• Journal of Environmental Science International
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• v.13 no.12
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• pp.1089-1102
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• 2004

Seasonal variation of biogeochemical characteristics was determined in Lake Shihwa from October 2002 to August 2003. When the lake was artificially constructed for the freshwater reservoir in 1988, the development of the strong haline density stratification resulted in two-layered system in water column and hypoxic/anoxic environment prevailed in the bottom layer due to oxidation of accumulated organic matters in the lake. Recently, seawater flux to the lake through the sluice has been increased to improve water quality in the lake since 2000, but seasonal stratification and hypoxic bottom layer of the lake still developed in the summer due to the nature of artificially enclosed lake system. As the lake is still receiving tremendous amount of organic matters and other pollutants from neighboring streams during the rainy summer season, limited seawater flux sluicing into the lake may not be enough for the physical and biogeochemical mass balance especially in the summer. The excess of accumulated organic matters in the bottom layer apparently exhausted dissolved oxygen and affected biogeochemical distributions and processes of organic and inorganic compounds in the stratified two-layered environment in the summer. During the summer, ammonia and dissolved organic carbon remarkably increased in the bottom layer due to the hypoxic/anoxic condition in the bottom layer. Phosphate also increased as the result of benthic flux from the bottom sediment. Meanwhile, dissolved organic carbon showed the highest value at the upstream area and decreased along the salinity gradient in the lake. In addition to the sources from the upstream, autochthonous origin of particulate organic carbon from algal bloom in the lake might be more important for sustaining aggravated water quality and development of deteriorated bottom environment in the summer. The removal of trace metals could be attributed to scavenging by strong insoluble metal-sulfide compounds in the hypoxic/anoxic bottom layer in the summer.

• Journal of Korean Society for Atmospheric Environment
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• v.10 no.E
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• pp.325-331
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• 1994

Organic extracts of diesel- exhaust particulates were analyzed for mutagenicity using Ames Salmonella typhimurium assay system. An experimental diesel microbus used was drived on the chassis dynamometer according to CVS-75 mode. The samples were taken from the mixed gases in a dilution tunnel. With a high-volume air sampler equipped with double filter holders, particulate matters were collected on a teflon-coated glass fiber filter placed behind a activated carbon filter. After ultrasonic extraction with benzene- ethanol and evaporation to dryness, the residue was dissolved in dimethylsulfoxide. Each sample was tested toward 2 strains, TA100 and TA98 by the pre-incubation method in the absence and presence of S-9mix. Average concentration of diesel- exhaust particulates was about 116.6mg/m$^3$, and 44.1~62.2 ％ to the total weight of particulates, consisted of organic matters. The mutagenicities of diesel- exhaust particulate organic matters were 4,512 and 2,205 revertants/m$^3$ toward TA100 without and with S-9mix, respectively. Those toward TA98 were 13,367 and 3,715 revertants/m$^3$, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.2
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• pp.205-213
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• 2007

We have studied NOM(natural organic matters) adsorption and biodegradation on 3 kinds of activated carbon and a anthracite. Coal based activated carbon showed the highest DOC(dissolved organic carbon) adsorption capability and roconut(samchully), wood (pica) in the order among the 3 kinds of activated carbon(F400). The biomass amount and activity also showed on coal, wood and coconut based activated carbon in the order. Over 15 minutes EBCT(empty bed contact time) needed to achieve 10 to 17% average removal efficiency and $18\sim24%$ maximum removal efficiency of NOM biodegradation in biofilter using anthracite. Hydrophobic and below 10,000 dalton NOM was much easier to adsorb into the activated carbon than hydrophilic NOM, THMFP(trihalomethane formation potential) and BDOC (biodegradable dissolved organic carbon)$_{slow}$ were much easier than HAA5FP(haloacetic acid 5 formation potential) and $BDOC_{rapid}$ to adsorb into the activated carbon. Hydrophilic and below 1,000 dalton NOM was much easily biodegraded and HAA5FP and $BDOC_{rapid}$ was easier than THMFT and $BDOC_{slow}$ to biodegrade in the biofilter.

