• Title/Summary/Keyword: dispersion state

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Evaluation and Optimization of Dispersion in Slurry Preparation of Commercial LTCC Material (상용 LTCC 소재의 슬러리 제조 공정에서 분산성 평가 및 최적화)

  • Kwon, Hyeok-Jung;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jong-Hee;Cho, Yong-Su
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.4
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    • pp.341-347
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    • 2008
  • Laminated LTCC components of high integrity, fabricated by thick film process, are applied to industrial field of IT technology along with miniaturization trend of electronic devices. Dispersion states were examined by several evaluation methods with MLS-22, which is one of commercial LTCC powders, to achieve optimal dispersion as basis for stable LTCC fabrication process. Slurry viscosity, surface roughness of dip-coated slide glass, sedimentaion of slurry, and SEM observation of dried surface were utilized with respective amount change of various commercial dispersants. Among these commercial dispersants, optimal dispersion state was obtained with 0.4 wt% of BYK-111, from the results of various evaluation methods.

Dispersions of partially reduced graphene oxide in various organic solvents and polymers

  • Kim, Hye Min;Kim, Seo Gyun;Lee, Heon Sang
    • Carbon letters
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    • v.23
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    • pp.55-62
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    • 2017
  • We report on the dispersion state of partially reduced graphene oxide (PRGO) in organic solvents, namely methyl ethyl ketone, ethyl acetate, methylene chloride, toluene, and xylene, by controlling the carbon to oxygen (C/O) atomic ratio of the PRGOs. A two-phase solvent exchange method is also proposed to transfer PRGO from water to an aprotic solvent, such as methyl ethyl ketone. We achieve relatively good dispersion in aprotic and non-polar solvents by controlling the C/O atomic ratio of the PRGOs and applying the two-phase solvent exchange method. There is an increase in the glass transition temperatures with the dispersion of PRGOs into amorphous polymers, in particular a $4.4^{\circ}C$ increase for poly(methyl methacrylate) and $3.0^{\circ}C$ increase for polycarbonate. Good dispersion of PRGO in a nonpolar polymer, such as linear low density polyethylene, is also obtained.

Effects of Surfactants on Dispersion Behavior of Vectran® in Water(II) -Study on the Manufacture and Properties of Wet-laid Nonwoven Fabrics- (Vectran®의 수중 분산 거동에 미치는 계면활성제의 영향(II) - 습식부직포의 제조와 그 물성연구 -)

  • Kang, Yoo-Jung;Song, Sun-Hye
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.327-333
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    • 2015
  • This paper aims to manufacture nonwoven fabrics by wet-laid technology using Vectran$^{(R)}$ one of the highly favoured high-performace fiber. In previous study, a novel evaluation on fiber dispersion was studied to select optimum surfactant by the need for the control of fiber dispersion in water with reference to wet-laid nonwoven technology. 3 Types of sulfonate anionic surfactants were chosen and added in a stage of agitation to improve dispersion behavior of fibers in water. It was observed that the state of fiber dispersion in water affected various properties of nonwovens, including appearance, physical properties, and mechanical properties. Nonwoven added SDBS was uniform in web structure, thickness and weight. Its average pore was small in size and consisted of fine pores and the value of porosity was high. Further, the difference of tensile value between 2 directions was the least. Consequentially, as the dispersion behavior of fiber increases, nonwoven shows more balanced and uniform physical properties in all directions.

Effective time-frequency characterization of Lamb wave dispersion in plate-like structures with non-reflecting boundaries

  • Wang, Zijian;Qiao, Pizhong;Shi, Binkai
    • Smart Structures and Systems
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    • v.21 no.2
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    • pp.195-205
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    • 2018
  • Research on Lamb wave-based damage identification in plate-like structures depends on precise knowledge of dispersive wave velocity. However, boundary reflections with the same frequency of interest and greater amplitude contaminate direct waves and thus compromise measurement of Lamb wave dispersion in different materials. In this study, non-reflecting boundaries were proposed in both numerical and experimental cases to facilitate time-frequency characterization of Lamb wave dispersion. First, the Lamb wave equations in isotropic and laminated materials were analytically solved. Second, the non-reflecting boundaries were used as a series of frames with gradually increased damping coefficients in finite element models to absorb waves at boundaries while avoiding wave reflections due to abrupt property changes of each frame. Third, damping clay was sealed at plate edges to reduce the boundary reflection in experimental test. Finally, the direct waves were subjected to the slant-stack and short-time Fourier transformations to calculate the dispersion curves of phase and group velocities, respectively. Both the numerical and experimental results suggest that the boundary reflections are effectively alleviated, and the dispersion curves generated by the time-frequency analysis are consistent with the analytical solutions, demonstrating that the combination of non-reflecting boundary and time-frequency analysis is a feasible and reliable scheme for characterizing Lamb wave dispersion in plate-like structures.

