• 제목/요약/키워드: dispersion effect

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Dispersion and Flocculation Behavior of Metal Oxide in Organic Solvent

  • Fujii, Katsuya;Yamamoto, Hideki;Shibata, Junji
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.353-356
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    • 2001
  • The relation between the flocculation and dispersion of metal oxide powders and the properties of solvents, such as dielectric constant and solubility parameter, was investigated for TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$particles. The particle size and median diameter of these metal oxides were measured in many organic solvents, from which the effect of solvents on the flocculation and dispersion of metal oxide powders was considered. The metal oxide powders of TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$tend to disperse in a solvent of higher polarity, whereas they are apt to flocculate in a solvent of low dielectric constant, because the Hamaker constant between the particles becomes larger in such a solvent. There we, however, some solvents that do not obey these tendencies. It is possible to evaluate the flocculation and dispersion of these metal oxide powders in many solvents by using numeral balances of Hansen’s three-dimensional solubility parameter (f$_{d}$, f$_{p}$ and f$_{h}$). There exists a solvent giving the optimal dispersion for each metal oxide, and the optimal dispersion point of f$_{d}$, f$_{p}$ and f$_{h}$ is determined by the combination of various metal oxide powders and solvents.nts.nts.nts.

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SMF 길이와 RDPS가 랜덤하게 분포하는 장거리 전송 링크에서의 왜곡된 WDM 채널의 보상 (Compensation for the Distorted WDM Channels in the Long-Haul Transmission Link with the Randomly Distributed SMF Lengths and RDPS)

  • 이성렬
    • 한국항행학회논문지
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    • 제19권4호
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    • pp.323-329
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    • 2015
  • 장거리 ($50\;fiber\;spans{\times}80km$) 전송 링크의 융통적 구성을 위해 단일 모드 광섬유 (SMF; single mode fiber)의 길이와 중계 구간 당 잉여 분산 (RDPS; residual dispersion per span)이 랜덤하게 분포하는 링크에서 광 위상 공액과 결합된 분산 제어 (DM; dispersion management)를 통한 왜곡된 WDM 채널의 보상 특성을 살펴보았다. WDM 채널들의 입사 전력이 0 dBm 이하로 제한된다면 SMF 길이와 RDPS가 랜덤하게 분포하는 링크를 통한 보상 효과가 균일하게 분포하는 링크에서의 보상 효과와 유사하게 나타나는 것을 확인하였다. 이는 제안한 랜덤 분포 링크 구조를 이용하면 장거리 WDM 전송 링크 설계와 구축에서 융통성을 확보할 수 있다는 것을 의미한다.

한국기업의 연봉제가 기업내 임금격차에 미치는 영향에 대한 연구 (Performance Based Pay and Pay Dispersion within Firm: The Korean case)

  • 김재구;김동배
    • 노동경제논집
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    • 제34권2호
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    • pp.29-52
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    • 2011
  • 본고는 1990년대 후반 이후 한국기업에 급속히 도입되어 온 연봉제가 실제로 성과에 따른 임금격차를 가져왔는지에 대하여 분석하였다. 노동부 "임금구조기본통계조사" 1996년부터 2006년까지 100인 이상 기업 대졸 사무직에 대한 자료를 활용하였고, 기업내 임금격차 변수로는 개인 속성에 대한 영향을 배제할 수 있도록 임금함수를 추정하고 잔차의 분산을 기업수준의 변수로 활용하여 분석하였다. 분석 결과, 연봉제의 도입은 기업내 임금격차를 확대시키는 것으로 나타났다. 그러나 연봉제 적용 비중과 임금격차 간의 관계는 비선형관계($\bigcap$)임을 시사하는 결과가 나타났다.

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알루미나 나노 Particle의 분산 평가 및 최적화

  • 박국효;신효순;여동훈;홍연우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.251-251
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    • 2009
  • The generation of energy and the cooling of system using thermoelectric semiconductor material have been in spotlight. Thermoelectric effect increases with the decrease of the thermal conductivity. In the thermoelectric devices, thermal conductivity is related to phonon scattering. Therefore, few studies have been conducted in the thermoelectric materials dispersed nano oxide particle for increasing the phonon scattering. However, core-shell structure which nano particle disperses in solvents and then which thermoelectric materials coated on the nano oxide particles has not been reported. In this study, we selected commercial nano powder such as $Al_2O_3$. This nano particle was about 20nm and was crushed aggregate by mechanical treatment. We have developed the effect of the dispersant and the solvent. The properties of particles were evaluated by SEM, TEM, particle size analysis, and BET. Dispersion and dispersion stability were evaluated by electronic microscope and turbidity.

