• Title/Summary/Keyword: dispersion relationship

검색결과 205건 처리시간 0.029초

소결된 백금주석 촉매의 산소 처리에 의한 재분산 연구 (Redispersion of Sintered PtSn Catalyst by Oxygen Treatment)

  • 최이선;김태희;고형림
    • Korean Chemical Engineering Research
    • /
    • 제60권3호
    • /
    • pp.459-467
    • /
    • 2022
  • Pt, PtSn 촉매를 제조한 후, 재분산 연구를 위해 수소분위기에서 소결시킨 후 여러 온도에서 산소처리를 적용하여 백금주석입자의 재분산 정도를 확인하고, 프로판 탈수소 반응실험으로 촉매의 활성을 측정하여 촉매의 물리적, 화학적 상태 변화와 활성의 관계를 이해하고자 하였다. 재분산 처리에 따른 촉매 활성 금속의 상태 및 촉매 입자 간 상호작용 등을 보기 위해 X-선 회절분석(XRD), CO-화학흡착(CO-pulse chemisorption), 수소 승온환원(H2-TPR) 분석을 실시하였다. 산소 재분산 처리 조건에 따라 백금의 분산도 및 입자 크기, 촉매의 결정상 및 환원 거동이 달라지는 것을 확인하였다. 촉매를 재분산 처리하였을 시 500 ℃에서 산소 처리한 촉매가 가장 높은 전환율과 활성회복률을 보였다. 500 ℃로 산소 처리한 촉매가 백금의 분산도도 비교적 높게 나타나고, 평균 입자 크기가 작아지는 것을 XRD와 CO-화학흡착 결과로부터 확인하여 백금주석입자가 재분산되는 것을 알 수 있었다. 이러한 산소처리에 의한 재분산으로 인해 촉매활성이 회복된다는 것을 알 수 있었고, 백금보다 백금주석 촉매의 활성회복률이 더 높았다.

이미지 분석시스템을 이용한 부선컬럼에서 기포크기의 측정 (Measurement of Bubble Size in Flotation Column using Image Analysis System)

  • 안기선;전호석;박철현
    • 자원리싸이클링
    • /
    • 제29권6호
    • /
    • pp.104-113
    • /
    • 2020
  • 기포크기는 컬럼부선에서 기포체류시간, 기포표면적플럭스(Sb) 및 운송율(Cr)에 영향을 미치는 중요 변수로 인식되고 있다. 본 논문은 부선컬럼에서 기포크기의 측정방법, 가동변수들의 관계 그리고 가스분산특성을 논한다. 기포크기는 고속카메라와 이미지 분석 시스템을 이용하여 가동변수들(가스속도, 세척수속도, 기포제농도)의 조건에 따라 부선컬럼에서 직접적으로 측정되었다. 각 측정과 산정된 기포크기 값들을 비교한 관계식이 ±15~20의 오차범위 내에서 도출되었고 평균 기포크기(Sauter mean diameter)는 0.718mm로 확인되었다. 본 시스템으로부터 기포크기 및 분포를 조절할 수 있는 경험식이 가동조건들(Jg: 0.65~1.3cm/s, JW: 0.13~0.52cm/s, frother concentration: 60~200ppm) 하에서 개발되었다. 기포제농도의 증가는 표면장면과 기포크기를 감소시킨다. 임계병합농도는 표면장력이 가장 낮은 49.24mN/m일 때인 기포제농도 200ppm이라고 판단된다. 공기속도의 감소, 기포제농도 및 세척수속도의 증가에 따라 기포크기가 감소하는 경향을 보였다. 가스홀드업은 가스속도와 비례관계에 있으며 고정된 가스속도 조건에서 기포제농도 및 세척수속도와 비례관계였다.

