• Title/Summary/Keyword: dispersion property

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Synthesis of stable colloidal zirconia sol by adsorption of polyvinyl alcohol (PVA 흡착에 의한 안정한 콜로이드 지르코니아 졸의 합성)

  • Lee, Jong-Kook;Moon, Gi-Dong;Kim, Hwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.2
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    • pp.165-174
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    • 1995
  • A stable suspension with a colloidal $ZrO_2$ particle was prepared by an adsorption of PV A and investigated to the effects of PV A on the dispersion and particle growth within suspension. With a suspension added the optimum concentration of PYA (about 500 ppm in this study), it was shown the property of a stable sol due to the formation of adsorbed PV A layer on surface and the reduction of an agglomeration among the particles. Most of nucleation in colloidal $ZrO_2$ were occured in the early stage of hydrolysis reaction and the plate-like monoclinic $ZrO_2$ particle were grown with an aging time. The rate of particle growth and yield for a reaction were decreased with an addition of PV A. The compact prepared from well- dispersed suspension by an addition of PV A was contained the homogeneous particle arrangement and pore distribution.

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Fiber Orientation Impacts on the Flexural Behavior of Steel Fiber Reinforced High Strength Concrete (섬유의 방향성이 강섬유 보강 초고강도 콘크리트의 휨거동 특성에 미치는 영향)

  • Kang, Su-Tae;Kim, Yun-Yong;Lee, Bang-Yun;Kim, Jin-Keun
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.731-739
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    • 2008
  • To evaluate the fiber orientation characteristics and estimate its effect on the flexural strength of steel fiber reinforced ultra high strength concrete with directions of concrete placing, we developed an image processing technique and carried out the flexural test to quantify the effect of fiber orientation characteristics on the flexural strength as well. The image processing technique developed in this study could evaluate quantitatively the fiber orientation property by the use of dispersion coefficient, the number of fibers in a unit area, and fiber orientation. It was also found that the fiber orientation characteristics were dependent on the direction of concrete placing. Fiber orientation characteristic was revealed to strongly affect the ultimate flexural strength, while hardly affecting the first cracking strength. Theoretical model for flexural strength was applied to compare with test results, which exhibited a good agreement.

Representation of Runoff Area by means of DEM (DEM을 이용한 유출역의 도시)

  • Kim, Joo Cheol;Yoon, Yeo Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.5B
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    • pp.287-293
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    • 2012
  • This study suggests the topographic index-based methodology which can be used to represent the saturation of soil and thereby change of variable runoff area at basin scale. ${\infty}$-flow direction method is applied to estimate topographic index because of its freedom from the restriction of 8-flow direction method as well as possibility of the minimum flow dispersion. From the comparison of topographic index distribution with the existing result the methodology is shown to be a workable one. It is judged that the representation of variable runoff area may be a systematic tool to investigate the dynamic and non-linear property of rainfall-runoff process because it can provide the explicit way to spatial distribution of basin saturation.

Preparation and Physical Properties of Acrylonitrile-Butadiene Rubber Nanocomposites Filled with Zinc Dimethacrylate (디메틸아크릴산 아연을 이용한 아크릴로나이트릴-부타디엔 고무 나노복합체의 제조 및 물성)

  • 진원섭;이해성;나창운
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.185-193
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    • 2004
  • Elastomeric nanocomposites were prepared by employing zinc dimethacrylate into an acrylonitrile-butadiene rubber, and their network structures, mechanical properties, and fracture morphologies were investigated according to the adding methods and contents of zinc dimethacrylate. The total crosslink density increased with increasing the zinc dimethacrylate level, due to increased ionic bonds. Both the tensile strength and tear strength increased with increasing zinc dimethacrylate loadings, and then decreased after reaching a maximum value. It was found that the tear strength and crack resistance were greatly affected by the mixing method of zinc dimethacrylate. The in-situ nanocomposites, where zinc dimethacrylate particles were formed by the reaction of zinc oxide and methacrylic acid, showed much improved tear strength and crack resistance compared to those of the nanocomposites based on the direct mixing of zinc dimetacrylate powders. This was because of the finer zinc dimethacrylate particles and improved dispersion of the in-situ nanocomposites.

