• Journal of Environmental Science International
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• v.31 no.4
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• pp.341-356
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• 2022

Electrical Conductivity (EC) or Total Dissolved Solids (TDS) has been often used to evaluate the water quality in some water education program for children and youth. This study attempted to find out whether EC (or TDS) can be used as a water pollution criteria in water education program. To clarify it, we used the water analysis data of July 2019 and January 2020 from Water Environment Information System. Data from 332 points in Han-river were used to investigate correlation between the parameters, such as BOD, COD, TN, TP vs EC. Correlation(r) for all data of BOD vs. EC was 0.347 for July 2019 and 0.483 for January 2020. No correlation was observed for BOD Ia and BOD Ib for July 2019 (r=-0.041, -0.030, respectively) and BOD Ia for January 2020 (r=0.041). Better correlation for all data of COD vs. EC was obtained (r=0.543 for July 2019 and r=0.610 for January 2020). However, no correlation was observed for COD Ia for January 2020. High vlaue of EC or TDS does not always mean water pollution, especially for clean water environment. Thus, EC (or TDS) alone can not be used as a water pollution criteria.

• Advances in environmental research
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• v.5 no.2
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• pp.141-151
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• 2016

Large amounts of aluminum hydroxide ($Al(OH)_3$) exist in water purification sludge (WPS) because of the added aluminum coagulant in water treatment process. Notably, $Al(OH)_3$ is an amphoteric compound, can be dissolved in its basic condition using sodium hydroxide to form aluminate ions ($Al(OH)_4{^-}$). However, in a process in which pH is increasing, the humid acid can be dissolved easily from WPS and will inhibit the recovery and reuse of the dissolved aluminate ions. This study attempts to fix this problem by a novel approach to separate $Al(OH)_4{^-}$ ions using nanofiltration (NF) technology. Sludge impurity in a alkaline solution is retained by the NF membrane, such that the process recovers $Al(OH)_4{^-}$ ions, and significantly decreases the organic matter or heavy metal impurities in the permeate solution. The $Al(OH)_4{^-}$ ion is an alkaline substance. Experimental results confirm that a recovered coagulant of $Al(OH)_4{^-}$ ion can effectively remove kaolin particles from slightly acidic synthetic raw water.

• Journal of Korean Society on Water Environment
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• v.39 no.6
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• pp.465-474
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• 2023

The chemical composition and molecular weight characteristics of dissolved organic matter (DOM) exert a profound influence on the efficiency of organic matter removal in water treatment systems, acting as efficiency predictive indicators. This research evaluated the primary chemical and molecular weight properties of DOM derived from diverse sources, including rivers, lakes, and biomasses, and assessed their relationship with the efficiency of coagulation/flocculation treatments. Dissolved organic carbon (DOC) removal efficiency through coagulation/flocculation exhibited significant correlations with DOM's hydrophobic distribution, the ratio of humic-like to protein-like fluorescence, and the molecular weight associated with humic substances (HS). These findings suggest that the DOC removal rate in coagulation/flocculation processes is enhanced by a higher presence of HS in DOM, an increased influence of externally sourced DOM, and more presence of high molecular weight compounds. The results of this study further posit that the efficacy of water treatment processes can be more accurately predicted when considering multiple DOM characteristics rather than relying on a singular trait. Based on major results from this study, a predictive model for DOC removal efficiency by coagulation/flocculation was formulated as: 24.3 - 7.83 × (fluorescence index) + 0.089 × (hydrophilic distribution) + 0.102 × (HS molecular weight). This proposed model, coupled with supplementary monitoring of influent organic matter, has the potential to enhance the design and predictive accuracy for coagulation/flocculation treatments targeting DOC removal in future applications.