The Effect of Carbide Precipitation on the High Temperature Deformation of Ni3Al and TiAl

  • Han, Chang-Suk;Kim, Jang-Woo;Kim, Young-Woo
    • 대한금속재료학회지
    • /
    • 제47권3호
    • /
    • pp.147-154
    • /
    • 2009
  • The effect of carbon addition on the microstructures and mechanical properties of $Ni_3Al$ and TiAl intermetallic alloys have been characterized. It is shown that carbon is not only an efficient solid solution strengthener in $Ni_3Al$ and TiAl, it is also an efficient precipitation strengthener by fine dispersion of carbide. Transmission electron microscope investigation has been performed on the particle-dislocation interactions in $Ni_3Al$ and TiAl intermetallics containing various types of fine precipitates. In an $L1_2$-ordered $Ni_3Al$ alloy with 4 mol.% of chromium and 0.2~3.0 mol.% of carbon, fine octahedral precipitates of $M_{23}C_6$ type carbide, which has the cube-cube orientation relationship with the matrix, appear during aging. Typical Orowan loops are formed in $Ni_3Al$ containing fine dispersions of $M_{23}C_6$ particles. In the L10-ordered TiAl containing 0.1~2.0 mol.% carbon, TEM observations revealed that needle-like precipitates, which lie only in one direction parallel to the [001] axis of the $L1_0$ matrix, appear in the matrix and preferentially at dislocations. Selected area electron diffraction (SAED) patterns analyses have shown that the needle-shaped precipitate is $Ti_3AlC$ of perovskite type. The orientation relationship between the $Ti_3AlC$ and the $L1_0$ matrix is found to be $(001)_{Ti3AlC}//(001)_{L10\;matrix}$ and $[010]_{Ti3AlC}//[010]_{L10\;matrix}$. By aging at higher temperatures or for longer period at 1073 K, plate-like precipitates of $Ti_2AlC$ with a hexagonal structure are formed on the {111} planes of the $L1_0$ matrix. The orientation relationship between the $(0001)_{Ti2AlC}//(111)_{L10\;matrix}$ is and $[1120]_{Ti2AlC}//[101]_{L10\;matrix}$. High temperature strength of TiAl increases appreciably by the precipitation of fine carbide. Dislocations bypass the carbide needles at further higher temperatures.

PL 리더십 성향과 프로젝트 특성요인이 프로젝트 참여 만족 및 성과에 미치는 영향 (The Effect of PL Leadership and Characteristics of Project on Project Participants' Satisfaction and Performance)

