• Title/Summary/Keyword: dispersion relation

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Relation between the Concentration of Hexagonal Boron Nitride Nano-Sheets Dispersed in Pure Water and Their Width and Height (초순수 용매 내 육방정 질화붕소 나노시트의 농도와 크기의 관계)

  • Cho, Dae-Hyun;Park, Miyoung;Ha, Seonghun
    • Tribology and Lubricants
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    • v.35 no.6
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    • pp.343-349
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    • 2019
  • According to a report in 2011, hexagonal boron nitride demonstrated good solubility in pure water, even without surfactants or organic functionalization. Hexagonal boron nitride nanosheets are an effective lubricant additive, and their solubility in pure water has motivated lubrication engineers to utilize aqueous solutions containing these nanosheets as water-based lubricants. In this study, we measure the width and height of the hexagonal boron nitride nanosheets dispersed in pure water by using the Zetasizer and atomic force microscopy. Without surfactants or functionalization, aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of hexagonal boron nitride nanosheets are synthesized via sonication-assisted hydrolysis. The Zetasizer provides only a one-dimensional size of approximately 410 nm, regardless of the concentration of the solution. Thus, it does not allow the estimation of the shape of the nanosheet. To acquire the three-dimensional size of the nanosheets, atomic force microscopy is employed. The aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of the hexagonal boron nitride nanosheets show average values of 740, 450, 700, and 610 nm in width, and 37, 26, 33, and 32 nm in thickness, respectively. No significant trend is observed between the concentration of the solution and size of the nanosheets. Therefore, when preparing a water-based lubricant, it may be appropriate to adjust conditions such as ultrasonication time rather than the concentration.

Influence of loose bonding, initial stress and reinforcement on Love-type wave propagating in a functionally graded piezoelectric composite structure

  • Singh, Abhishek K.;Parween, Zeenat;Chaki, Mriganka S.;Mahto, Shruti
    • Smart Structures and Systems
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    • v.22 no.3
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    • pp.341-358
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    • 2018
  • This present study investigates Love-type wave propagation in composite structure consists of a loosely bonded functionally graded piezoelectric material (FGPM) stratum lying over a functionally graded initially-stressed fibre-reinforced material (FGIFM) substrate. The closed-form expressions of the dispersion relation have been obtained analytically for both the cases of electrically open and electrically short conditions. Some special cases of the problem have also been studied and the obtained results are found in well-agreement with the classical Love wave equation. The emphatic influence of wave number, bonding parameter associated with bonding of stratum with substrate of the composite structure, piezoelectric coefficient as well as dielectric constant of the piezoelectric stratum, horizontal initial stresses, and functional gradedness of the composite structure on the phase velocity of Love-type wave has been reported and illustrated through numerical computation along with graphical demonstration in both the cases of electrically open and electrically short condition for the reinforced and reinforced-free composite structure. Comparative study has been carried out to analyze the distinct cases associated with functional gradedness of the composite structure and also various cases which reveals the influence of piezoelectricity, reinforcement and horizontal initial stress acting in the composite structure, and bonding of the stratum and substrate of the composite structure in context of the present problem which serves as one of the major highlights of the study.

Electrical Breakdown Properties of Extrusion Blended Low Density Polyethylene (사출 블렌드 저밀도 폴리에틸렌의 절연파괴 특성)

  • 조돈찬;김형주;신현택;이충호;이수원;홍진웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.593-596
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    • 2001
  • In the previous work, the effect of blending with two kinds of low density polyethylene (LDPE) on physical and electrical properties have been investigated. From the results, blending with two kinds of LDPE was effective method on changing the morphology of LDPE and improving the high-field characteristics in high temperature region. Especially, it suggested that the F$\_$BImp/ was associated with the changes of the crystal size. In this work, the relationship between the morphology and the high-field characteristics of blended LDPE was discussed. In addition, the physical and electrical properties of blended LDPE with extrusion treatment were investigated. The two groups of specimen were prepared; Group 1 was prepared by passing 1 time through the extruder included in the film-blowing process, and Group 2 was prepared by passing 2 times through the extruder. From the relation between the crystal size which was perpendicular to the (020) plane and the F$\_$BImp/ of blended LDPE, it was confirmed that the F$\_$BImp/ was associated with the changes of crystal size due to the blending. Moreover, the F$\_$BImp/ of blended LDPE in Group 2 was higher than that of blended LDPE in Group 1. The crystal size of the (020) plane became smaller according to the extrusion treatment. These results suggest that the uniform distribution and dispersion of crystalline occurred due to the extrusion treatment and the morphological change due to the extrusion treatment influenced on the electrical properties of blended LDPE.