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화약 폭발에 의한 탄화수소계 연료의 분산매질 형성에 관한 연구 (A Study on Dispersed Media Formation of Hydrocarbon Fuel by an Explosive Burster)

  • 유재헌
    • 한국안전학회지
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    • 제31권2호
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    • pp.33-40
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    • 2016
  • Liquid fuel can be easily exploded and release more energy of detonation than conventional explosives because it has different explosion mechanism. In order to analyze dispersion characteristics of liquid fuel for the safety purpose, two tests are conducted. First, pre-test, which is a computer simulation, is carried out by a software called ANSYS AUTODYN to eliminate the effect of a canister that usually causes irregular dispersion of the fuel. Second, field test is performed to find out the amount and density effect of bursting charge. High speed cameras are installed in front of the canister to visualize the mechanism. Velocity, area and radius of the dispersed cloud are measured by image processing software, these are shown that the amount of bursting charge affects cloud velocity and area but density is not a significant factor of cloud formation.

에폭시수지 복합재료의 기계적.열적 성질에 대한 $TiO_2$ 나노입자의 영향 (Effect of $TiO_2$ Nanoparticle on the Mechanical and Thermal Properties of Epoxy Resin Composites)

  • 문용재;최정영;김부안;문창권
    • 동력기계공학회지
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    • 제14권4호
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    • pp.68-75
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    • 2010
  • The effect of dispersion agent, the content and size of nanoparticle on the mechanical and thermal properties has been investigated in $TiO_2$ nanoparticle/epoxy resin composites(nanocomposites). The weight fraction of fabricated nanocomposites were 0, 1, 3, 5%, respectively. The glass transition temperature was lower than pure epoxy resin and decreased with the increasing of nanopaticle content. This is considered that the cross link of epoxy resin during solidification was hindered by the presence of nanoparticles. Nanocomposites of 3wt% content with dispersion agent showed the best tensile strength. The tensile strength of 20㎚ $TiO_2$ nanocomposites were higher than one of 200nm $TiO_2$ nanocomposites.

적층 세라믹콘덴서 제조공정에서 $BaTiO_3$의 분산이 테이프캐스팅 성형체의 물성에 미치는 영향 (Effect of $BaTiO_3$ Dispersion on the Properties of Cast Tapes in Processing of Multilayer Ceramic Capacitor(MLCC))

  • 김봉호;김병관;김명호;백운규
    • 한국세라믹학회지
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    • 제33권2호
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    • pp.214-222
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    • 1996
  • The effect of physicochemical properties of organic solvent and dispersant among organic solvent dispersant binder and plasticizer which are used as processing additives in MLCC fabrication process on the dispersion of BaTiO3 was studied. The steric and electrostatic stabilization mechanisms in dispersion of BaTiO3 in organic media were evaluated respectively. The sttability of BaTiO3 achieved bysteric stabilization was dependent on the fraction of surface coverage of dispersant adsorption on BaTiO3. The electrostatic repulsive forces of BaTiO3 particles dispersed in orgainc media was found to be appreciabley great and dependent mainly on the kinds of organic solvent used. The mechanism affecting the stability of BaTiO3 was studied by the method of rheologi-cal behaviors of BaTiO3 suspension.