• Journal of Korean Society on Water Environment
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• v.21 no.6
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• pp.595-601
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• 2005

In this research, effects of water circulation on phosphorus release from sediment into water body were studied. Sediments sampled at the Daechung Lake were used for the column experiments with circulation and non-circulation conditions. Deaeration coefficient, $K_1$ and reaeration coefficient, $K_2$ of non-circulation condition were 0.133 and 0, respectively, while $K_1$ and $K_2$ for circulation condition were 0.46 and 0.018, respectively. Oxidation Reduction Potential (ORP) showed a linear relationship with dissolved oxygen (DO) when DO is over 2 mg/L. Phosphorus concentration induced by phosphorus release from sediment was highly dependent upon DO, ORP, and pH. Under anaerobic condition, phosphorus release rate was higher for $Fe^{2+}$-bounded phosphorus compared to that of $Ca^{2+}$-bounded phosphorus.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.2
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• pp.242-246
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• 2004

Dissolved air flotation (DAF) is an effective solid/liquid separation process for low density particles, such as algal flocs, humus materials and clay particles produced from low turbidity water. The fraction of humic substances for natural organic matters (NOMs) are considered problematic in water because it can readily react with chlorine to form harmful by-products (trihalomethanes) and can be exposed to undesirable color, tastes and odors in drinking water. A broad class of NOMs includes fulvic acid, humic acid and humin. This paper will discuss the results from a study that performed with a DAF pump process using synthetic wastewater contained humic substance. Batch jar tests were performed to evaluate coagulant dose and recycle ratio on flotation efficiency.

• Advances in environmental research
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• v.1 no.3
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• pp.181-189
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• 2012

Trihalomethanes, produced as a result of chlorination of drinking water, are considered a potential health hazard. The trihalomethane formation potential (THMFP) of a raw water source may indicate the maximum trihalomethanes (THMs) that are likely to be produced when chlorine reacts with natural organic matter (NOM) present in the water. A study was conducted to evaluate the THMFP in seven different drinking water sources in the vicinity of Kalpakkam, a rural township, on the east coast of India. Water from seven stations were analysed for THMFP. THMFP was compared with surrogate parameters such as dissolved organic carbon (DOC), ultraviolet absorbance ($UV_{254}$) and bromide. The data showed that THMFP was high in water from open wells as compared to closed bore wells, possibly due to more photosynthetic activity. Proximity to sea, and consequently the levels of bromide, was an important factor that influenced THM formation. THM surrogate parameters showed good correlation with THMFP.

• 제어로봇시스템학회:학술대회논문집
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• 2005.06a
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• pp.935-940
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• 2005

We are faced with water pollutions on a population explosion. Considering the importance, we research European rivers based on OECD reports. Observations in the reports have defects that make evaluation of environmental situations be difficult. By using interpolations in the compensation quantitative structure-activity relation ships (CQSAR), we complement the defects in the water quality of rivers through big cities. Thus, we get complete data set for dissolved oxygen, biochemical oxygen demand, and total phosphorus. Using the data set, we examine re-naturalization of the Rhein and the Donau in Germany. We investigate the effect of dams between Slovakia and Hungary, by using reconstructions of neural networks in CQSAR. The reconstructions have functions to extract a principal relation. On the investigation, we examine assertions of conservation groups. As the result, we confirm the re-naturalization is effective, and find a negative effect of the dam construction on changes of dissolved oxygens in the Hungary Donau. We investigate the Seine and the Thames, too.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.48 no.3
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• pp.262-266
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• 2003

The present study was carried out to investigate the relationships among intertillage and muddying by free-ranging ducks (Chinese native ducks) and pH, dissolved oxygen of irrigation water, and physicochemical properties of soil. Two paddy fields comprised of the muddying (muddy water without physical stimulation to a rice plant by the ducks) and the control plots (no ducks) were used for this study. As a muddying plot, 50 hills were randomly selected and each hill was fenced with a wire net in order to prevent from stimulating physically by the ducks. The variation in irrigation pH was smaller in the muddying plot than the control plot, and the pH was around 7.4. Dissolved oxygen was significantly higher (P＜0.01) in the muddying plot than the control plot during the first half period after the ducks were introduced. Then it decreased rapidly as the rice plants grew in all plots. The contents of the suspended soil and turbidity in irrigation water were not changed over the free-ranging period, but $\textrm{NH}_3\textrm{-N}$ and $\textrm{P}_2\textrm{O}_5$ were decreased by intertillage and muddying by the ducks. There were no differences in both the soil physics and chemistry between the muddying plot and the control plot during and after finishing of the free-ranging period. These results indicate that intertillage and muddying by the ducks resulted in a small variation in stagnant water pH, and reduced the dissolved oxygen and $\textrm{P}_2\textrm{O}_5$, although the physiochemical properties of soil were not changed.

