• Journal of Korea Water Resources Association
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• v.47 no.10
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• pp.891-906
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• 2014

This study suggests the hedging rule of MIP (Mixed Integer Programing) in counting the risk evaluation criteria of the objective function and constraints in order to provide the optimum operating rule in reservoir system as constraining water shortage as much as possible which may happen in the downstream control point of water supply in the aspect of water system management. The proposed model is applied to the Han-river reservoir system for two testing periods (Case I: Jan. 1993~Dec. 1997, Case II: Jan. 1999~Dec. 2003). The model based on the hedging rule with trigger volume, estimated in this study shows that in Case I, the monthly minimum discharge was $310.6{\times}10^6m^3$ in the single operation, $56.3{\times}10^6m^3$ in the joint operation, and $317.5{\times}10^6m^3$ in the hedging rule and also, in Case II, the monthly minimum discharge was found to be $204.2{\times}10^6m^3$ in the single operation, $111.2{\times}10^6m^3$ in the joint operation, and $243.7{\times}10^6m^3$ in the hedging rule. In conclusion, the hedging rule, proposed in this study can decrease vulnerability while guarantees reliability and resiliency.

• Membrane Journal
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• v.26 no.1
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• pp.70-75
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• 2016

The reuse of wastewater is being diffused to manage and develop the water resources. Generally, the treated wastewater is discharged to the river after being treated to meet the effluent quality standard or reused for diverse uses through the reprocessing. And recently, as the reuse of the treated wastewater is activated, the technologies to utilize for the high quality water resources such as industrial water by reusing the wastewater with Membrane Distillation (MD) are under development. In this study, the direct contact membrane distillation (DCMD) process has been applied to treat sewage discharge water for water reuse. The laboratory scale experiment was performed by using a hydrophobic PVDF membrane with the pore size of $0.22{\mu}m$. The influence of operating parameters, such as feed temperature, feed flow rate, feed concentration, on the permeate flux and rejection has been investigated. All filtration tests were conducted till the feed volume reached a concentration factor of 3.0. Thus, the operating period ranged between 19 hr and 49 hr depending on filtration performance. The results showed that above 92% of TN, TP, COD and TOC in the feed could be rejected regardless of an operating condition. The water flux was ranged from 13.8 to 20.3 LMH. The lowest flux was obtained at the operating condition with the feed temperature of $50^{\circ}C$ and feed flow velocity of 500 mL/min while the highest one was measured with $60^{\circ}C$ and 900 mL/min. When the concentration factor reached 3.0, water flux declined by approximately ranged from 14.5% to 33.3%. But the fouling in MD is almost fully reversible, with more than 90% recovery of permeate water flux following a DI water rinse without the addition of chemical cleaning reagents.

• Korean Journal of Agricultural Science
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• v.17 no.2
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• pp.102-114
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• 1990

This study was carried out to analyze the operation of the sluice gates by taking Sabkyo Reservoir as the model, and to examine the formulae of the design criteria for the Agricultural Land Improvement Project by hydraulic model experiments. The results were summarized as follows ; 1. According to the records of gate operation for 9 years, the mean height of the opened gates was 4.13 m, the mean number of operated gates were 4.04, the average annual number of operation were 67 times, the average annual operating time were 192.5 hours, and the average operating time were 2.88 hours. 2. The water supplied through Sabkyo Reservoir was 88.15 megatons per year, which was about 1.4 times the effective storage capacity. And the annual volume of pumping in May, which is the most water demanding season, was 29.56 megatons in average. 3. As the submerged orifice was transformed into the surface orifice, the suggested formulae for the orifice flow on the design criteria for the Agricultural Land Improvement Project showed a discontinuous line on the transition zone. It should be improved, because it is different from the real hydraulic phenomena. 4. The formulae for the orifice flow which are divided into the submerged and surface orifices are being used. However, these formulae could be substituted for the formular, $q=C{\cdot}W\sqrt{2gH_1}$, if the discharge coefficient considering the reservoir water level, the sea water level, and the gate opening height is used.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.1
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• pp.1-9
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• 1999

