• 제목/요약/키워드: dissolved in water

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우리나라 주요 호소의 수질특성에 대한 통계적 분석 (Statistical Analysis on Water Quality Characteristics of Large Lakes in Korea)

  • 공동수
    • 한국물환경학회지
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    • 제35권2호
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    • pp.165-180
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    • 2019
  • Water quality data of 81 lakes in Korea, 2013 ~ 2017 were analyzed. Most water quality parameters showed left-skewed distribution, while dissolved oxygen showed normal distribution. pH and dissolved oxygen showed a positive correlation with organic matter and nutrients, which appeared to be a nonsense correlation mediated by the algae. The ratio of $BOD_5$ and $COD_{Mn}$ to CBOD was 21 % and 52 % in the freshwater lakes, respectively. TOC concentration appeared to be underestimated by the UV digestion method, when salinity exceeds $700{\mu}S\;cm^{-1}$. In terms of nitrogen/phosphorus ratio, the limiting factor for algal growth seemed to be phosphorus in most of the lakes. Chlorophyll ${\alpha}$ increased acutely with decrease of N/P ratio. However, it seemed to be a nonsense correlation mediated by phosphorus concentration, since the N/P ratio depended on phosphorus. The N/P ratio of brackish lakes was lower than that of the freshwater, at the same concentration of phosphorus. It is worth examining denitrification that occurs, in bottom layer and sediment, during saline stratification. $Chl.{\alpha}$ concentration decreased in the form of a power function with increase of mean depth. The primary reason is that deep lakes are mainly at the less-disturbed upstream. However, it is necessary to investigate the effect of sediment, on water quality in shallow lakes. Light attenuation in the upper layer, was dominated by tripton (non-algal suspended solids) absorption/scattering (average relative contribution of 39 %), followed by CDOM (colored dissolved organic matter) (average 37 %) and $Chl.{\alpha}$ (average 21 %).

가압펌프에 의해 해체된 플럭이 가압식 막여과 공정의 제거효율 및 막오염에 미치는 영향 (Effect of Coagulated Flocs Broken by the Pressure Pump on Removal Rate and Membrane Fouling of Pressurized MF process)

  • 김준현;문백수;박종수;조윤호;김진호
    • 멤브레인
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    • 제23권6호
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    • pp.460-468
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    • 2013
  • 가압식 MF공정의 전처리공정으로 침전지가 없는 혼화/응집공정에서 적정응집제 투입농도선정 및 유기물 제거성능을 평가하였다. 전처리 공정에서 생성된 플럭이 가압펌프의 임펠러에 의해 해체됨을 확인하였으며 원수탁도가 10 NTU 이하로 유입이 될 때, 혼화/응집조와 펌프후단에서 플럭형성을 위한 최적응집제 투입량은 4 mg/L (as PACl 17%)이었다. 이때의 DOC 제거율은 평균 43%이었으며, 응집제투입량을 계속적으로 증가시켜 8 mg/L (as PACl 17%)로 투입을 하였을 때, DOC 제거율은 평균 48%를 나타내어 제거율은 크게 개선되지 않았다. 전처리가 없는 PVDF 가압식 MF공정의 TMP는 0.54 bar에서 운영이 되었으며, 혼화/응집 전처리 공정을 적용하여 운영 시 TMP는 0.41 bar로 안정적인 운영이 가능하였다.

Determination Of Dissolved Trace Metals In Sea Water By Atomic Absorption Spectrophotometry After Concentration By Fe (III) - APDC Coprecipitation

  • Lee, Dong-Soo;Lee, Soo-Hyung;Kwak, Hi-Sang;Lee, Kwang Woo
    • 한국해양학회지
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    • 제15권1호
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    • pp.66-70
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    • 1980
  • A method for the determination of dissolved species of Cd, Co, Cu, Ni, Pb and Zn in sea water by flame atomic absorption spectrophotometry (AAS) is described. Prior to analysis by AAS, these elements are concentrated by coprecipitation with iron pyrrolidinedithiocarbamate at pH 3 because of matrix effects and their low concentration levels in sea water. The detection limits are 0.01, 0.04, 0.02, 0.05, 0.08, and 0.03$\mu\textrm{g}$/l, and the relative standard deviations are 1.0, 2.4, 1.3, 2.9, 2.0 and 2.9% for Cd, Co, Cu, Ni, Pb and Zn, respectively. The method is shown to be satisfactory in terms of recovery and precision for the determination of these metals in sea water.

