neutralization of nss S $O_4$$^{2-}$ and the particle size of major ions are also discussed.

Ecological Environment of Native Habitats and Host Plant in Mistletoe (Viscum album var. coloratum) (겨우살이의 서식지생태환경과 기주식물)

  • Lee, Bo-Duk
    • Korean Journal of Plant Resources
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    • v.22 no.5
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    • pp.389-393
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    • 2009
  • Regional distribution of mistletoe (Viscum album var.coloratum) and its habitual environments were investigated in order to obtain the basal data on the artificial propagation to cope with its increasing consume for medicine. Mistletoes inhabited throughout the overall region of the South Korea investigated. They were parasitic mainly to the Quercus spp. including Q. serrata and rarely to the Castanea crenata var. dulcis, Prunus serrulata var. spontanea, Alnus japonica, and Pyrus pyrifolia, etc. Mistletoes were not observed on the conifers such as Pinus densiflora and Pinus koraiensis and some deciduous broad-leaved trees species such as Zelkova serrata, Diospyros kaki, Acer mono, Acer palmatum, and Morus alba. Their habitats were located from zero to 1,200 m above sea level nevertheless the direction or slope of the mountains, suggesting that artificial propagation can be carried out nation widely to the well-grown parasite tree species. Parasitic specificity related to the physical and chemical characteristic of the epidermal tissues will be studied further.

Establishment of the Physicochemical and Radiological Database of Raw Materials and By-Products in Domestic Distribution (국내 유통중인 원료물질 및 공정부산물의 물리화학적 및 방사선적 특성 데이터베이스 구축)

  • Lim, Chung-Sup;Lim, Jong-Myoung;Park, Ji-Young;Chung, Kun Ho;Kim, Chang-Jong;Chang, Byung-Uck;Ji, Young-Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.4
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    • pp.331-341
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    • 2016
  • To evaluate the physicochemical and radiological properties of raw materials and by-products in domestic distribution, about 220 samples with 16 species were prepared. We measured the energy spectrum and the chemical content, such as U, Th, and K, using a $LaBr_3$ scintillation detector and ED-XRF. In addition, HPGe detector was used to analyze the radioac-tivity of $^{234}Th$, $^{234}mPa$, and $^{214}Bi$ in uranium decay series and $^{228}Ac$, $^{212}Pb$, and $^{208}Tl$ in thorium decay series, and $^{40}K$. The correlation between characteristic variables, such as the count rate in several ROIs, chemical content, and radioactivity, was assessed to infer the radioactivity of natural radionuclides through a rapid screening method. Based on the results, a characteristic database for raw material and by-product in domestic distribution was established and it will provide useful information in the analysis procedure and improve the accuracy and reproducibility in the analysis of natural radionuclides.

Assessment of Reliability when Using Diagnostic Binary Ratios of Polycyclic Aromatic Hydrocarbons in Ambient Air PM10

  • Pongpiachan, Siwatt
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.18
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    • pp.8605-8611
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    • 2016
  • The reliability of using diagnostic binary ratios of particulate carcinogenic polycyclic aromatic hydrocarbons (PAHs) as chemical tracers for source characterisation was assessed by collecting PM10 samples from various air quality observatory sites in Thailand. The major objectives of this research were to evaluate the effects of day and night on the alterations of six different PAH diagnostic binary ratios: An/(An + Phe), Fluo/(Fluo + Pyr), B[a]A/(B[a]A + Chry), B[a]P/(B[a]P + B[e]P), Ind/(Ind + B[g,h,i]P), and B[k]F/Ind, and to investigate the impacts of site-specific conditions on the alterations of PAH diagnostic binary ratios by applying the concept of the coefficient of divergence (COD). No significant differences between day and night were found for any of the diagnostic binary ratios of PAHs, which indicates that the photodecomposition process is of minor importance in terms of PAH reduction. Interestingly, comparatively high values of COD for An/(An + Phe) in PM10 collected from sites with heavy traffic and in residential zones underline the influence of heterogeneous reactions triggered by oxidising gaseous species from vehicular exhausts. Therefore, special attention must be paid when interpreting the data of these diagnostic binary ratios, particularly for cases of low-molecular-weight PAHs.