  • 양희동;김명진;강소라
    • Asia pacific journal of information systems
    • /
    • 제20권4호
    • /
    • pp.53-79
    • /
    • 2010
  • The study was originated from recognition that project participants' satisfaction should be Improved to raise project performance and to make progress of a successful project since the above dissatisfaction was operated as a danger factor of the project. The study selected one large-scale sample project and attempted measuring characteristics of the project, participants' satisfaction and project performance with the whole project participants. The study analyzed correlations between individual level (team members) and group level (development team), and examined what effect a sub project manager under complicated hierarchical organization of the large-scale project, namely PL (project leader)'s leadership style had on each individual project participant's satisfaction and what effect project uncertainty in organization/technology environment had on project participants' satisfaction and project performance. The study verified that development team (group) had an effect on team member (individual)-level project participants' satisfaction by disclosing that there was a significant dispersion among groups within project participants' satisfaction by each individual. It is analyzed that it is necessary to make improvement through approach by each pertinent team to raise individual-level project participants' satisfaction. The study also verified PL's ideal leadership under strict methodology and hierarchical control of the large-scale project. Based on the verification of the hypotheses, the results of the analysis were produced as follows. First, the development team affects the satisfaction level that an individual has when he/she participates in a project. This suggests that the satisfaction with project participation should be improved at the team level. In addition, the project management style and leadership orientation of the manager of a sub project who is mostly affected by the team proved to have a direct influence on the satisfaction with project participation and project performances. Second, both the performance-oriented leadership and the relationship-oriented leadership of the PL of the development team were verified to have a significant effect on the satisfaction of the team members associated with project participation. In other words, when the team members recognize that the PL of the development team shows both the performance-oriented leadership and the relationship-oriented leadership, their satisfaction with project participation increases accordingly. Third, it was verified that the uncertainty of the organizational environment significantly affects the satisfaction level when the PL of the development team exerts a relationship-oriented and performance-oriented leadership. The higher the uncertainty of the organizational environment is, the more the satisfaction with project participation decreases whereas the relationship-oriented leadership has a more positive effect on the satisfaction than the performance-oriented leadership style. Fourth, when the PL of the development team exerts the relationship-related and performance-related leadership, the uncertainty of the technological environment has a significant influence on the satisfaction level. The higher the uncertainty of the technological environment is, the more the satisfaction with project participation decreases whereas the performance-oriented leadership has a more positive effect on the satisfaction than the relationship-oriented leadership style. The result of the research on the uncertainty of the project environment suggests that when the development team leader exerts a relationship-oriented and performance-oriented leadership style, the uncertainty of the organizational environment has a significant effect on the satisfaction with project participation; the higher the uncertainty of the organizational environment, the more the satisfaction level decreases, and the relationship-oriented leadership style affects the satisfaction level more positively than the performance-oriented leadership style. In addition, when the development team leader displays a relationship-oriented and performance-oriented leadership style, the uncertainty of the technological environment has a significant effect on the satisfaction with project participation; the higher the uncertainty of the technological environment. the more the satisfaction level decreases. The performance-oriented leadership style as well affects the satisfaction level more positively than the relationship-oriented leadership style. Based on the above results, the research provides the following implications when handling multiple concurrent projects. First, the satisfaction with the participation in the multiple concurrent projects needs to be enhanced at the team (group) level. Second. the manager of the project team, particularly the middle managers should have both a performance-oriented and relationship (task and human)-oriented attitude and exert a consolidated leadership in order to improve the satisfaction of team members with project participation and their performances. Third, as the uncertainty factor of the technological and organizational environment among the characteristics factors of the project has room for methodological improvement depending on one's effort even though there are some complications, we need to continuously prevent and control the risks resulting from the uncertainties of the technological and organizational environment of the project in order to enhance the satisfaction of project participation and project performances. Fourth, the performance (task)-oriented leadership is required when there is uncertainty in a technological environment while the relationship (human)-oriented leadership is required when there is uncertainty in an organizational environment. This research has the following limitations. First, this research intended to select one large-sized sample project and measure the project characteristics, the satisfaction of all the participants associated with project participation, and their performances. Therefore, it is inappropriate to generalize and apply the result of this result onto other numerous projects. Second, as this case study entailed a survey to measure the characteristics factors and performance of the project, since the result value was based on the perception of project team members, the data may have insufficient objectivity. Third, though this research targeted on all the project participants, some development teams did not provide sufficient data and questionnaires were collected from some specific development teams among the 23 development teams, causing a significant deviation in the response rate among the development teams. Therefore, we need to continuously conduct the follow-up researches making comparisons among the multiple projects, and centering on the characteristics factors of the project and its satisfaction level.

파랑에너지를 이용한 항내 해수순환증진에 대한 연구 (A Study on the Water Circulation Enhancement inside Harbor Utilizing Wave Energy)

  • 오병철;전인식;정태성;이달수
    • 한국해안해양공학회지
    • /
    • 제14권3호
    • /
    • pp.209-221
    • /
    • 2002
  • 본 논문에서는 파랑에너지를 이용하여 항외의 해수를 항내로 유도하여 항내의 해수순환을 향상시키는 방법에 대하여 검토하였다. 파랑에너지를 활용하여 항내의 해수순환을 도모하기 위한 해안구조물로서는 월류제를 채택하여 제주외항에 적용하고 그 효과를 확률적인 관점에서 정량적으로 평가하였다. 월류제를 통한 해수유입량은 파고와 조위에 의하여 결정되는 것으로 가정하였으며 해수유입율과 파고 및 조위간의 함수관계는 수리모형실험 결과로부터 구하였다. 파랑수치모형의 후산자료와 검조소의 조위관측자료로부터 계산된 파고와 조위의 확률분포로부터 월류제를 통한 해수유입량의 확률분포를 구하는 방법을 제시하여 제주 외항에 적용한 결과 월류제를 통한 유량의 확률분포는 Gamma 함수에 근접하는 것으로 나타났으며 월류제의 최적위치에 대해서도 논의하였다. 그리고 월류제의 유무에 따른 항내오염확산을 계산하여 월류제에 의한 항내수질정화효과를 평가하였다.

