• 대한화학회지
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• 제65권5호
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• pp.320-326
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• 2021

본 연구는 콘택트렌즈를 중합 시 사용하는 교차결합제의 구조가 콘택트렌즈의 물리적 특성 및 약물 용출에 미치는 영향을 조사하였다. 4종의 교차결합제를 0.3%와 3%를 각각 사용하여 콘택트렌즈를 제작하였으며 약물은 안약에 사용하는 ofloxacin을 사용하였다. 친수성 교차결합제를 사용한 콘택트렌즈는 함수율과 습윤성이 향상되었으며 친수성 작용기가 많을수록 효과가 크게 나타났다. 약물용출 농도는 친수성이 강한 교차결합제 사용 시 가장 높게 나타났으며 교차결합제의 농도가 높은 콘택트렌즈는 용출되는 약물 농도가 낮고 용출시간은 길어졌다. 콘택트렌즈의 교차결합제 구조는 콘택트렌즈의 성능 향상과 약물 방출조절에 영향을 주었다.

• Nuclear Engineering and Technology
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• 제30권2호
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• pp.99-111
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• 1998

Chemical composition of the insoluble residue in a simulated spent PWR fuel(SIMRJEL) were studied. SIMFUELS were prepared by adding calculated amount of FP(fission product) elements with a burnup of 3.6% FIMA(fission per initial metal atom) to uranium in nitrate solution, evaporating the mixed solution to dryness, calcining at 90$0^{\circ}C$ in a stream of 4% H$_2$ + 96% He, and heating the pellet at 140$0^{\circ}C$ under high and low oxygen potentials. Insoluble residue was obtained from the dissolution of the SIMFUEL with HNO$_3$(1 : 1). The chemical composition of the SIMFUELs and the insoluble residues was determined by EPMA(electron probe microanalysis), XPS(X-ray photoelectron spectroscopy) and by XRD (X-ray diffraction) measurements. All of the insoluble residues suspended and precipitated were composed mainly of Mo, Ru with a small amount of Zr, Rh, Pd and Cd. The amount of insoluble residue(<1 wt.%) and a Mo/Ru ratio decreased with increasing oxygen potential. Formation of the zirconium molybdate precipitate, ZrMo$_2$O$_{7}$(OH)$_2$($H_2O$)$_2$, was observed in the residues. The possible role of Mo on the phase formation was discussed in regard to oxygen potential.l.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 가을 학술논문 발표대회
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• pp.77-78
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• 2020

An alkaline activator was synthesized by dissolving waste glass powder (WGP) in NaOH-4M solution to explore its effects on the Class-C fly ash (FA) and ground granulated blast furnace slag (GGBS) based alkali-activated material (AAM). The compressive strength and porosity were measured, and (SEM-EDX) were used to study the hydration mechanism and microstructure. Results indicated that the composition of alkali solutions was significant in enhancing the properties of the obtained AAM. As the amount of dissolved WGP increased in alkaline solution, the silicon concentration increased, causing the accelerated reactivity of FA/GGBS to develop Ca-based hydrate gel as the main reaction product in the system, thereby increasing the strength. Further increase in WGP dissolution led to strength loss, which were believed to be due to the excessive water demand of FA/GGBS composites to achieve optimum mixing consistency. Increasing the GGBS proportion in a composite also appeared to improve the strength which contributed to develop C-S-H-type hydration.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.136-137
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• 2021

The soda lime waste glass powder was dissolved in NaOH-4M solution to synthesize an alkaline activator, which was used to activate Class-C fly ash (FA). Compressive and flexural strength tests were conducted to determine the mechanical properties. Archimedes' principle was applied to measure the porosity of samples, (SEM-EDX) and XRD was used to study the microstructure and phase changes of samples. Through Inductive Coupled Plazma technique, the solution was found to increase the concentration of Si as the amount of dissolved glass powder was increased. Owing to the increased concentration of Si in an alkaline solution, the reactivity of FA was accelerated resulting in an increased strength and reduced porosity. Additionally, the dissolution of FA was improved as well as the formation of amorphous phases in the matrix was also enhances with the concentration of increased Si in an alkaline solution.

• Advances in nano research
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• 제15권6호
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• pp.541-550
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• 2023

The escalating growth of industrial sectors has led to a pervasive global problem—oil pollution, particularly in industrial areas. The release of substantial volumes of oil and its by-products into the environment has resulted in extensive contamination. Multiple factors contribute to the entry of these substances into water bodies and soils, thereby inflicting irreparable consequences on ecosystems, natural resources, and human health. Consequently, it becomes imperative to comprehend the characteristics and behavior of oil pollution, anticipate its impacts, and develop effective mitigation strategies. Understanding this intricate issue requires considering the physicochemical properties of the environment, the interactions between oil and sediments, and biological factors such as evaporation and dissolution. Although the oil industry has brought about remarkable advancements, its activities have raised significant concerns regarding pollution from extraction and production processes. Oil-rich nations face a particularly challenging predicament of soil pollution caused by petroleum compounds. The areas surrounding oil exploration mines and refineries often endure contamination due to oil leakages from storage tanks and transmission lines resulting from deterioration and damage. Investigating the dispersion of such pollutants and devising methods to remediate petroleum-contaminated soil represent crucial and intricate issues within the realm of environmental geotechnics.