Urban Thermo-profiles and Community Structure of Quercus mongolica Forests along an Urban-rural Land Use Gradient: Implications for Management and Restoration of Urban Ecosystems

  • Cho, Yong-Chan;Cho, Hyun-Je;Lee, Chang-Seok
    • Journal of Ecology and Environment
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    • v.32 no.3
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    • pp.167-176
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    • 2009
  • Land cover changes associated with urbanization have driven climate change and pollution, which alter properties of ecosystems at local, regional, and continental scales. Thus, the relationships among urban ecological variables such as community composition, structure, health, soil and functioning need to be better understood to restore and improve urban ecosystems. In this study, we discuss urban ecosystem management and research from a futuristic perspective based on analyses of vegetation structure, composition, and successional trends, as well as the chemical properties of soils and the distribution of heat along an urban-rural gradient. Urban thermo-profile analysis using satellite images showed an obvious mitigating effect of vegetation on the Seoul heat island. Community attributes of Quercus mongolica stands reflected the effects of urbanization, such as pronounced increases in disturbance-related and pollution-tolerant species, such as Styrax japonica and Sorbus alnifolia. Retrogressive successional trends were detected in urban sites relative to those in rural sites. Changes in the urban climate and biotic environment have the potential to significantly influence the practice and outcomes of ecological management, restoration and forecasting because of the associated changes in future bio-physical settings. Thus, for management (i.e., creation and restoration) of urban green spaces, forward-thinking perspectives supported by historical information are necessary.

$C_{x}F_{y}$ Polymer Film Deposition in rf and dc $C_{7}F_{16}$ Vapor Plasmas

  • Sakai, Y.;Akazawa, M.;Sakai, Yosuke;Sugawara, H.;Tabata, M.;Lungu, C.P.;Lungu, A.M.
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.1
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    • pp.1-6
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    • 2001
  • $C_{x}F_{y}$ polymer film was deposited in rf and dc Fluorinert vapor ($C_{7}F_{16}$) plasmas. In the plasma phase, the spatial distribution of optical emission spectra and the temporal concentration of decomposed species were monitored, and kinetics of the $C_{7}F_{16}$ decomposition process was discussed. Deposition of $C_{x}F_{y}$ film has been tried on substrates of stainless steel, glass, molybdenum and silicon wafers at room temperature in the vapor pressures of 40 and 100 Pa. The films deposited in the rf plasma showed excellent electrical properties as an insulator for multi-layered interconnection of deep-submicron LSI, i.e. the low dielectric constant ∼2.0, the dielectric strength ∼2 MV/cm and the high deposition rate ∼100nm/min at 100W input power.

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Chemical Characterization of Water-Soluble Organic Acids in Size-Segregated Particles at a Suburban Site in Saitama, Japan

  • Bao, Linfa;Sakamoto, Kazuhiko
    • Asian Journal of Atmospheric Environment
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    • v.3 no.1
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    • pp.42-51
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    • 2009
  • Saturated n-dicarboxylic acids ($C_2-C_7$, $C_9$), unsaturated dicarboxylic acids (maleic, fumaric, phthalic acid), ketocarboxylic acids (pyruvic, glyoxylic acid), and dicarbonyls (glyoxal, methylglyoxal) were determined in size-segregated samples with a high-volume Andersen air sampler at a suburban site in Saitama, Japan, May 12-17 and July 24-27, 2007 and January 22-31, 2008. The seasonal average concentrations of these detected organic acids were 670 $ng/m^3$, accounting for about 4.4-5.7% (C/C) of water-soluble organic carbon (WSOC) and 2.3-3.6% (C/C) of organic carbon (OC). The most abundant species of dicarboxylic acids was oxalic acid, followed by malonic, phthalic, or succinic acids. Glyoxylic acid and methyglyoxal were most abundant ketocarboxylic acid and dicarbonyl, respectively. Seasonal differences, size-segregated concentrations, and the correlations of these acids with ambient temperatures, oxidants, elemental carbon (EC), OC, WSOC, and ionic components were also discussed in terms of their corresponding sources and possible secondary formation pathways. The results suggested that photochemical reactions contributed more to the formation of particulate organic acids in Saitama suburban areas than did direct emissions from anthropogenic and natural sources. However, direct emissions of vehicles were also important sources of several organic acids in particles, such as phthalic and adipic acids, especially in winter.