Solid-State Laser Mode-Locking Near 1.25 μm Employing a Carbon Nanotube Saturable Absorber Mirror

  • Cho, Won-Bae;Choi, Sun-Young;Kim, Jun-Wan;Yeom, Dong-Il;Kim, Ki-Hong;Rotermund, Fabian;Lim, Han-Jo
    • Journal of the Optical Society of Korea
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    • v.15 no.1
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    • pp.56-60
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    • 2011
  • We demonstrate passive mode-locking of a Cr:forsterite laser with a single-walled carbon nanotube saturable absorber mirror (SWCNT-SAM). Without compensation of intra-cavity dispersion, the self-mode-locked laser generates 11.7 ps pulses at a repetition rate of 86 MHz. The dispersion-compensated laser yields ultrashort pulses as short as 80 fs near $1.25\;{\mu}m$ at 78 MHz with average output powers up to 295 mW, representing the highest power ever reported for mode-locked solid-state lasers based on saturable absorption of SWCNTs in this spectral region.

An Analytical Investigation on the Build-up of the Temperature Field due to a Point Heat Source in Shallow Coastal Water with Oscillatory Alongshore-flow

  • Jung, Kyung-Tae;Kim, Chong-Hak;Jang, Chan-Joo;Lee, Ho-Jin;Kang, Sok-Kuh;Yjm, Ki-Dai
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.63-74
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    • 2003
  • The build-up of the heat field in shallow coastal water due to a point source has been investigated using an analytical solution of a time-integral form derived by extending the solutions by Holley(1969) and also presented in Harleman (1971). The uniform water depth is assumed with non-isotropic turbulent dispersion. The alongshore-flow is assumed to be uni-directional, spatially uniform and oscillatory. Due to the presence of the oscillatory alongshore-flow, the heat build-up occurs in an oscillatory manner, and the excess temperature thereby fluctuates in that course and even in the quasi-steady state. A series of calculations reveal that proper choices of the decay coefficient as well as dispersion coefficients are critical to the reliable prediction of the excess temperature field. The dispersion coefficients determine the absolute values of the excess temperature and characterize the shoreline profile, particularly within the tidal excursion distance, while the decay coefficient determines the absolute value of the excess temperature and the convergence rate to that of the quasi-steady state. Within the e-folding time scale $1/k_d$ (where $k_d$ is the heat decay coefficient), heat build-up occurs more than 90% of the quasi-steady state values in a region within a tidal excursion distance (L), while occurs increasingly less the farther we go to the downstream direction (about 80% at 1.25L, and 70% at 1.5L). Calculations with onshore and offshore discharges indicate that thermal spreading in the direction of the shoreline is reduced as the shoreline constraint which controls the lateral mixing is reduced. The importance of collecting long-term records of in situ meteorological conditions and clarifying the definition of the heat loss coefficient is addressed. Interactive use of analytical and numerical modeling is recommended as a desirable way to obtain a reliable estimate of the far-field excess temperature along with extensive field measurements.

Biopharmaceutical Evaluation of a Solid Dispersion System Containing Sibutramine Freebase