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고도정수처리(DAF) 정수장 전력설비 적정 설계를 위한 고조파 현장 측정 및 분석 (The diagnosis and analysis for the correct design of electrical system in water treatment plan(Dissolved Air FIotation Process))

  • 김동룡;김기태;한병옥;한상옥
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 춘계학술대회 논문집 전기설비전문위원
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    • pp.61-63
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    • 2007
  • In these days there are many troubles - system data error, control malfunctions, cable overheating - in water treatment plant. Specially DAF(Dissolved Air Floation Process) plant has high frequency than previous water treatment process. DAF plant has diverse equipment, nonlinear loads for the precise control. But there is no sufficient overall study about harmonics condition of water treatment plant just taking a following partial action without a fundamental solution. On designing of power system, designer should have regard to harmonics condition, but there is no guide reflected harmonics condition on DAF plant This study says what is the result of guideless design about harmonics. With the result of diagnosis and analysis in DAF plant, economical efficiency and safety of plant will be upgraded in the next design.

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횡성호의 유기물 수지 및 거동 특성 (Organic Matters Budget and Movement Characteristic in Lake Hoengseong)

  • 정승현;박혜경;윤석환
    • 한국물환경학회지
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    • 제28권2호
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    • pp.238-246
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    • 2012
  • Organic matters budget in Lake Hoengseong were monthly investigated from April 2009 to November 2009. The intense rainfall occurred at between July and August and the hydrological factors were highly varied during the rainfall season. By the concentrated rainfall, the elevation, influx and efflux were sharply increased and the turbid water was also flowed into the middle water column in Lake. The inflow of turbid water increased the nutrient concentrations in water body and this appears to stimulate of phytoplankton regard as the primary productivity of influx of organic matter. Monthly average concentration of dissolved organic carbon (DOC) was generally higher than the particulate organic carbon (POC) concentration in Lake, but Temporal and spatial variation of POC concentration was higher than DOC and the maximum POC concentration was recorded in surface water in August, had the highest phytoplankton biomass. Organic carbon concentration in inflow site was rarely changed during the dry season, but the concentration was rapidly increased by the initial intense rainfall. In organic matters budget, the most of the organic matters was inflowed from the inflow site at rainfall season. Especially, the influx of allochthonous organic matters during the intense rainfall was 72.4% in the total influx organic matters.

Chemical Water Quality of Lake Eui-Am

  • Choe, Sang;Kwak, Hi-Sang
    • 한국해양학회지
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    • 제6권2호
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    • pp.63-77
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    • 1971
  • An year-long survey of chemical water quality for Lake Eui-am in Kang-won Province, Korea, was conducted from June 1970 to May 1971 to study the water quality and seasonal variations of productivities in relation to selected physical and chemical environmental factors. A monthly series of water samples were taken at the deepest basin of 18m depth of the lake. Water quality parameters determined were water temperature, Secchi disc reading(transparency), pH, O$\_$2/, CO$\_$2/, alkalinity, acidity, Cl, hardness, Ca, Mg, total residue, total ignitious residue, COD, BOD$\_$5/, nutrients, total-Fe, soluble Fe, Mn and Cu. On the whole, the results indicate that the chemical water quality of Lake Eui-am is high, and vary with season. The lake water is characterized that higher levels of dissolved oxygen(8.6 ml/L in mean of whole water) or percent saturation of dissolved oxygen(114%), and of nitrate nitrogen (523 $\mu\textrm{g}$/L). On the other hand, CO$\_$2/(9.6ppm), chlorides(3.5ppm), Ca(7.7ppm) Mg(2.2ppm), hardness(28.5ppm), silica(2.4ppm) and BOD$\_$5/(1.08ppm) are quite low. In terms of nutrient levels, the lake water exhibit slight signs of eutrophication. The high values for nitrate nitrogen, soluble iron and Cu of the lake water suggest that there are some imputs such as domestic and industrial discharges to the lake.