A Study on the Numerical Wave Propagation Properties of the Finite Difference-Time Domain(FD-TD) Method for EM Wave Problems (전자파 문제에 대한 시간영역-유한차분법의 수치파 전파모델의 성질에 관한 연구)

  • 김인석
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.8
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    • pp.1595-1611
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    • 1994
  • In this paper, the numerical wave propagation properties of the finite difference-time domain(FD-TD) method is investigated as a discrete model describing electromagnetic(EM) wave propagation phenomena. The leap-frog approximation of Maxwell's curl equations in time-space simulates EM wave propagation in terms of the numerical characteristic and the domain of dependence. A geometrical interpretation of the FD-TD numerical procedure is presented. The numerical dispersion error due to the leap-frog approximation and its dependence on the stability factor are illustrated. The FD-TD method using the leap-frog approximation is inherently a descriptive model. Thus, not only any physical picture about EM wave propagation phenomena can be drawn through this model, but also physical or engineering parameters in the frequency domain can be extracted from descriptive results. E-plane filter characteristics in the WR-28 rectangular waveguide and reflection property of an inductive iris in the WR-90 rectangluar waveguide extracted from simulation of the FD-TD model is included.

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Environmentally Friendly Moisture-proof Paper with Superior Moisture Proof Property (I) -Properties of Moisture Proof Chemicals- (방습 효과가 우수한 환경친화적 방습지(제1보) -방습제의 특성-)

  • 유재국;조욱기;이명구
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.4
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    • pp.15-20
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    • 2001
  • The function of the moisture-proof paper is to prevent moisture from adsorbing into the packed goods. Water-vapor transmission rate of the moisture-proof paper should be less than 100g/$m^2$.24hr and the optimum rate would be less than 50g/$m^2$.24hr. In general the moisture-proof paper has been made by laminating polyethylene or polypropylene on top of the base paper. However this kind of moisture-proof paper has a problem in recycling so that it brings about environmental pollution. In general the moisture-proof paper has been made by laminating polyethylene or polypropylene on top of the base paper. However this kind of moisture-proof paper has a problem in recycling so that it brings about environmental pollution. The purpose of this paper was to make moisture-proof paper using the mixture of SB latex and wax emulsion which was recyclable and environmentally friendly. Water vapor transmission rate showed less than 50g/$m^2$.24hr in mixture ratio of 85:15, 87:13, 90:10. Especially the mixture ratio of 87:13 showed the most favorable water-vapor transmission rate. However, the moisture-proof layer was destroyed slightly by folding in packing. It has been observed that there was no close relationship between water-vapor transmission rate of the moisture-proof paper and grammage of the base paper, but the density of base paper had influenced on water vapor transmission rate. It was also observed that the moisture-proof paper could be recycled. The moisture-proof paper was similar to base paper in degree of the pulping, and there was no significant difference in dispersion between moisture-proof paper and base paper. Most of wax particles which caused the spots during drying process could be removed by flotation process. Tensile strength and tear strength of both moisture-proof paper and base paper after pulping were measured to examine the fiber bonding, and no significant difference in physical properties was observed.

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Fabrication of Metallic Particle Dispersed Ceramic Based Nanocomposite Powders by the Spray Pyrolysis Process Using Ultrasonic Atomizer and Reduction Process

  • Choa, Y.H.;Kim, B.H.;Jeong, Y.K.;Chae, K.W.;T.Nakayama;T. Kusunose;T.Sekino;K. Niibara
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.151-156
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    • 2001
  • MgO based nanocomposite powder including ferromagnetic iron particle dispersions, which can be available for the magnetic and catalytic applications, was fabricated by the spray pyrolysis process using ultra-sonic atomizer and reduction processes. Liquid source was prepared from iron (Fe)-nitrate, as a source of Fe nano-dispersion, and magnesium (Mg)-nitrate, as a source of MgO materials, with pure water solvent. After the chamber were heated to given temperatures (500~$^800{\circ}C$), the mist of liquid droplets generated by ultrasonic atomizer carried into the chamber by a carrier gas of air, and the ist was decomposed into Fe-oxide and MgO nano-powder. The obtained powders were reduced by hydrogen atmosphere at 600~$^800{\circ}C$. The reduction behavior was investigated by thermal gravity and hygrometry. After reduction, the aggregated sub-micron Fe/MgO powders were obtained, and each aggregated powder composed of nano-sized Fe/MgO materials. By the difference of the chamber temperature, the particle size of Fe and MgO was changed in a few 10 nm levels. Also, the nano-porous Fe-MgO sub-micron powders were obtained. Through this preparation process and the evaluation of phase and microstructure, it was concluded that the Fe/MgO nanocomposite powders with high surface area and the higher coercive force were successfully fabricated.