  • Lee, Min-Suk;Chang, Hee-Chul;Kim, Taewan;Park, Jung-Hwa;Lee, Bong-Sang;Kim, Sung-Hee;Kim, Do-Hwan;Kim, Bo-Gyun;Oh, Seong-Tae;Kang, Myung-Joo;Park, Jong-Hyeok;Lee, Jaehwi;Choi, Young-Wook
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.749-754
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    • 2008
  • To increase the solubility of sibutramine freebase, the solid dispersion was prepared using a fluid-bed granulator. The solid dispersion containing sibutramine freebase was characterized by differential scanning calorimetry (DSC) and powder X-ray diffraction (XRD). After filling the sibutramine solid dispersion in the gelatin hard capsule, we performed in vitro dissolution test, the stability test under accelerated conditions and pharmacokinetic study in beagle dogs. The DSC and XRD data showed that sibutramine solid dispersion would be amorphous state. The dissolution rate of sibutramine solid dispersion was significantly increased about 70% than sibutramine freebase. The stability of sibutramine solid dispersion capsules was equivalent or above to commercial product of sibutramine. In beagle dogs, the sibutramine solid dispersion showed equivalent pharmacokinetic behavior with commercial product of sibutramine hydrochloride. In conclusion, the solid dispersion system provided a possible way to overcome the low solubility of sibutramine freebase, and the sibutramine solid dispersion can be a bioequivalent with the commercial product in humans.

Numerical Simulation of Buoyant flume Dispersion in a Stratified Atmosphere Using a Lagrangian Stochastic Model

  • Kim, Hyun-Goo;Noh, Yoo-Jeong;Lee, Choung-Mook;Park, Don-Bum
    • Journal of Mechanical Science and Technology
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    • v.17 no.3
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    • pp.440-448
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    • 2003
  • In the present paper, numerical simulations of buoyant plume dispersion in a neutral and stable atmospheric boundary layer have been carride out. A Lagrangian Stochastic Model (LSM) with a Non-Linear Eddy Viscosity Model (NLEVM) for turbulence is used to generate a Reynolds stress field as an input condition of dispersion simulation. A modified plume-rise equation is included in dispersion simulation in order to consider momentum effect in an initial stage of plume rise resulting in an improved prediction by comparing with the experimental data. The LSM is validated by comparing with the prediction of an Eulerian Dispersion Model (EDM) and by the measured results of vertical profiles of mean concentration in the downstream of an elevated source in an atmospheric boundary layer. The LSM predicts accurate results especially in the vicinity of the source where the EDM underestimates the peak concentration by 40% due to inherent limitations of gradient diffusion theory. As a verification study, the LSM simulation of buoyant plume dispersions under a neutral and stable atmospheric condition is compared with a wind-tunnel experiment, which shows good qualitative agreements.

A Study on Dispersion Characteristics of Odor from Hanwoo and Dairy Farms (한우 및 젖소농장 발생 악취의 확산특성 연구)

  • Kim, Doo-Hwan;Ha, Duck-Min;Lee, Jae-Young;Kim, Hee-Ho;Song, Jun-Ik
    • Journal of Animal Environmental Science
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    • v.21 no.1
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    • pp.1-8
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    • 2015
  • This study was conducted to investigate the dispersion prediction of odor from Hanwoo and dairy farms. Gaussian Plume model used in considering of farm size, wind velocity, atmospheric stability and threshold odor unit to prediction of odor dispersion based on the survey on current state of odor emission and control from 9 site of Hanwoo and 9 site of dairy farms. Farm size, wind velocity and atmospheric stability were affected the distance of odor dispersion, showed longer distance in cases of large farm, low wind velocity and stable atmospheric condition. We will suggestion the adjusted distance of odor dispersion according to farm size was estimated to 50~100 m in Hanwoo farm and 50~150 m in dairy farm when apply the 3OU, 5 m/s wind velocity and stable atmospheric condition.

A Study on Dispersion Characteristics of Odor from Swine Farms (양돈장 발생 악취의 확산특성 연구)

  • Kim, Doo-Hwan;Ha, Duck-Min;Lee, In-Bok;Choi, Dong-Yun;Song, Jun-Ik
    • Journal of Animal Environmental Science
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    • v.20 no.2
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    • pp.41-48
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    • 2014
  • This study was conducted to investigate the dispersion prediction of odor from swine farms in Korea. Gaussian Plume model used in considering of farm size, wind velocity, atmospheric stability and threshold odor unit to prediction of odor dispersion based on the survey on current state of odor emission and control from 48 site of swine farms. Farm size, wind velocity and atmospheric stability were affected the distance of odor dispersion, showed longer distance in cases of large farm, low wind velocity and stable atmospheric condition. We will suggestion the adjusted distance of odor dispersion according to farm size was estimated to 180 m in small farm and 320 m in large farm when apply the 3 OU, 5 m/s wind velocity and stable atmospheric condition.