• Korea-Australia Rheology Journal
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• 제16권4호
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• pp.201-212
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• 2004

Properties of polymer based nanocomposites depend on dispersion state of embedded fillers. In order to examine the effect of dispersion state on rheological properties, a new bi-mode FENE dumbbell model was proposed. The FENE dumbbell model includes two separate ensemble sets of dumbbells with different fric­tion coefficients, which simulate behavior of well dispersed and aggregated carbon nanotubes (CNTs). A new parameter indicating dispersion state of the CNT was proposed to account for degree of dispersion quantitatively as well as qualitatively. Rheological material functions in elongational, steady shear, and oscillatory shear flows were obtained numerically. The CNT/epoxy nanocomposites with different dis­persion state were prepared depending on whether a solvent is used for the dispersion of CNTs or not. Dis­persion state of the CNT in the epoxy nanocomposites was morphologically characterized by the field emission scanning electronic microscope and the transmission electron microscope images. It was found that the numerical prediction was in a good agreement with experimental results especially for steady state shear flow.

• 대한기계학회논문집A
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• 제31권4호
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• pp.483-489
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• 2007

We have investigated quantitative measurement techniques of the degree of dispersion of single-walled carbon nanotubes (SWNTs). SWNTs were suspended in aqueous media using a sodium dodecyl sulfate (SDS) surfactant. SWNTs with different dispersion states were prepared by controlling the intensity and time of sonication and centrifugation. The laser spectroscopic techniques were employed to characterize the dispersion state; i.e., raman fluorescence and absorption spectroscopic techniques. Raman spectroscopy has been used to probe the dispersion and aggregation state of SWNTs in solution. Individually suspended SWNTs show increased fluorescence peaks and decreased roping peaks at a raman shift 267 $cm^{-1}$ compared with the samples containing bundles of SWNTs. The ultraviolet-visible-near infrared (UV-vis-NIR) absorption spectrum of decanted supernatant samples show sharp van Hove singularity peaks

• 폴리머
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• 제35권1호
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• pp.60-65
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• 2011

고분자 나노복합재의 성능을 극대화 하기 위해서는 나노업자 분산도의 향상과 더불어 분산상태가 물성 변화에 미치는 영향을 정확히 이해하는 것이 매우 중요하다. 본 연구에서는 탄소나노튜브 첨가 고분자 복합재의 분산상태를 정량적으로 평가할 수 있는 방법을 제시하고자 하였다. 자외선-가시광선 분광광도법을 이용하여 탄소나노튜브의 분산상태에 따른 투과도를 측정하였으며, 동일 농도에서 분산상태가 향상됨에 띠라 투과도가 감소하는 것을 확인하였다. 이러한 결과를 바탕으로 기존의 Beer-Lambert 투과도 법칙에 분산상태의 변화를 포함할 수 있는 새로운 분산도 평가인자인 유효 농도 인자를 제시하였다. 이를 통해 탄소나노튜브의 분산상태의 변화와 함께 다양한 탄소나노튜브의 농도 및 시편 두께에 따른 투과도 결과를 분석함으로써 제시한 분산도 평가방법과 유효 농도 인자의 유효성을 확인하였다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1283-1285
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• 2008

We describe how the phenomenon of dielectric dispersion in nematic liquid crystals influences the director dynamics and thus the switching speed of nematic-based displays.

• KSBB Journal
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• 제26권4호
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• pp.283-292
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• 2011

Solid dispersion is one of well-established pharmaceutical techniques to improve the dissolution and consequent bioavailability of poorly water soluble drugs. It is defined as a dispersion of drug in an inert carrier matrix. Solid dispersions can be classified into three generations according to the carrier used in the system. First and second generations consist of crystalline and amorphous substances, respectively. Third generation carriers are surfactant, mixture of polymer and surfactants, and mixture of polymers. Solid dispersions can be generallyprepared by melting method and solvent method. While melting method requires high temperature to melt carrier and dissolve drug, solvent method utilizes solvent to dissolve the components. The improvement in dissolution through solid dispersions is attributed to reduction in drug particle size, improvement in wettability, and/or formation of amorphous state. The primary characteristics of solid dispersions, the presenceof drug in amorphous state, could be determined by differential scanning calorimetry (DSC), powder X-ray diffraction (PXRD), and fourier-transformed infrared spectroscopy (FTIR). In spite of the significant improvement in dissolution by solid dispersion technique, some drawbacks have limited the commercial application of solid dispersions. Thus, further studies should be conducted in a direction to improve the congeniality to commercialization.