Study on Coal Combustion Characteristics with 1MWth Test Facility (1MWth 실험연소로를 이용한 석탄의 연소특성 연구)

  • Jang, Gil Hong;Chang, In Gab;Jeong, Seok Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1464-1472
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    • 1999
  • Design and operation of $1MW_{th}$ pulverized coal combustion testing facility are described. Also the influence of air staging on NOx emission and burnout of coal flames was investigated in this facility. The test facility consisted of coal feeding system, firing system and flue gas treatment system. A top-fired externally air staging burner was adopted in order to avoid influence of gravity on the coal particles and for easy maintenance. Distribution of temperature and chemical species concentration of coal flames could be measured in vertical pass of furnace. Main fuel was pulverized (83.4% less than $80{\mu}m$) Australian high bituminous coal. From variety of test conditions, overall excess air ratio was selected at 1.2(20% excess air). Tho study showed that increasing the staged air resulted in lower NOx omission, and it was suggested to be more than 40% of the total combustion air for the substantial NOx reduction. Sufficient burnout was not achievable when NOx emission was less than 500ppm. Also, the amount of core air did not influence tho NOx reduction.

The Study of Cyanobacterial Flora from Geothermal Springs of Bakreswar, West Bengal, India

  • Debnath, Manojit;Mandal, Narayan Chandra;Ray, Samit
    • ALGAE
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    • v.24 no.4
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    • pp.185-193
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    • 2009
  • Geothermal springs in India, formed as a result of volcanic or tectonic activities, are characterized by high temperature and relatively abundant reduced compounds. These thermal springs are inhabited by characteristic thermophilic organisms including cyanobacteria. Cyanobacteria are among the few organisms that can occupy high temperature aquatic environments including hot springs. In alkaline and neutral hot springs and streams flowing from them cyanobacteria can form thick colourful mats that exhibit banding patterns. The present investigation involves study of mat forming cyanobacterial flora from hot springs located in Bakreswar, West Bengal, India. The important species found are Synechococcus bigranulatus, S. lividus, Gloeocapsa gelatinosa, G. muralis, Phormidium laminosum, P. frigidum, Oscillatoria princes, O. fragilis, Lyngbya lutea, Pseudanabaena sp., Calothrix thermalis, and Fischerella thermalis. Their distribution pattern in relation to physico-chemical parameters of spring water has also been studied. Three cyanobacterial strains of the above mentioned list were grown in culture and their pigment content and nitrogen fixing capacity were also studied. Nitrogen fixing capacities of Calothrix thermalis, Nostoc sp. (isolated in culture) and Fischerella thermalis are 5.14, 0.29, and 2.60 n mole $C_2H_4/{\mu}g$ of Chl-${\alpha}$/hr respectively. Carotenoid : Chlorophyll-${\alpha}$ ratio of four mat samples collected from Kharkunda, Suryakunda, Dudhkunda and bathing pool are 2.45, 1.60, 1.48, and 1.34, respectively. Higher value of Carotenoid : Chlorophyll-${\alpha}$ ratio coincided with higher temperature.

Drying Experiment of Borate Waste and Characteristics of Dried Products (붕산함유폐액의 건조와 건조물의 특성)

  • Kang, Mun-Ja;Kim, Hwan-Young;Kim, Joon-Hyung
    • Nuclear Engineering and Technology
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    • v.24 no.3
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    • pp.219-227
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    • 1992
  • An experiment was conducted to determine the reaction of boric acid with lime and the drying of its product using a reactor-dryer. no characteristics of dried products were observed. The major chemical species of dried Products was calcium borate of 2CaO.B$_2$O$_3$. From the particle size distribution of the dried products, it was found that quick lime was better than slaked lime as an additive. The Ca/B mole ratio of reaction was determined to be 3/4 considering the cohesion and agglomeration properties of dried products. The flowability of dried products up to 8 wt% of water content was acceptable for transport process and to reduce drying time.

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