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제주도 한라산 남북측 사면 용천수의 수리지구화학

  • 이광식;박원배;현승규;김용제;문덕철;김구영
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.408-412
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    • 2004
  • A total of 23 springs distributed in the southern and northern sides of Mt. Hala in Jeju Island were seasonally sampled and analyzed for their major ion chemistry and oxygen and hydrogen isotope compositions to investigate their hydrogeochemical and isotopic characteristics. Dissolved ion concentrations of the south-side springs slightly increase with decreasing altitude. This indicates that dissolved ion concentrations of groundwater recharged at higher altitudes increase by water-rock interaction during the downgradient migration of groundwater through highly permeable volcanic aquifer. Dissolved ion concentrations of the north-side springs also slightly increase with decreasing altitude, but dramatically increase at ~300 m.a.s.l. This may indicate a sudden input of contaminants to the north-side groundwater system around ~300 m.a.s.l. Springs located in areas above ~300 m.a.s.l. have very low concentrations of dissolved ions, showing little seasonal variations. Whereas springs located in areas below ~300 m.a.s.l. show a big seasonal variation in the concentration of dissolved ions. Seasonal variation of oxygen isotope compositions of springs is ~3$\textperthousand$ for high-altitude springs (~1700 m.a.s.l.) and is ~2$\textperthousand$ near shore, indicating an attenuation of the variation through mixing with other groundwater bodies during migration.

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Combination of Sequential Batch Reactor (SBR) and Dissolved Ozone Flotation-Pressurized Ozone Oxidation (DOF-PO2) Processes for Treatment of Pigment Processing Wastewater

  • Kim, Jeong-Hyun;Kim, Hyung-Suk;Lee, Byoung-Ho
    • Environmental Engineering Research
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    • 제16권2호
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    • pp.97-102
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    • 2011
  • This study investigates the treatment of pigment wastewater using a sequential batch reactor (SBR) followed by dissolved ozone flotation-pressurized ozone oxidation treatement (DOF-$PO_2$). The process efficiency has been evaluated at the lab scale on the basis of water quality parameters. In addition, the effect of pure oxygen and air was investigated on the removal of COD, BOD, and TN in the SBR process. It was observed that under comparable conditions the removal efficiencies of these water quality parameters using pure oxygen and air were similar. The effect of the recycle rate was also investigated for its impact on the water quality parameters using different ozone dissolving pressures in a DOF process in order to optimise conditions. The results conclude that the use of an SBR and ozone contact by DOF-$PO_2$ is a highly effective treatment for pigment wastewater and aids in the achievement of effluent discharge criteria.

Variation Pattern of ${\delta}^{13}C_{DIC}$ of the Odaecheon Stream Water

  • Shin, Woo-Jin;Chung, Gong-Soo
    • 한국지구과학회:학술대회논문집
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    • 한국지구과학회 2005년도 춘계학술발표회 논문집
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    • pp.115-125
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    • 2005
  • Carbon isotopic composition of a stream (Odaecheon Stream) monitored over 7 months from July 2004 to January 2005 in Gangweon Province ranges from -9.24 to -4.69‰. Strong negative correlation between ${\delta}^{13}C_{DIC}$ and water temperature suggests that temperature is a dominant factor controlling ${\delta}^{13}C_{DIC}$ in the Odaecheon Stream. The variation pattern of ${\delta}^{13}C_{DIC}$ was thought to be caused by fractionation of C isotope between stream water and atmosphere and more fractionation at reduced temperature. More fractionation of C isotope between stream water and atmosphere at reduced temperature resulted in increase of ${\delta}^{13}C_{DIC}$ of stream water in winter compared to summer. Photosynthesis and respiration of aqueous biota seem to affect little in ${\delta}^{13}C_{DIC}$ as indicated by little variation of dissolved oxygen and reverse variation pattern of Eh in the stream and scarce aqueous biota in stream water. pH seems to be controlled by $CO_2{2}$ exchange between stream water and atmosphere. During summer more $CO_2{2}$ exchange between stream water and atmosphere resulted in decrease in pH value.

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An Antioxidant Capacity Assay Using a Polyvinyl Alcohol-Based DPPH Pellet

  • Ahn, Yeong-Hee;Yoo, Jong-Shin;Kim, Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • 제31권9호
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    • pp.2557-2560
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    • 2010
  • To assay for antioxidant capacity of natural products considered important in producing human health benefits, a practical and economical method using pellet techniques was developed. A standard visualizing reagent, 1,1diphenyl-2-picryl-hydrazyl (DPPH), was mixed with a water-miscible polyvinyl alcohol (PVA), serving as a solid phase support for the DPPH reagent. A DPPH pellet was prepared by dropping a small volume of the DPPH solution onto PET film, and drying in an oven. The PVA-based DPPH pellet was dissolved into water, in which the water-miscible PVA plays as a non-ionic surfactant to help the DPPH reagent to be dissolved into the solvent. Using the DPPH assay, the antioxidant capacity of water-soluble extracts of black soybean, barley, green tea, and green gram was examined. Among the natural products tested, green tea showed the highest antioxidant capacity. This PVA-based DPPH antioxidant assay can be further applied in the natural food, raw plant material, and health product inspection field.