• Wind and Structures
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• 제4권1호
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• pp.31-44
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• 2001

Mean concentrations of ammonia gas released as a tracer from an isolated low-rise building have been measured and predicted. Predictions were calculated using computational fluid dynamics (CFD) and two dispersion models: a diffusion model and a Lagrangian particle tracking technique. Explicit account was taken of the natural variation of wind direction by a technique based on the weighted summation of individual steady state wind direction results according to the probability density function of the wind direction. The results indicated that at distances >3 building heights downstream the weighted predictions from either model are satisfactory but that in the near wake the diffusion model is less successful. Weighted solutions give significantly improved predictions over unweighted results. Lack of plume spread is identified as the main cause of inaccuracies in predictions and this is linked to inadequate resolution of flow features and mixing in the CFD model. Further work on non-steady state simulation of wake flows for dispersion studies is recommended.

• 한국음향학회지
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• 제18권4호
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• pp.47-52
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• 1999

본 논문에서는 특징 파라미터의 분산과 인식성능에 대한 기여도를 고려하여 각 특징 파라미터를 가중시키는 방법을 제안하였다. 각 특징 파라미터의 인식률에 비례하게 전체 기여도를 설정하고, 각 특징 파라미터의 분산에 따라 가중요인을 설정하였다. 전체 기여도와 분산에 따른 가중요인을 사용하여 각 특징 파라미터의 상태별 가중치를 설정하였다. 제안한 방법의 유효성을 살펴보기 위해 유사음소 단위의 HMM 음성인식시스템을 사용하여 인식실험을 하였다. 인식실험에서 제안한 방법으로 가중치를 설정하였을 경우에 인식률이 7.7% 향상됨을 볼 수 있었다.

• Journal of applied mathematics & informatics
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• 제35권3_4호
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• pp.241-260
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• 2017

An analysis is made to study the solute transport in a Casson fluid flow through an annulus in presence of oscillatory flow field and determine how this flow influence the solute dispersion along the annular region. Axial dispersion coefficient and the mean concentration expressions are calculated using the generalized dispersion model. Dispersion coefficient in oscillatory flow is found to be a function of frequency parameter, Schmidt number, and the pressure fluctuation component besides its dependency on yield stress of the fluid, annular gap and time in the case of steady flow. Due to the oscillatory nature of the flow, the dispersion coefficient changes cyclically and the amplitude and magnitude of the dispersion increases initially with time and reaches a non - transient state after a certain critical time. This critical value varies with frequency parameter and independent of the other parameters. It is found that the presence of inner cylinder and increase in the size of the inner cylinder inhibits the dispersion process. This model may be used in understanding the dispersion phenomenon in cardiovascular flows and in particular in catheterized arteries.

• 대한화장품학회지
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• 제24권3호
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• pp.73-80
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• 1998

This Study was performed to get the suitable oil dispersion agent by assessment of color strength of organic pigment in non-aqueous systems. Organic pigment is used as a color expression material with other body pigments in the make-up products. But occasionally aggregation or agglomeration occurs for the lack of affinity with medium, This function is the cause of disturbing homogeneous dispersion, and then bring about an instability of products. Our study, research of dispersion mechanism between the pigment and oil phase, has been executed to solve this problem, and find a oil dispersion agent having optimum dispersion condition. Generally dispersion is related to between the solid-liquid mutual properties and electrical phenomena associated with solid-liquid interface. This factor is determined to input energy, milling time, optical properties, particle size, rheological properties, etc. Ideal dispersion state is told that coloring primary solid particle is homogeneously dispersed in medium. Good dispersed colorants are strongly and clearly appeared. We are already known that the particle size of organic pigment, chemical properties and viscosity of medium, refractive index. Consequently We determine the affinity of medium and organic pigment by measuring of color strength in the same mechanical condition. UV-VISIBLE RECORDING SPECTRO PHOTOMETER is used for measuring apparatus. We can decided the dispersion level of oil dispersion agent by measuring absorbance of color strength in the visible range that diluted medium for colloid colorant particles.

• Current Optics and Photonics
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• 제5권3호
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• pp.250-260
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• 2021

A tapered As₂S₃ photonic crystal fiber (PCF) with four layers of air holes in a hexagonal array around the core is designed in this paper. Numerical simulation shows that the dispersion D decreases and the nonlinearity coefficient γ increases from the thick to the thin end along the tapered PCF. We simulate the midinfrared pulse compression in the tapered As₂S₃ PCF using the adaptive split-step Fourier method. Initial Gaussian pulses of 4.4 ps and a central wavelength of 2.5 ㎛ propagating in the tapered PCF are located in the anomalous dispersion region. With an average power of assumed input pulses at 3 mW and a repetition frequency of 81.0 MHz, we theoretically obtain a pulse duration of 56 fs and a compression factor of 78 when the pulse propagates from the thick end to the thin end of the tapered PCF. When confinement loss in the tapered PCF is included in the simulation, the minimum pulse duration reaches 72 fs; correspondingly, the maximum compression factor reaches 61. The results show that in the anomalous-dispersion region, midinfrared pulses can be efficiently compressed in a dispersion-decreasing and nonlinearity-increasing tapered As₂S₃ PCF. Due to confinement loss in the tapered fiber, the efficiency of pulse compression is suppressed.