Hydrographic survey was carried out in the mid-eastern Yellow Sea from Keum River to Taean Peninsula in order to study the motion of the freshwater from the Keum River during July 07-12, 1997 when a large volume of freshwater was discharged from the Keum River weir. The low-salinity (less than 30.0 psu) plume was distributed over the large area between the Keum River and Ochong Island, 60 km northwest off the Keum River mouth. A band of relatively low saline water, originating from the Keum River, was also observed to the north of Ochong Island. The strong haline front had advanced from near Sibidongpa Island to Ochong Island, 25 km northwest of Sibidongpa Island, for 48 hours. A northwestward flow of a speed greater than 0.2 m/s was observed in the surface plume layer to the north of Sibidongpa Island where the water column was strongly stratified. The observed mean flow and the change of the frontal position are interpreted as resulting from the spreading of the Keum River plume. These results suggest that the discharge from the Keum River plays an important role in the coastal circulation of the mid-eastern Yellow Sea adjacent to the river.

• Clean Technology
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• v.18 no.2
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• pp.177-182
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• 2012

Mesoporous anatase $TiO_2$ nanoparticles have been synthesized by a hydrothermal method using a tri-block copolymer as a soft template. The resulting $TiO_2$ materials have a high specific surface area of $230\;m^2/g$, a predominant pore size of 6.8 nm and a pore volume of 0.404 mL/g. The electrochemical properties of mesoporous anatase $TiO_2$ for lithium ion battery (LIB) anode materials have been investigated by typical coin cell tests. The initial discharge capacity of these materials is 240 mAh/g, significantly higher than the theoretical capacity (175 mAh/g) of LTO ($Li_4Ti_5O_{12}$). Although the discharge capacity decreases with the C-rate increase, the mesoporous $TiO_2$ is very promising for LIB anode because the surface for the Li insertion is presented significantly with mesopores. Nitrogen doping has a certain effect to control the capacity decrease by improving the electron transport in $TiO_2$ framework.

• Journal of the Korean Electrochemical Society
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• v.3 no.4
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• pp.224-231
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• 2000

The exfoliation of graphite (layer) was progressed due to the irreversible insertion of PC molecules between graphene layers, when propylene carbonate (PC) solvent was used as the organic solvents. The problem could be mitigated by the replacement of PC by ethylene carbonate (EC). But, the freezing point of EC-based electrolyte increased due to the high freezing point of $EC(36.2^{\circ}C)$. Therefore, EC+PC mixed electrolyte is expected as a good organic electrolyte for lithium ion battery. The EC-based organic electrolyte containing PC within pertinent quantity can be expected to have high molar conductivity and reduced exfoliation of graphite layer. The dielectric constant and molar conductivity of $LiPF_6/PC+EC+DEC$ electrolyte was investigated with a variation in the PC content. The electrochemical properties of carbon electrode in the electrolyte were also investigated. Molar conductivity and dielectric constant increased linearly by increasing the PC volume fraction in the electrolyte. The results of charge-discharge test for carbon/electrolyte/Li cell indicated that the initial irreversible specific capacity(IIC) of MCMB-6-28s and MPCF3000 decreased by the addition of $0.83 vol\%$ of PC, but increased with PC content over than $0.83 vol\%$. In the case of MPCF3000 and PCG100 having less than $10 vol\%$ PC, IIC was lower than 50 mAh/g. The discharge specific capacities varied with carbon material, but did not vary with PC content in the electrolyte.

• Journal of Korean Society on Water Environment
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• v.29 no.6
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• pp.847-851
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• 2013

This study describes the results of an investigation conducted in order to characterize the quantity and quality of individual gray water streams. The highest pollutants concentrations were found in gray water originating from kitchen and laundry with $BOD_5$ concentrations in the order of several hundreds $mgl^{-1}$. In contrast to this, bathroom was regarded as a major contributor of Escherichia coli. Laundry gray water has higher pH, sodium, sulfate, anionic surfactants. Individual gray water types had different contribution to the overall daily discharge and relative pollutants loads. Kitchen, although accounting for only 13% of the total volume, was identified as a major source of microorganisms with Total coliforms, Escherichia coli, Fecal streptococcus taking up 82%, 74% and 54% of their relative daily load, respectively. The laundry gray water, although being responsible for 36% of the total daily discharge, was established as a significant contributor of sodium, sulfate, anionic surfactants and TOC (70%, 72%, 84% and 52%, respectively). But the laundry gray water was a minor source of microorganisms. Bathroom was found to be a major gray water producer, making up 51% of the flow, but constituted less than 50% of the relative daily load in most cases.