그래핀 기반 폴리이미드 복합재의 기계적 물성 (Mechanical Properties of Graphene-based Polyimide Composites)

  • 남기호;유재상;유남호;한학수;구본철
    • Composites Research
    • /
    • 제30권5호
    • /
    • pp.261-266
    • /
    • 2017
  • 고분자 복합재료는 유기 중합체인 고분자 수지를 기지로 다양한 충전제를 균일하게 분산시킨 소재로서 가공성이 우수하며 제품의 다양성이 많은 특징이 있다. 최근에는 탄소 나노소재들이 개발됨에 따라 이를 보강재로 활용하여 보다 우수한 복합재료를 개발하기 위한 많은 노력이 있다. 보강재 본래의 특성을 최대한 복합재료로 전환시키기 위해서는 이들의 분산, 배향 및 계면특성이 매우 중요하게 여겨진다. 본 총설 논문에서는 그래핀 기반 폴리이미드 복합재료의 고강도화 및 고인성화 기술 전략으로써 그래핀 기능화에 의한 표면 화학구조와 물성간 상관관계를 도출하고 설명하고자 한다.

강우재현 원심모형실험에 적용하기 위한 수평변위 계측장치의 개발 (Development of Horizontal Displacement Sensor for Rainfall-simulated Centrifugal Model Test)

  • 이충원;박성용;김용성
    • 한국지반환경공학회 논문집
    • /
    • 제15권12호
    • /
    • pp.71-77
    • /
    • 2014
  • 집중호우는 사면의 붕괴와 사회 기반시설물의 파괴 등을 포함하는 다수의 재해를 유발한다. 이러한 관점에서 강우재현 원심모형실험은 지반구조물의 안정성을 평가하기 위한 합리적인 수단이 될 수 있다. 원심모형실험에서 모형의 변위를 취득하기 위하여 일반적으로 LVDT 또는 레이저 변위계가 사용된다. 그러나 강우모사 시 LVDT는 모형지반으로의 과다 침윤의 문제가 있으며, 레이저 변위계는 레이저의 산란에 의해 계측치의 정확성이 저하된다. 따라서 본 연구에서는 강우재현 원심모형실험에 적용하기 위한 수평변위 계측장치를 개발하였다. 본 연구를 통하여 탄성의 박철판과 스트레인 게이지를 이용하여 제작된 본 장치는 관입을 위한 말단부를 고정시켜 수행한 검정 결과로부터 정확한 변위-변형률 관계를 나타냄을 확인하였다.

부산직할시 영도지역의 정호간 지하수 간섭에 관한 수리지질 특성 연구 (A Study of Hydrogeological Properties Concerning to Groundwater Interference between Wells in the Yeongdo Island, Pusan, Korea)

  • 김항묵
    • 기술사
    • /
    • 제27권6호
    • /
    • pp.72-84
    • /
    • 1994
  • This is about an environmental study of groundwater interference by hydrodynamic dispersion between the well A and well C in Dongsam-dong, the Yeongdo Island, Pusan, Korea. The groundwater in the study wells come from the fracture zones deeply seated in welded lapilli rhyodacitic tuff of the Late Cretaceous Yucheon Group. The boring depth at the well A is 190 meters, and the optimal pumping rate of the well A is about 100 cubic meters per day therein. The fractured aquifers in impermeable welded tuff show the conjugate fracturing type and are of anisotropic. The aquifers along two fracture zones in the well A are 80 and 100 meters in depth, respectively. It is not suggested that those fractured aquifers are simply connected between the well A and C. The sea level fluctuation by ebb and high tides in a day is not effective to the groundwater table in the well A. The pumping for 15 days at the well A doesn't give rise to any changes of the groundwater levels in the neighbor well C. The radius of influence of the well A is measured as less than 200 meters. The measuring electric conductivity for the test of salt tracer doesn't testify any relationship between the well A and the well C. There is the main difference between the well A and the well C on the basis of the water analysis of those wells. the well A is located in the high content zone of salt much over the standard value for drinking, whereas the other wells B. C. D are in the low content area of salt below the standard value. It is elucidated for the high content zone of salt in Yeongdo around the well A to have been uplifted over 20 meters.

