• Title/Summary/Keyword: dispersion property

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Pigment Influence of High Density Polyethylene Electrical Strength (고밀도 폴리에틸렌의 전계 세기의 영향)

  • Choi, Yong-Sung;Wee, Sung-Dong;Hwang, Jong-Sun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.50-53
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    • 2008
  • In this work, the $TiO_2$ pigment influence in HDPE dielectric strength was analyzed. Chemical and structural characterizations were made to identify changes during the processing and your influence in the electrical properties. Formulations containing 0, 0.5, 1, 2.5, 4 and 6 of titanium dioxide were processed by extrusion and injection molding with stabilization-antioxidants, ultraviolet stabilizers and plasticizers. The electrical strength tests were analyzed by the statistical distribution of Weibull, and the maximum likelihood method. The high concentrations present lower values to electrical strength. The $\beta$ parameter could be using to insulator particles dispersion. The $TiO_2$ concentration variation shows that these incorporations implicate strength values increase has a maximum (5,35MV/cm). High pigment concentration induces a little falls in property values. Observing the $\beta$ parameter, minimum experiment electric field (Ebmin) and electric strength value, found that the best electric perform formulation was the formulation with 2.5% $TiO_2$ weight.

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Growth Mechanism of Nickel Nanodispersoids during Consolidation of $Al_2O_3/Ni$ Nanocomposite Powder ($Al_2O_3/Ni$ 나노복합분말의 치밀화중 분산상 Ni의 성장기구)

  • ;;;;T. Sekino;K. Niihara
    • Journal of Powder Materials
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    • v.7 no.4
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    • pp.237-243
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    • 2000
  • The property and performance of the $Al_2O_3/Ni$ nanocomposites have been known to strongly depend on the structural feature of Ni nanodispersoids which affects considerably the structure of matrix. Such nanodispersoids undergo structural evolution in the process of consolidation. Thus, it is very important to understand the microstructural development of Ni nanodispersoids depending on the structure change of the matrix by consolidation. The present investigation has focused on the growth mechanism of Ni nanodispersoids in the initial stage of sintering. $Al_2O_3/Ni$ powder mixtures were prepared by wet ball milling and hydrogen reduction of $Al_2O_3$ and Ni oxide powders. Microstructural development and the growth mechanism of Ni dispersion during isothermal sintering were investigated depending on the porosity and structure of powder compacts. The growth mechanism of Ni was discussed based upon the reported kinetic mechanisms. It is found that the growth mechanism is closely related to the structural change of the compacts that affect material transport for coarsening. The result revealed that with decreasing porosity by consolidation the growth mechanism of Ni nanoparticles is changed from the migration-coalescence process to the interparticle transport mechanism.

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Surface Modification of Cement-Reinforcing Carbon Fibers by Low Temperature Plasma Process (저온 플라즈마 공정을 이용한 시멘트 보강용 탄소 섬유의 표면개질)

  • Cho, Dong Lyun;Kim, Hoon
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.361-365
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    • 2005
  • Cement-reinforcing carbon fibers were surface-modified with $O_2$, $H_2O$, acrylic acid, diaminocyclohexane plasmas and their effects were investigated. Hydrophobic surfaces with water contact angles of $75{\sim}80^{\circ}$ were changed to hydrophilic surfaces. The water contact angles were reduced down to lower than $10^{\circ}$. As a result, the fiber's hygroscopic property and dispersion in water were improved. Also, Zeta potential of the fiber in water was changed from a negative value to positive values. As a result, adhesion with cement that had a negative Zeta potential was improved up to 57~124% through increased electrostatic interaction.