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The functions & Requirements of the Semi-Conducting layer in the power cable. (전력 케이블에서 반도전층의 역할과 요구 특성)

  • Jung, Yun-Tack;Nam, Jong-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.101-105
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    • 2001
  • For high voltage XLPE power cables, semiconducting layers have been applied to prevent discharge at the interface between conductor and insulation, and/or insulation and external shielding layer. The semiconducting layers may be also effective to release electrical stress in the interface. The property of semiconducting layers are significantly related to the quality and reliability of power cables. Generally, these semiconducting layers are formed by extruding, the conductibility of the material is given by the carbon black mixed with base polymer. The life of power cables is depended on the smoothness of the interface between insulation and semiconducting layer. If the smoothness is no good, the life of power cables is shorter because the electrical stress and water tree is increased. The causes of no good smoothness are the void of the interface, the protrusions, the contaminants and impurities of the semiconducting layer. The selection and dispersion of the Carbon Black is the significant factor to determine the life of power cable in the manufacturing of semiconducting compound.

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Effects of Organoclay on the Thermal Insulating Properties of Rigid Polyurethane Foams Blown by Environmentally Friendly Blowing Agents

  • Kim, Youn-Hee;Choi, Seok-Jin;Kim, Ji-Mun;Han, Mi-Sun;Kim, Woo-Nyon;Bang, Kyu-Tae
    • Macromolecular Research
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    • v.15 no.7
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    • pp.676-681
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    • 2007
  • A process designed to synthesize rigid polyurethane foam (PUF) with insulative properties via the modulation of PUF cell size via the addition of clay and the application of ultrasound was assessed. The blowing agents utilized in this study include water, cyclopentane, and HFC-365mfc, all of which are known to be environmentally-friendly blowing agents. The rigid PUFs were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI) and polyether polyol with a density of $50kg/m^3$. In addition, rigid PUFs/clay nanocomposites were synthesized with clay modified by PMDI with and without the application of ultrasound. The PUF generated using water as a blowing agent evidenced the highest tensile strength. The tensile strength of the PUF/nanocomposites was higher than that of the neat PUF and the strength was even higher with the application of ultrasound. The cell size of the PUF/clay nanocomposites was less than that of the neat PUF, regardless of the type of blowing agent utilized. It appears that the higher tensile strength and lower cell size of the PUF/clay nanocomposites may be attributable to the uniform dispersion of the clay via ultrasonic agitation. The thermal conductivity of the PUF/clay nanocomposites generated with HCFC-141b evidenced the lowest value when PUF/clay nanocomposites were compared with other blowing agents, including HFC-365mfc, cyclopentane, and water. Ultrasound has also proven effective with regard to the reduction of the thermal conductivity of the PUF/clay nanocomposites with any of the blowing agents employed in this study. It has also been suggested that the uniformly dispersed clay particles in the PUF matrix function as diffusion barriers, which prevent the amelioration of the thermal insulation property.

Al-10wt%Ti-4wt%F Alloys as In-situ Composites through Rapid Solidification(II) (급냉응고법에 의한 In-Situ 복합재료로서의 Al-10wt%Ti-4wt%Fe 합금 (II))

  • Kim, Hye-Seong;Jeong, Jae-Pil;Gwon, Suk-In;Geum, Dong-Hwa
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1127-1132
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    • 1998
  • The possibilities of producing Al-10%Ti-4%Fe composites through in-situ processing and thus achieving mechanical property improvements over binary Al-10%Ti to a level or higher exhibited by PM SiC/A12124 composites were explored in this study. The microstructure of in-situ processed Al-10%Ti-4%Fe composites was similar to that of Al matrix composites reinforced with discontinuous SiC particulates(SiC/A12124) and significant enhancements in elastic modulus, tensile strength and wear resistance were observed as compared to Al-10%Ti alloy. These results can be attributed to the in-situ formed Al. Fe by third element addition, leading to additional dispersion strengthening effect over $Al_3Ti$ phase reinforcement in Al-Ti system.

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