  • PDF

사출 블렌드 저밀도 폴리에틸렌의 절연파괴 특성 (Electrical Breakdown Properties of Extrusion Blended Low Density Polyethylene)

  • 조돈찬;김형주;신현택;이충호;이수원;홍진웅
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
    • /
    • pp.593-596
    • /
    • 2001
  • In the previous work, the effect of blending with two kinds of low density polyethylene (LDPE) on physical and electrical properties have been investigated. From the results, blending with two kinds of LDPE was effective method on changing the morphology of LDPE and improving the high-field characteristics in high temperature region. Especially, it suggested that the F$\_$BImp/ was associated with the changes of the crystal size. In this work, the relationship between the morphology and the high-field characteristics of blended LDPE was discussed. In addition, the physical and electrical properties of blended LDPE with extrusion treatment were investigated. The two groups of specimen were prepared; Group 1 was prepared by passing 1 time through the extruder included in the film-blowing process, and Group 2 was prepared by passing 2 times through the extruder. From the relation between the crystal size which was perpendicular to the (020) plane and the F$\_$BImp/ of blended LDPE, it was confirmed that the F$\_$BImp/ was associated with the changes of crystal size due to the blending. Moreover, the F$\_$BImp/ of blended LDPE in Group 2 was higher than that of blended LDPE in Group 1. The crystal size of the (020) plane became smaller according to the extrusion treatment. These results suggest that the uniform distribution and dispersion of crystalline occurred due to the extrusion treatment and the morphological change due to the extrusion treatment influenced on the electrical properties of blended LDPE.

  • PDF

절화장미 시설하우스에서 방제 작업시 농약의 피부노출 특성 (The characteristics of farmer's dermal exposure during pesticide spraying and dilution in cut rose greenhouse)

  • 김효철;김경란;이경숙;김경수;조경아
    • 한국산업보건학회지
    • /
    • 제17권3호
    • /
    • pp.203-211
    • /
    • 2007
  • This study was conducted in cut rose cultivation field in Goyang to evaluate pesticide exposure of farmers and the relationship between the exposure and work environment/method for cut rose farmers. Dermal exposure was assessed with patch (thin chromatography layer paper), cotton glove by body parts during mixing and spraying works in which pyrethroid, organophosphate, carbamate pesticide were used in 4 cut rose greenhouses located in Goyang province, checking characteristics of environment/working method at the same time. Body parts assessed were as follows ; glove : hand, patch : head, neck(front/back), chest, back, shoulder(right/left), upperarm(right/left), forearm(right/left), thigh(right/left), shin(right/left). Pesticides were analyzed using gas chromatography(NPD/FID) after extracting with ethyl acetate. Exposure amount differed according to pesticide type. But after standardizing with total net weight of pesticide sprayed, there were no significant difference among pesticides. There were significant difference in exposure amount among body parts(especially exposure amount of thigh, shin were more than the others), which means exposure happen not by pesticide dispersion in air but by contact with cut rose(leaf, branch) indirectly. Walking forward during spraying made farmers more exposed than waling backward, these results means contacts with leaves/branches made exposure happen in cut rose greenhouse also. As a result, pesticide exposure in cut rose greenhouse was related with contact of leaf/branch which pesticide remained in, which made exposure pattern (especially exposure amount) differ by body parts