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Study of PSII-treated PMMA, PHEMA, and PHPMA ; Investigation of Their Surface Stabilities

  • Hyuneui Lim;Lee, Yeonhee;Seunghee Han;Jeonghee Cho;Moojin suh;Kem, Kang-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.204-204
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    • 1999
  • The plasma source ion implantation(PSII) technique which is a method using high negative voltage pulse in plasma system has the potential to change the surface properties of polymer. PSII technique increase the surface free energy by introducing polar functional groups on the surface so that it improves reactivity, hydrophilicity, adhension, biocompatability, etc. However, the mobility of polymer chains enables the modified surface layers to adapt their composition to interfacial force. This hydrophobic recovery interrupts the stability of modified surfaces to keep for the long time. In this study, poly(methyl methacrylate)(PMMA), poly(2-hydroxyethyl methacrylate)(PHEMA), and polu(2-hydroxypropyl methacylate)(PHPMA) for contact lens application, were modified to improve the wettability with PSII technique and were investigated the surface stabilities. Polymer film was prepared with solution casting(3 wt.% solution) and was annealed at 11$0^{\circ}C$ under vacuum oven to remove solvent completely and to eliminate physical ageing. The thickness of the film measured by scanning electron microscopy (SEM) and surface profilometer was about 10${\mu}{\textrm}{m}$. Polymers were treated with different kinds of gases, pulse frequency, pulse with, pulse voltage, and treatment time. Even though PMMA, PHEMA, and PHPMA have similar repeat unit structure, the optimal treatment conditions and the tendency to hydrophobic recovery were different. PHPMA, more hydrophilic polymer than PMMA and PHEMA showd better wettability and stability after mild treatment. Surface tensions were obtained by water and diiodomethane contact angle measurements to monitor the relation between hydrophobic recovery and polymer structure. Different ion species in plasma change the polar component and dispersion component of polymer surface. For better wettability surface, the increase of polar component was a dominant factor. We also characterized modified polymer surfaces using x-ray photoelectron spectroscopy(XPS), secondary ion mass spectrometry(SIMS), Fourier Transform infrared spectroscopy(FT-IR), and SEM.

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The AGN-Bar Connection

  • Lee, Gwang-Ho;Woo, Jong-Hak;Lee, Myung-Gyoon;Park, Chang-Bom;Choi, Yun-Young;Hwang, Ho-Seong;Lee, Jong-Hwan;Sohn, Ju-Bee
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.33.1-33.1
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    • 2010
  • We investigate the relation between the presence of bars in galaxies and AGN activities. Bars are believed to play an important role in fueling of AGN. Although there have been many previous studies on this topic, "the AGN-Bar Connection" is still an open question. To better understand the connection, we use a volume-limited sample of 9,726 late-type galaxies brighter than $M_r$=-19.5+5logh at $0.02{\leqq}z{\leqq}0.05489$, drawn from SDSS DR7. Among galaxies in the sample, 1,963 galaxies are classified as AGN-host galaxies based on the emission-line ratios while barred galaxies are identified by visual inspection. The bar fraction in AGN host galaxies (22.5%) is 3-times higher than in star-forming galaxies (8.6%). However, this trend is simply caused by the fact that the bar fraction increases with galaxy mass or luminosity and that AGN host galaxies are on average more massive than star-forming galaxies. Nevertheless, we find that among AGN host galaxies, the bar fraction increases with the Eddington ratio $(L_{[OIII]}/M_{[BH]})$, and this trend remains intact even at fixed galaxy luminosity and stellar velocity dispersion. These results imply that bars play a role in triggering AGNs.

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An efficient shear deformation theory for wave propagation in functionally graded material beams with porosities

  • Benadouda, Mourad;Atmane, Hassen Ait;Tounsi, Abdelouahed;Bernard, Fabrice;Mahmoud, S.R.
    • Earthquakes and Structures
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    • v.13 no.3
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    • pp.255-265
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    • 2017
  • In this paper, an efficient shear deformation theory is developed for wave propagation analysis in a functionally graded beam. More particularly, porosities that may occur in Functionally Graded Materials (FGMs) during their manufacture are considered. The proposed shear deformation theory is efficient method because it permits us to show the effect of both bending and shear components and this is carried out by dividing the transverse displacement into the bending and shear parts. Material properties are assumed graded in the thickness direction according to a simple power law distribution in terms of the volume fractions of the constituents; but the rule of mixture is modified to describe and approximate material properties of the functionally graded beams with porosity phases. The governing equations of the wave propagation in the functionally graded beam are derived by employing the Hamilton's principle. The analytical dispersion relation of the functionally graded beam is obtained by solving an eigenvalue problem. The effects of the volume fraction distributions, the depth of beam, the number of wave and the porosity on wave propagation in functionally graded beam are discussed in details. It can be concluded that the present theory is not only accurate but also simple in predicting the wave propagation characteristics in the functionally graded beam.

