• Korean Journal of Materials Research
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• v.32 no.4
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• pp.230-236
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• 2022

The formation behavior of a passive state film on the surface of STS304 in electrolytic solution was analyzed to determine its metallic ion composition. The properties of passive state films vary depending on the Fe and Cr ions in the electrolytic solution. It was observed that the passive state film surface became flat and glossy as the concentration of Fe and Cr ions in the electrolytic solution increased. The corrosion resistance property of the passive state film was proportional to the amount of Fe and Cr in the electrolytic solution. An initial passive state film with high Fe concentration was formed on the surface of STS304 during early electrolytic polishing. Osmotic pressure of Fe ions occurs between the passive state film and electrolytic solution due to the Fe ion concentration gradient. The Fe in the passive state film is dissolved into the electrolyte, and Cr fills up the Fe ion vacancies. As a result, a good corrosion-resistant floating film was formed. The more Fe ions in the electrolytic solution, the faster the film is formed, and as a result, a flat passive state film containing a large amount of Cr can be formed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.40-43
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• 2000

Groundwater qualities in Nakdong river region were investigated during 1999 and 2000. Groundwater samples were collected twice from about 150 sites over the region. The EC and TDS obtained in first survey (October, 1999) show rather high values than those in second survey(April, 2000) and this seems to be caused by groundwater temperature. There is obvious positive correlation between EC and TDS. For the study area, the following equation can be written : TDS(mg/l) = <0.64~0.70> x EC($mutextrm{s}$/cm). As the concentration of major ions increases in natural condition, there is a tendency that the ratio of TDS and EC has consistent value. This observation suggests that TDS measurement can be replaced by EC measurement in the some ranges.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.4
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• pp.340-347
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• 2008

Dissolution process of serpentine in distilled water was systematically investigated for study on pre-treatment of serpentine which was a candidate material for carbon dioxide sequestration. The metallic ions(Ca, Si, Mg etc.) were dissolved in distilled water at ambient condition and their concentrations were changed with dissolution time. The precise evaluation of dissolution process for serpentine dissolved solvent was performed by ion conductivity and pH measurement. Serpentine dissolution in distilled water was evaluated as a stable pre-treatment process without changes of crystallographic structure and chemical structure changes.

• Environmental Engineering Research
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• v.11 no.5
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• pp.266-276
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• 2006

Commonly, the flocculant is dissolved in process or recycle water in industrial plant which has many ionic materials. Therefore, the polymer degradation in aqueous solution by chemical, mechanical or bacteriological may occur, sometimes rapidly. Even if the same flocculant is dissolved, the flocculation characteristics and the properties of dissolving polymer varied with the kind of dissolving water. In this study, we try to estimate the interaction between flocculants and ionic materials in dissolving water using self inversing emulsion polymer; polyacrylamide-co-trimethyl ammonium ethyl acrylate chloride flocculants which have varying molecular weights and structures at a several conditions. The polymeric flocculant is dissolved in artificial dissolving water with Potassium Chloride (PC), Calcium Chloride anhydrous (CC), Potassium Hydroxide (PH), Sodium Chloride (SC), Sodium Bromate (SB) and Iron (II) Sulfate Heptahydrate (IS) as ionic sources. Experimental results indicate that the cationic and anionic ions in dissolving water induce the hydrolysis, degradation of cationic functional group and uncoiling of polymeric flocculants, therefore, the flocculation efficiency decreased by undesired polymer. According that result, it is important to estimate not only its structures and physical properties but also the qualities of dissolving water to optimize the efficiency.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.435-437
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• 2003

In order to investigate processes and factors controlling the chemical and isotopic compositions of the Han River, seasonal studies were carried out. The North Han River was much lower in the concentrations of total dissolved solids (TDS), dissolved inorganic carbon (DIC) and major ions than the South Han River, but higher in $SiO_2$ concentration, $\delta$$^{34}$ $S_{so4}$ value and $^{87}$ Sr/$^{86}$ Sr ratio. This indicates that the chemical and isotopic compositions of the Han River were strongly controlled by the geology of their drainage basins: silicate rocks in the North Han River and carbonate rocks in the South Han River. The $\delta$$^{34}$ $S_{so4}$ values were relatively higher in the North Han River (5.90$\pm$1.46$\textperthousand$)) than in the South Han River (3.48$\pm$0.73$\textperthousand$). This implies that dissolved S $O_{4}$$^{2-}$ in the North Han River might be mostly derived from deposition of atmospheric sulfates, whereas in the South Han River from oxidation of sulfide minerals in the abandoned poly-metallic deposits and the coal-bearing sedimentary rocks distributed over the upstream as well as deposition of atmospheric sulfates. The $^{87}$ S $r^{86}$ Sr ratios in the North Han River were distinctly higher than those in the South Han River, reflecting water-rock interaction with different rock types.pes.