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Effect of NCO Index on the Particle Size of Polycarbonate Diol-based Polyurethane Dispersion

  • Kim, Dong-Eun;Kang, Seung-Oh;Lee, Sang-Ho
    • Elastomers and Composites
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    • 제55권1호
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    • pp.20-25
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    • 2020
  • The effect of the isocyanate index (NCO index) on the particle size and particle size distribution of a waterborne polyurethane dispersion (WPUD) with polycarbonate-diol was determined. The WPUDs were prepared using a conventional acetone process with polycarbonate-polyol (Mn = 2028), 4,4'-methylenebis(cyclohexyl isocyanate) (H12MDI), 2,2-bis(hydroxymethyl) propionic acid (DMPA), and dibutyltin dilaurate catalyst. At NCO index values below 1.5, the number average particle diameter of the WPUDs significantly increased with the NCO index, whereas the particle diameter slightly varied at higher NCO indexes. The dependency of the WPUD viscosity on the NCO index exhibited similar behavior to that of the particle size. The relative values of the full width at half maximum of the WPUD particle distribution curves at various NCO indexes were not influenced by the NCO index.

중거리에서 대류경계층 연직방향 plume 확산의 일반화 (Generalization of Vertical Plume Despersion in the concective Boundary Layer at Long Distances on Mesoscale)

  • 서석진
    • 한국대기환경학회지
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    • 제16권2호
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    • pp.141-150
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    • 2000
  • In order to genralize the vertical dispersion of plume at long distances on mesoscale over complex terrain dispersion coefficients data have been obtained systematically according to lapsed time after release by using a composite turbulence water tank that simulates convective boundary layer. Dispersion experiments have been carried out for various combined conditions of thermal turbulence intensity mechanical turbulence intensity and plume release height at slightly to moderately unstable conditions. Results of tracer dispersion experiments conducted using water tank camera and image processing system have been converted into atmospheric dispersion data through the application of similarity law. The equation $\sigma$z/Zi=aX/(b+c X2)0.5 where $\sigma$2; vertical dispersion coefficient zi : mixing height X : dimen-sionaless downwind distance was confirmed to be an appropriate and general equation for expressing $\sigma$2 variation with turbulence intensity and plume release height, The value of "a" was found to be principally affected by mechanical turbulence intensity and that of "b" by mechanical turbulence intensity and release height. It was confirmed that the magnitude of "c" varies with release height. Results of water tank experiments on the relationship of $\sigma$2 vs downwind distance x have been compared with actual atmospheric dispersion data such as CONDORS data and Bowne's nomogram Operating conditions of a composite turbulence water tank for simulating the field turbulence situations of CONDORS experiments and Bowne's $\sigma$2(x) nomogram for suburban area have also been investigated in terms of water temperature difference between convection water tank and bottom plate heating tank grid plate stroke mixing water depth length scale and velocity scale. Moreover the effect of mechanical turbulence intensity on vertical dispersion has been discussed in the light of release height and downwind distance. height and downwind distance.

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Capacitance 측정법을 이용한 나노 SiC 에폭시 복합재료의 내부 강화재 분산 예측방법 (Prediction Method of Dispersion Condition for Reinforced Epoxy in Nano SiC Particles Using Capacitance Measurement)

  • 권동준;왕작가;김제준;장기욱;박종만
    • Composites Research
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    • 제26권6호
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    • pp.337-342
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    • 2013
  • 나노입자를 이용하여 강화 효과를 높이기 위해서는 고분자 기지 내부의 균일한 분산 상태를 확보하여야 한다. 또한 균일분산 조건 확보 후 균일 분산상태를 증명할 평가자료가 필요하다. 본 연구는 에폭시 수지와 SiC 나노입자를 혼합한 SiC/에폭시 복합 수지를 제조할 경우 커패시턴스 측정법을 이용한 강화재 분산도 예측 연구를 진행하였다. 커패시턴스는 전기용량을 의미하며 측정 재료의 내부 전하량과 비례한다. 기존 에폭시 수지에 비해 나노 SiC 입자를 함유할 경우 전하량이 증가되는 이론을 바탕으로 구간별 커패시턴스 측정에 따른 분산도 평가를 진행하고, 커패시턴스 분산도 예측방법에 대한 타당성을 FE-SEM과 물리적 강도 증가 방법으로 평가하였다. 소니케이션 분산 방법과 교반기 분산 방법을 이용하여 분산 방법에 따른 SiC 나노입자 분산도 상태를 비교하였다. 인장강도와 커패시턴스 간의 상관관계가 있었으며, 파단면에 대한 비교를 할 때 분산성 향상에 대한 차이를 확인할 수 있었다.