Coastally Trapped Waves over a Double Shelf Topography(II) : Free Waves with Linear Topographies (양향성 대륙붕의 대륙붕파 (II): 선형함수적 해저지형에서의 자유파)

  • PANG Ig-Chan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.25 no.6
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    • pp.443-456
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    • 1992
  • For a linear double shelf bottom topography as in the Yellow Sea, the dispersion relation of coastally trapped waves is derived for the general case Including high-frequency and short waves and for the case of low-frequency and long waves. With linear bottom topography, the governing equation is Bessel's equation for the latter case but Hummer's equation for the former case. Hypergeometric Functions, which are the solutions of Hummer's equation, are derived and converted to various special functions for the limiting cases. On a double shelf topography, the divergence effects of horizontal flow are important for the wave dynamics, irrespective of cross-shelf dimensions, while on a single shelf they are usually neglected when the cross-shelf dimension is much smaller than the Rossby deformation radius. The divergence effect allows the existence of Kelvin wave and reduces the phase speeds of continental shelf waves. Finally, the frictionless eigenfunctions are proved to be orthogonal.

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The Selection and Decision in R&D and Patents: A Hurdle Negative Binomial Approach (허들음이항모형을 이용한 기업의 혁신선택과 특허성과의 결정요인에 관한 연구)

  • Park, Jaemin
    • Journal of Korea Technology Innovation Society
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    • v.17 no.3
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    • pp.449-466
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    • 2014
  • There have been various researches on the relationship between a company's R&D investment and the outcome from innovation. However, these studies failed to effectively analyze the decision-making process followed by companies in relation to knowledge production. Especially, in analyzing the patent of companies, the Poisson model has been commonly used, but its limitations have been pointed out. In recent years, many studies have adopted negative binomial models, but they still pose limitations in analyzing the selection process. This paper proposed a hurdle negative binomial model to effectively reflect the company's decision embedded within patent information and conduct an empirical analysis on a survey of businesses' activities. In particular, the study analyzed the selection process of companies in determining the number of patents. As a result of estimation, the presence of over-dispersion was identified. In addition, the Wald-test confirmed that setting up of hurdles was valid, and there was a difference between the results of hurdle models and those of general negative binomial settings.

Aluminium Aluminium Titanate-Mullite Composites: Part2. Thermal Shock Resistance (Aluminium Aluminium Titanate-Mullite 복합체: Part2. 열충격성)

  • Kim, Ik-Jin;Gang, Won-Ho;Go, Yeong-Sin
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.206-212
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    • 1994
  • Aluminium titanate-mullite composites with varying chemical compositions were prepared by the stepwise hydrolysis of $Si(OC_2H_5)_4$, and $Ti(OC_2H_5)_4$in $AI_2O_3$ ethanolic colloidal dispersion. Sintered bodies having 20-50~01% mullite at $1600^{\circ}C$ for 2h have shown, that it is possible to develop an aluminium titanate with moderately high strength and low thermal expansion coefficient. This was obtained by inhibiting grain site of aluminium titanate with mullite and microcracks. Those with 80-70vol % aluminium titanate have excellent thermal shock resistance and has room-temperature strengths of 31-45MPa. The relation between thermal shock resistance and strength, Young's modulus, sound velocity and thermal expansion coefficient was discussed.

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The Fatigue Behavior of Mechanically Alloyed Al-4Mg Alloys Dispersed with Oxide Particles (기계적합금화된 분산형 Al-4Mg기 합금의 피로거동)

  • Pyun, J.W.;Cho, J.S.;Kwun, S.I.;Jo, Y.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.4
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    • pp.237-242
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    • 1993
  • The fatigue behaviors of mechanically alloyed Al-4Mg alloys dispersed with either $Al_2O_3$ or $MgAl_2O_4$ oxide particles were investigated. This study maily concerned with the role of coherency of dispersed particles with the matrix on the fatigue behavior of the alloys. The $MgAl_2O_4$ which has a spinel structure with the lattice parameter of exactly the twice of Al showed the habit relation with the matrix. The mechanically alloyed Al-4Mg alloys showed stable stress responses with fatigue cycles from start to failure regadless of strain amplitudes and of existence of dispersoids. The Al-4Mg alloy dispersed with $MgAl_2O_4$ showed not only the better static mechanical properties but also the better low cycle fatigue resistance than that with $Al_2O_3$, i.e., much higher plastic strain energy dissipated to failure, at low strain amplitude. However, this alloy showed inferior fatigue resistance to that dispersed with $Al_2O_3$ or that without dispersion at high strain amplitude. These results imply that $MgAl_2O_4$ may promote lowering the stacking fault energy of the alloy inherited from the coherency with the matrix so that dislocations shuttle back and forth on the same slip plane without cross slipping to other planes during fatigue at low strain amplitude resulting in long fatigue life.

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