• Economic and Environmental Geology
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• v.34 no.6
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• pp.539-553
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• 2001

Geochemical data of the Han river water, including four tributary water samples in the main Han river are presented in this paper. The concentration of dissolved ions in the North Han river water decreases in order of Ca>Na>K>Mg and HCO$_3$>NO$_3$>SO$_4$>Cl, which it mainly affected by the chemical weathering of granite and gneiss in the drainage basin. Meanwhile, the South Han river water shows a decreasing order of Ca>Mg>Na>K and HCO$_3$>SO$_4$>NO$_3$>Cl, which is controlled by the bed rock geology of carbornate rooks and the inflow of acid mine drainage from the metal and coal mines in the Taebaegsan and Hwanggangri areas. The main Han river waters are characterized by unusually high concentration of Na, Cl and SO$_4$ (Ca>Na>K>Mg and HCO$_3$>SO$_4$>CI>NO), indicating a significant anthropogenic pollution by human activities in the metropolitan Seoul city. The geochemical data of the Han river waters from 1981 through 1996 to 1999 records a significant increase in SO$_4$ and NO$_3$, which responsible for the increasing arid mane drainage and municipal anthropogenic pollution.

• Journal of the Korean Ceramic Society
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• v.22 no.1
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• pp.35-39
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• 1985

Synthetic mica $NaMg_{2.5}(Si_4O_{10})F_2 (Na-TSM)$ was treated with HCl solution and H-type exchange resin to investigate the chemical stability and the ion exchange by measuring the dissolution of chemical components and the exchanged $H^+$ ion. The replacement of $Na^+$ ion occurred in contact with HCl solution and H-type ion exchange resin at the surface of Na-TSM particles reached $Na^+$ ions at maximum value of 70~80%. $Mg^{2+}$ ion of octahedral layer became to dissolve from the pH2 solution and th amount of it dissolved in-creased almost proportional to $H^+$ ion concentration from around 0.02N $H^+$ ion equilibrium concentration. The crystalline structure of Na-TSM was destructed by dissolution of Mg2+ ion in cncentrated hydrochloric acid solution and resulted silica gel precipitation.

• Journal of Conservation Science
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• v.5 no.2 s.6
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• pp.35-44
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• 1996

We propose a new method to remove salts that have permeated into excavated metal objects. This method cleans the excavated metal objects by using high temperature, high pressure deoxvgenated water containing inhibitors for corrosion of metals. The method greatly reduces the washing time compared with previous methods. Waste water from the method does not need treatment, nor do chemicals need to be removed from the metal objects. Furthermore, this method is applicable to some kind of metals(for example iron objects, bronze objects). We measured quantitatively the soluble salts dissolved from actual metal objects and found that there was a large difference between soluble chloride ions and sulfate ions.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.6
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• pp.81-88
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• 2015

The molecular weight (MW) and crystallinity of cotton linter need to be controlled to be dissolved well in N-methylmorpholine N-oxide (NMMO) solvent for manufacturing regenerated fibers of clothing fabrics. Electron beam irradiation or sulfuric acid pre-treatment followed by alkaline peroxide bleaching has been used to control MW effectively and to improve brightness of cotton linter. Auto-hydrolysis of cotton linter without electron beam irradiation or chemical pre-treatment was found to be effective as an alternative pre-treatment method. Removal of metal ions, that hampered dissolution of cotton linter by NMMO, was also investigated when the auto-hydrolysis was accompanied with ionic polymers and chelating agent.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05a
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• pp.136-139
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• 2004

Olefin/paraffin separation by the facilitated transport membrane using silver salts as carriers has been considered as a promising alternative to the conventional energy intensive distillation process. The basis for the separation is the ability of silver ions to react reversibly with olefin forming silver-olefin complexes.(omitted)