• Journal of Environmental Science International
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• v.17 no.6
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• pp.611-621
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• 2008

This study intends to provide the necessary basic data needed for predicting the water quality and examining changes in water quality on the basis of the hydrological changes: an outflow or the character of a flow by investigating the interaction of the parameters through the estimation of optimal parameters need for predicting the water quality of the dam basin and the sensitivity among those estimated parameters. Im-Ha Dam in the upstream area of the Nakdong River was selected for analysis, and the water quality survey data necessary for parameter estimation was based on the monthly water quality data (water temperature, BOD, T-N and T-P) between December 1, $2005{\sim}$November 31, 2006. K1C(the saturated growth rate of plant plankton), K1RC (endogenous respiratory quotient of plankton), KDC(deoxidized ratio), K71C(minealized ratio of dissolved organic phosphorus), K83C(mineralized ratio of dissolved organic nitrogen) have been considered as the factors of the water quality performed in this water quality simulation, that is, the most effective parameters on BOD, T-N and T-P. In the result of the analysis of the sensitivity, KDC(deoxidized ratio) was the most sensitively reacted parameter on BOD and it was K71C(mineralized ratio of dissolved organic phosphorus) and K83C(mineralized ratio of dissolved organic nitrogen) on T-N and T-P. It is considered that it will be possible to apply the most optimal parameter to an analysis of the water quality simulation at Im-Ha Ho basin in the goal year by examining the interaction of the parameters through the parameters sampling which are able to applicable to prediction of the water quality and the analysis of the its sensitivity, in the future, also the analysis on the basis of the hydrological conditions: an outflow or the character of a flow will be needed.

• Journal of Korean Society on Water Environment
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• v.23 no.6
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• pp.843-849
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• 2007

Monitoring of NOM characteristics is important for improving removal efficiency of natural organic matter (NOM) in water treatment processes. In this study, several NOM characteristics, which include specific UV absorbance (SUVA), total carbonate content, molecular weight distribution, and fluorescence properties, were measured using samples collected from a pilot-scale water treatment plant consisting of coagulation/flocculation (C/F), filtration, ozonation and granular activated carbon (GAC) processes. The highest removal of NOM was observed in C/F and filtration processes as demonstrated by the reduction of dissolved organic carbon (DOC) by 25% and 21%, respectively. Despite nearly no change in DOC, however, the lowest SUVA value and the highest total carbohydrate content were observed in the sample from ozonation process. This indicates that non-degradable aromatic compounds become depleted and biodegradable organic compounds are enriched during the process. Comparison of synchronous fluorescence spectra of the samples showed that ozoation process increased protein-like fluorescence while it decreased fulvic-like and terrestrial humic-like fluorescence. Consistently, a slight peak of protein-like fluorescence was observed in the sample from ozonation process. The greatest change in molecular weight distributions of the samples was observed in C/F process. Comparison of size exclusion chromatogram of the samples revealed that NOM fractions with the molecular weight greater than 2000 Da were reduced by over 90% after C/F process. SUVA values and total carbohydrate content of the samples were well correlated with a ratio of protein-like fluorescence and terrestrial humic-like fluorescence intensities with the correlation coefficients of 0.99 and 0.91, respectively. This suggests that synchronous fluorescence properties of NOM could be used as useful tolls for monitoring changes of some NOM characteristics during water treatment processes.