Densification and Some Properties of Carbon Nanotubes-Dispersed Al2O3 Nanocomposite Powders (탄소나노튜브가 분산된 Al2O3 나노복합분말의 치밀화 및 특성)

  • Yoo Seung-Hwa;Yang Jae-Kyo;Oh Sung-Tag;Kang Kae-Myung;Kang Sung-Goon;Choa Yong-Ho
    • Journal of Powder Materials
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    • v.12 no.6 s.53
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    • pp.393-398
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    • 2005
  • In-situ processing route was adopted to disperse carbon nanotubes (CNTs) into $Al_2O_3$ powders homogeneously. The $Al_2O_3$ composite powders with homogeneous dispersion of CNTs could be synthesized by a catalytic route for in-situ formation of CNTs on nano-sized Fe dispersed $Al_2O_3$ powders. CNTs/Fe/$Al_2O_3$ nanopowders were densified by spark plasma sintering (SPS). The hardness and bending strength as well as electrical conductivity increased with increasing sintering temperature. However, the electrical conductivity of the composites sintered at above $1500^{\circ}C$ showed decreased value with increasing sintering temperature due to the oxidation of CNTs.

Thermal Property of CNT/Cu Nanocomposite (Carbon Nanotube/Cu 나노복합체의 열적특성)

  • Hong, Youn-Jeong;Kim, Hye-Jin;Jung, Chung-Hun;Lee, Kyu-Mann
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.89-90
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    • 2006
  • The CNTs are of great interest because of their unique complete properties of matter, especially, the large thermal conductivity (Thermal conductivity of CNTs ~ >2000W /mK vs. Thermal conductivity of Aluminum ~ >204W/mK). However, owing to the strong agglomeration cause by the vander wall's force, the CNTs are limited to applicate. In this study. we suggest a new method for CNTs dispersion. which are developed by the mechanical and chemical method. and then Cu was coated. This new process produces CNTs/Cu nanocomposite powders. The CNTs are homogeneously located within the Cu powders by chemical reaction. And the thermal properties of the CNTs/Cu nanocomposite were investigated.

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Preparation and Property of Water Based Manetic Fluid by Peptization Method (해교법에 의한 수상자성유체의 제조 및 특성에 관한 연구)

  • Oh, Jae-Hyun;Kim, Min-Seuk;Kim, Mahn;Kim, Seung-Wan
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.234-240
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    • 1993
  • The water-based magnetic fluids were prepared with the synthesized ultrafine magnetite, dodecanoic acid as surfactant. Characteristics of synthesized ultrafine magnetite were investigated with X-ray Diffraction Pattern, Transmission Electron Microscope, Vibrating Sample Magnetometer and BET analysis. Dispersion characteristics of water-based magnetic fluids were investigated in relation to amounts of surfactant, pH and solid content.

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Preparation of Al@Fe2O3 Core-Shell Composites Using Amphiphilic Graft Copolymer Template

  • Patel, Rajkumar;Kim, Sang Jin;Kim, Jin Kyu;Park, Jung Su;Kim, Jong Hak
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.209-213
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    • 2014
  • A graft copolymer of poly(vinyl chloride)-g-poly(oxyethylene methacrylate) (PVC-g-POEM) was synthesized via atom transfer radical polymerization (ATRP) and used as a structure-directing agent to prepare $Al@Fe_2O_3$ core-shell nanocomposites through a sol-gel process. The amphiphilic property of PVC-g-POEM allows for good dispersion of Al particles and leads to specific interaction with iron ethoxide, a precursor of $Fe_2O_3$. Secondary bonding interaction in the sol-gel composites was characterized by Fourier transform-infrared (FT-IR) spectroscopy. The well-organized morphology of $Al@Fe_2O_3$ core-shell nanocomposites was observed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Energy dispersive X-ray (EDX) and X-ray diffraction (XRD) were used to analyze the elemental composition and crystallization structure of the composites.