• Journal of Korean Society on Water Environment
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• v.30 no.1
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• pp.80-86
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• 2014

Unlike to natural organic matters (NOMs), effluent organic matters (EfOMs) are not well understood due to their complexity and heterogeneity. In this study, EfOMs from sewage and industrial wastewater treatment effluents and Suwannee River NOM (SRNOM) were isolated into hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions. Specific ultraviolet absorbance (SUVA) and fluorescence excitation emission matrix (FEEM) analyses were used to characterize physicochemical properties. In addition, acute toxicity and oxidative stress to Daphnia magna were evaluated to characterize toxicological properties. EfOMs showed similar properties to microbially derived organic matters having low hydrophobicity, which are totally different from SRNOM having high hydrophobicity. Moreover, acute toxicity and antioxidant enzyme activity in D. magna was largely dependent on fraction types of EfOMs. These findings suggest that EfOMs have different physicochemical and toxicological properties compared with those of NOMs, which needs to be further identified with various sources of EfOMs.

• Ocean and Polar Research
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• v.41 no.2
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• pp.63-77
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• 2019

In order to investigate the behavior and seasonal variability of Mn as one of the bio-essential metals in the Amundsen sea, which is known as the most biologically productive coastal area around the Antartica, seawaters were collected using a clean sampling system for 10 stations (96 ea) in 2014 (ANA04B) and for 12 stations (139 ea) in 2016 (ANA06B) surveys of RV ARAON. Dissolved and particulate Mn concentration varied in the range of 0.15-4.43 nmol/kg and <0.01 to 2.42 nM in 2014 and in the range of 0.25-4.15 nmol/kg and 0.01-2.64 nM in 2016, respectively. From the sectional distribution of dissolved and particulate Mn, it might be suggested that dissolved/particulate Mn was provided from iceberg melting and diffusion/resuspension from sediments, respectively. Although this sea is highly productive, there was little evidence regarding the biological origin of dissolved Mn, but particulate Mn only in sea ice and offshore areas could be explained as originating from organic matters, e.g. phytoplanktons. And it could be suggested that the subsurface maximum of dissolved Mn was formed by isopycnal transport of melting materials from ice wall to offshore. Compared to early (2014) summer, temperature, salinity, biomass, dissolved and particulate Mn in late (2016) summer indicated that temporal variations might be resulted from the reduction of ice melting and mCDW flow, which induced a reduction in resuspension. In addition, in the late summer, particles including biomass were reduced, which brought about a reduction in the removal rate of dissolved Mn.

• Journal of environmental and Sanitary engineering
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• v.22 no.3
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• pp.13-26
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• 2007

Changes in the characteristics of dissolved organic matter was studied at selected stations in the Nakdong river basin using physical and chemical methods. Characteristics of dissolved organic matters were analysed and assessed. Production of disinfection byproducts were also investigated. 1. Result of relatedness study among each items of analyses showed that relatedness on BOD values were highest with cattle excrement treatment facilities where there is no synthetic organic materials and relatedness on $COD_{Mn}$ were highest at the mainstream Nakdong river. In case of $COD_{Cr}$ (which has more oxidative power than $COD_{Mn}$), the values were higher in the sidestreams indicating the higher content of recalcitrant compounds. The relatedness values for the $UV_{254}$ also showed higher values in the sidestreams and treatment facilities than mainstream indicating the presence of organic aromatic compounds. 2. Ratio of DOC on total organic carbon were higher in the mainstream which is attributable to the influent particulate organic materials produced by agricultural activities. The values were 10-15% higher in the mainstream compared with sidestreams. 3. Result of biodegradability test indicate that concentrations of recalcitrant DOC were higher in the sidestreams than in the mainstream. The values of recalcitrant DOC were higher with the forest stream indicating the effect of soil oriented humic substances. 4. Result of THM production test carried out at 10 stations in the Nakdong river show that $CHCl_3$ was detected with the highest value and the value was highest at Waekwan station.