• Korean Chemical Engineering Research
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• v.59 no.1
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• pp.42-48
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• 2021

Zn and Al added LiNi0.85Co0.15O2 cathode materials were synthesized to improve electrochemical properties and thermal stability using a solid-state route. Crystal structure, particle size and surface shape of the synthesized cathode materials was measured using XRD (X-ray diffraction) and SEM (scanning electron microscopy). CV (cyclic voltammetry), first charge-discharge profiles, rate capability, and cycle life were measured using battery cycler (Maccor, series 4000). Strong binding energy of Al-O bond enhanced structure stability of cathode material. Electrochemical properties were improved by preventing cation mixing between Li+ and Ni2+. Large ion radius of Zn+ increased lattice parameter of NC cathode material, which meant unit-cell volume was expanded. NCZA25 showed 80% of capacity retention at 0.5 C-rate during 100 cycles, which was 12% higher than that of NC cathode. The discharge capacity of NCZA25 showed 104 mAh/g at 5 C-rate. NCZA25 achieved 36 mAh/g more capacity than that of NC cathod. NCZA25 cathode material showed excellent rate capability and cycling performance.

• Journal of Environmental Impact Assessment
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• v.32 no.6
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• pp.473-487
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• 2023

Korea's multi-purpose dams, which were constructed in the 1970s and 1980s, have a single outlet located near the bottom for hydropower generation. Problems such as freezing damage to crops due to cold water discharge and an increase the foggy days have been raised downstream of some dams. In this study, we analyzed the effect of water intake depth on the reservoir's water temperature stratification structure and outflow temperature targeting Hapcheon Reservoir, where hypolimnetic withdrawal is drawn via a fixed depth outlet. Using AEM3D, a three-dimensional hydrodynamic water quality model, the vertical water temperature distribution of Hapcheon Reservoir was reproduced and the seasonal water temperature stratification structure was analyzed. Simulation periods were wet and dry year to compare and analyze changes in water temperature stratification according to hydrological conditions. In addition, by applying the intake depth change scenario, the effect of water intake depth on the thermal structure was analyzed. As a result of the simulation, it was analyzed that if the hypolimnetic withdrawal is changed to epilimnetic withdrawal, the formation location of the thermocline will decrease by 6.5 m in the wet year and 6.8 m in the dry year, resulting in a shallower water depth. Additionally, the water stability indices, Schmidt Stability Index (SSI) and Buoyancy frequency (N²), were found to increase, resulting in an increase in thermal stratification strength. Changing higher withdrawal elevations, the annual average discharge water temperature increases by 3.5℃ in the wet year and by 5.0℃ in the dry year, which reduces the influence of the downstream river. However, the volume of the low-water temperature layer and the strength of the water temperature stratification within the lake increase, so the water intake depth is a major factor in dam operation for future water quality management.

• Clean Technology
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• v.30 no.3
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• pp.220-227
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• 2024

As the demand for lithium-ion batteries with high capacity and high energy density has rapidly increased, silicon anodes (theoretical capacity = 3,570 mA h g^-1) have garnered attention as potential replacements for conventional graphite anodes (theoretical capacity = 372 mA h g^-1). However, silicon anodes suffer from severe volume expansion (~360%) during lithiation, low ionic conductivity (10^-14 ~ 10^-13 cm² S^-1), and low electrical conductivity (10^-2 S cm^-1), resulting in poor cycling and rate performance. To address these issues, this study synthesized core@shell-structured silicon@carbon nanoparticles (Si@C NPs) via a one-pot spray pyrolysis process using Pluronic-F127. Pluronic-F127 in the spray solution contributes to the synthesis of nanoparticles by preventing the formation of silicon nanoparticle/dextrin agglomerates and by undergoing pyrolysis simultaneously. Additionally, dextrin derived amorphous carbon was coated on the surface of the silicon nanoparticles to act as an electron transport pathway within the anodes and enhance the electrical contact between the silicon nanoparticles. The Si@C NPs exhibited a discharge capacity of 1,912 mA h g^-1 after 50 cycles at 1.0 A g^-1 and high rate capabilities (discharge capacity of 1,493 mA h g^-1 at 3.0 Ag^-1). The silicon@carbon composite nanoparticle synthesis strategy based on the spray pyrolysis process presented in this study is expected to offer a new direction for improving the performance of silicon anode materials.