• 한국분말재료학회지
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• 제30권6호
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• pp.493-501
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• 2023

This study aimed to develop a solid self-nanoemulsifying drug delivery system (solid-SNEDDS) to enhance the formulation of ketoconazole (KTZ), a BCS Class II drug with poor solubility. Ketoconazole, which is insoluble above pH 3, requires solubilization for effective delivery. This SNEDDS comprises oil, surfactant, and co-surfactant, which spontaneously emulsify in the gastrointestinal tract environment to form nanoemulsions with droplet sizes less than 100 nm. The optimal SNE-vehicle composition of oleic acid, TPGS, and PEG 400 at a 10:80:10 weight ratio was determined based on the smallest droplet size achieved. This composition was used to prepare liquid SNEDDS containing ketoconazole. The droplet size and polydispersity index (PDI) of the resulting liquid SNEDDS were analyzed. Subsequently, solid-SNEDDS was fabricated using a spray-drying method with solidifying carriers such as silicon dioxide, crospovidone, and magnesium alumetasilicate. The physicochemical properties of the solid-SNEDDS were characterized by scanning electron microscopy and powder X-ray diffraction, and its solubility, droplet size, and PDI were evaluated. In particular, the solid-SNEDDS containing ketoconazole and crospovidone in a 2:1 weight ratio exhibited significantly enhanced solubility, highlighting its potential for improved medication adherence and dissolution rates.

• 한국결정성장학회지
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• 제15권6호
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• pp.244-251
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• 2005

수열합성법에 의해 제조된 티탄산바륨 (BT01, BT02, BT03, BT04, BT05)의 입자크기와 분체특성과의 상관관계를 비표면적, 제타전위, XPS, XRD 및 SEM에 의해 조사하였다. 레이져광산법에 의해 측정된 입자의 크기는 비표면적과 XRD를 통해 결정된 격자이방성과 밀접한 관계가 있음을 보였다. 분말의 비표면적은 입자의 크기가 증가함에 따라 감소하였으며, BT03 시료는 동일한 입자크기의 BT04에 비하여 큰 비표면적을 보였으며, 이는 입자들의 응집에 기인하는 것으로 SEM사진 및 XRD 분석을 통하여 밝혀졌다. 입자의 크기가 증가함에 따라 제타전위는 증가하는 경향을 보였으며, BT02와 BT03 분말은 다른 분말에 비하여 제타전위가 큰 음의 값을 나타내었다. XPS 분석결과 분쇄시 티탄산바륨과 물 사이의 반응에 의한 $Ba^{2+}$ 이온의 용출과 관련이 있는 것으로 분석되었다.

• 열처리공학회지
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• 제29권1호
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• pp.15-23
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• 2016

The effects of austenitizing temperature and cooling rate on precipitation behavior and tensile properties were investigated in an Mn-Mo-Nb-V pressure vessel steel. During austenitizing, it was shown that the austenite coarsening was somewhat suppressed by undissolved NbC. After cooling from austenitizing, the microstructure of all the steels mainly consisted of upper bainite. However, the steel comprised a little lower bainite and martensite in the case of aqua oil quenching from $1000^{\circ}C$, which would be due to increased hardenability by partly dissolved Nb and comparatively large austenite grains. The average size of NbC in austenite at higher temperature was analyzed to be smaller than that at lower temperature because of the more dissolution. It was found that the NbC did not grow much during fast cooling from austenitizing. Meanwhile, the NbC grew much during slow cooling, probably due to wide temperature range of cooling and sufficiently long time for NbC to grow. It was conjectured the V precipitates newly formed and/or grew during cooling from austenitizing and during tempering. On the other hand, the formation of NbC was almost completed before tempering and little more precipitated during tempering. Among the tempered steels, the steel which was fast cooled from $1000^{\circ}C$ showed the highest tensile strength, which seemed to come from the microstructure of fine upper bainite and some low temperature phases as well as the comparatively fine NbC precipitates.

• 공업화학
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• 제27권4호
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• pp.449-454
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• 2016

본 연구에서는 구형의 폴리스티렌 구슬을 틀로 사용하여, 크기분포가 좁으면서 속은 비어있고 벽이 다공성인 구조의 탄소 마이크로 캡슐을 합성하였다. 폴리스티렌의 표면은 무기물인 실리카졸이 쉽게 입혀질 수 있도록 폴리비닐피롤리돈(PVP)을 코팅하여 변조하였다. PVP가 코팅된 PS 마이크로 입자표면에 SBA-16 졸을 부착시킨 다음, 실리카층에 존재하는 중간 크기의 세공 내에 탄소원을 채워 넣는 음각식 형뜨기법을 적용함으로써 속이 빈 구조의 탄소 마이크로캡슐을 제조하였다. 탄화과정을 거치고 틀로 사용한 다공성 실리카입자를 HF로 용해하면, 좁은 입자크기분포를 갖는 중간세공이 함유된 계란껍질형의 탄소입자를 얻을 수 있었다. 계란껍질형 탄소 마이크로캡슐 입자의 다공성과 전기화학적 특성은 XRD, SEM, TEM, 질소분자 흡/탈착분석법 및 cyclic voltammetry법으로 평가하였다. 이들 탄소입자는 슈퍼캐패시터와 같은 전자재료로서 유효하게 사용될 만한 높은 전기전도도와 용량을 나타내었다.

• 한국주조공학회지
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• 제38권2호
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• pp.32-40
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• 2018

Changes in the microstructures and mechanical properties of an AC2B alloy through solution heat treatment were investigated using recycled AC2B cutting chips as raw material. The as-cast microstructure of the AC2B alloy comprised ${\alpha}$-Al, $Al_2Cu$, and coarse needle-shaped phases considered to be eutectic Si and an Al-Fe-Si based intermetallic compound. After solution heat treatments at $505^{\circ}C$ for 1 h and 6 h, the samples showed complete dissolution of $Al_2Cu$ and relatively fine distribution of intermetallic compounds. Hardness test results showed that the hardness rapidly increased after the solution heat treatment for 1 h by solid solution hardening, and the increase of hardness exhibited a plateau from 1 h to 6 h. The results of the hardness and tensile tests showed that there was no visible difference in the effect of 1 h and 6 h solid solution treatment.