• Environmental Engineering Research
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• v.21 no.4
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• pp.427-435
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• 2016

In this study, change in water-dissolved oxygen (DO) was analyzed under various synthetic water qualities and nanobubbles (NBs) application conditions, such as gas type, initial DO as well as water dissolved, suspended and organic matters contents. When oxygen, rather than air, was introduced into nitrogen-desorbed ultra-pure water, the stagnation time was significantly increased. It took ten days for DO concentration to drop back to saturation. The higher the initial DO concentration, the longer particles were observed above saturation due to particle stability improvement. The oxygen mass transfer rate of 0.0482 mg/L/min was found to reach a maximum at an electrolytic concentration of 0.75 g/L, beyond which the transfer rate decreased due to adsorption of negative ions of the electrolyte at the interface. High levels of turbidity caused by suspended solids have become a barrier to dissolution of NBs oxygen into the water solution, and thus affected the transfer performance. On the other hand, by applying NBs for just an hour, up to 7.2% degradation of glucose as representative organic matter was achieved. Thus, NBs technology would maintain a high DO extent for an extended duration, and thus can improve water quality provided that water chemistry is closely monitored during its application.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2205-2213
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• 2000

To investigate removal efficiency of dissolved matter by NF and RO, a pilot plant was operated for six months using groundwater treated by UF membrane. After the pilot plant operation, we performed autopsy test to identify characteristics of foulant attached on the membrane surface applying the used NF and RO in the pilot plant test. In autopsy test, we measured permeate flux and recovery rate of flux by chemical cleaning in each membrane. We also analyzed chemical cleaning disposal to examine component of foulant. Permeate flux of NF and RO1 showed rapid decline after 100 days of operation. Especially, reduction of specific flux in RO1 was more serious than in NF. Specific flux of RO2 with a low recovery rate resulted in gradual flux decline. Removal efficiencies of dissolved inorganic matters as a conductivity were 76.3%, 88.2% and 95.3% respectively for NF, RO1 and RO2, and RO2 presented the highest removal efficiency. And those of dissolved organic matters as TOC were about 80% for both NF and RO. The specific flux of membranes declined gradually from the feed water inlet to outlet of the membrane module and it showed that membrane fouling increased along the feed flow direction. Namely, concentration of pollutants became higher and volume of feed water was less as the feed flow approached to the outlet. It seemed that major foul ants were Ca consolidated into inorganic material and Si consolidated into organic material on the membrane surface. Fe was a great contribution to irreversible fouling. The SEM results indicated that the organic matter was attached to the first layer, closer to the membrane, and then inorganic matter with tetragonal shape layered over them. We could not observe biofouling because microorganism, which was cause of biofouling, was almost pretreated in UF membrane.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2005.10a
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• pp.604-609
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• 2005

Runoff characteristics of organic matters and nutrients from greenhouse site in paddy field area were investigated during the irrigation period in 2004. The greenhouse selected which situated near the Nam river, Jinju, Korea used the ground water as the irrigation purpose. And, the rotating system of paddy field to upland was adapted as a cropping system which is a typical practice in this area. Various items such as total phosphorus(T-P), total nitrogen(T-N), dissolved oxygen(DO), BOD, etc. were observed to figure out the seasonal and spatial variation in the study sites. it was found that the risk of water pollution due to the contamination of nutrients in canals in green house sites, and their neighbouring small sized streams are much higher than those in ordinary paddy field areas. Further surveys and investigations are required to find out the counter measures to reduce water pollution occurred in greenhouse sites.

• Journal of Environmental Science International
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• v.26 no.3
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• pp.401-410
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• 2017

This study analyzed the changes in the concentrations of organic matters in constructed treatment wetlands, coming from discharge water from a sewage treatment plant and non-point pollutant sources during rainfall events. At the beginning of a rainfall event, a massive amount of particulate organic matter flowed in, and was removed from the sedimentation basin (S1, S2); dissolved organic matter was removed after passing through stepwise treatment processes in the wetland. During dry period in the wetland, the removal efficiency rate for COD and TOC was -21 and -7%, respectively; during the rainfall event, the removal efficiency rate for COD and TOC were 47 and 43%, respectively. The highly-concentrated organic matters that flowd in at the beginning of the rainfall event was stabilized by various structures in the wetland before water discharge. Cyanobacteria blooms annually at the confluence of the So-ok stream and Daecheong Lake. Therefore, it is expected that the wetland will contribute significantly to reducing cyanobacteria and improving water quality in the area.