Hydrothermal Synthesis of Red-Emitting Y(V0.5,P0.5)O4:Eu Nanophosphors and their Application to Transparent Plasma Display Fabrication (적색발광 Y(V0.5,P0.5)O4:Eu 나노형광체의 수열 합성 및 투명 플라즈마 디스플레이 소자 제작으로의 응용)

  • Song, Woo-Seuk;Yang, Hee-Sun
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.86-93
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    • 2011
  • Transparent plasma display can be realized by developing the synthetic chemistry of appropriate nanophosphors and generating nanophosphor-based transparent luminescent layers. For this goal, red-emitting $Y(V_{0.5},\;P_{0.5})O_4$:Eu nanophosphors were synthesized by a facile hydrothermal route at $200^{\circ}C$ for 48 h and the resulting nanophosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and emission property of the as-synthesized and annealed nanophosphors were compared. Choosing 2-methoxyethanol as a dispersion medium and applying a standard sonication, well-dispersed nanophosphor solutions could be prepared. Using these dispersions, visible transparent nanophosphor layers were spin-deposited on glass substrates. By combining $Y(V_{0.5},\;P_{0.5})O_4$:Eu nanophosphor layer/glass substrate as a rear plate with a front plate used in a conventional plasma display panels (PDPs), mini-sized transparent red-emitting PDPs were constructed. Transmittance and luminance properties of two transparent test panels using as-synthesized versus $800^{\circ}C$-annealed nanophosphors were characterized and compared.

Effect of Guar Gum on Rheological Properties of Acorn Flour Dispersions

  • Yoo, Byoung-Seung;Shon, Kwang-Joon;Chang, Young-Sang
    • Food Science and Biotechnology
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    • v.14 no.2
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    • pp.233-237
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    • 2005
  • Rheological properties of acorn flour-guar gum mixtures (4% w/w) at different guar gum concentrations (0, 0.2, 0.4, 0.6, and 0.8% w/w) were evaluated in steady and dynamic shear. The acorn flour-guar gum mixtures at $25^{\circ}C$ showed high shear-thinning flow behavior (n= 0.20-0.27). Consistency index (K), apparent viscosity (${\eta}_{a,100}$), and Casson yield stress (${\sigma}_{oc}$) increased with the increase in guar gum concentration. Within the temperature range of $25-70^{\circ}C$, the {\eta}_{a,100}$ of mixtures obeyed the Arrhenius relationship with high determination coefficient ($R^2=\;0.974-0.994$). Activation energy values (5.37-6.77 kJ/mole) of acorn flour dispersions in the mixtures with guar gum (0.2-0.8%) were much lower than that (12.5 kJ/mole) of acorn flour dispersion (0% guar gum). Storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) increased with the increase in guar gum concentration. Dynamic rheological data of 1n (G', G") versus ln frequency (w) of guar gum-acorn flour mixtures had positive slopes with G' greater than G" over most of the frequency range, indicating that they exhibited weak gel-like behavior.

Inundation Map at Imwon Port with Past and Virtual Tsunamis (과거 및 가상 지진해일에 의한 임원항의 침수예상도)

  • Kim, Tae-Rim;Cho, He-Rin;Cho, Yong-Sik
    • Journal of the Earthquake Engineering Society of Korea
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    • v.21 no.1
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    • pp.1-9
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    • 2017
  • The scale of disaster and damage witnessed in the 2004 Indian Ocean Tsunami and the 2011 Great East Japan Tsunami has motivated researchers in developing foolproof disaster mitigation techniques for safety of coastal communities. This study focuses on developing tsunami hazard map by numerical modeling at Imwon Port to minimize losses of human beings and property damage when a real tsunami event occurs. A hazard map is developed based on inundation maps obtained by numerical modeling of 3 past and 11 virtual tsunami cases. The linear shallow-water equations with manipulation of frequency dispersion and the non-linear shallow-water equations are employed to obtain inundation maps. The inundation map gives the maximum extent of expected flooded area and corresponding inundation depths which helps in identifying vulnerable areas for unexpected tsunami attacks. The information can be used for planning and developing safety zones and evacuation structures to minimize damage in case of real tsunami events.