• 제목/요약/키워드: direct determination

검색결과 511건 처리시간 0.023초

Determination of Pd(II) and Pt(II) Metal Cyano Complexes Using Capillary Electrophoresis

  • Lee, Hue-Jin;Lee, Sang-Ho;Chung, Koo-Soon;Lee, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제15권11호
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    • pp.945-949
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    • 1994
  • Mixtures of cyano complexes of palladium(II) and platinum(II) were separated by capillary electrophoresis using a fused silica capillary as a separation column and 30 mM phosphate buffer (pH 7) containing 15 wt. % acetonitrile as a running buffer. By virtue of the high ionic mobilities of the negatively charged cyano complexes of Pd(II) and Pt(II), they were separated using a cathodic injection and anodic detection scheme. The metal complexes eluted through the capillary were detected by direct UV absorption at 214 nm. A linear relationship between peak area and concentration was obtained for both ions and the detection limit was lower than $10^{-14}$ mole. The proposed method was applied to real sample, e.g., anode slime obtained from an electrolytic copper refinary, as a method for the simultaneous determination of palladium and platinum.

아스팔트 콘크리트 포장의 반사균열 저항성 평가를 위한 반복직접인장시험의 파괴기준 설정 (Establishment of Failure Criteria of Repeated Direct Tensile Test to Evaluate Reflective Cracking Resistance of Asphalt Concrete Pavement)

  • 이봉림;김낙석
    • 대한토목학회논문집
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    • 제36권6호
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    • pp.1109-1116
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    • 2016
  • 아스팔트 콘크리트 포장의 반사균열 저항성을 평가하기 위해 다양한 방법이 적용되고 있다. 반복직접인장시험은 기존실험에 비해 저렴하고 간편하게 아스팔트 콘크리트 포장의 반사균열 저항성을 평가할 수 있는 장점이 있다. 국내에 반복직접인장시험을 도입하기 위해서는 파괴기준의 결정이 필요하다. 반복직접인장시험의 파괴횟수를 결정하기 위해 다양한 방법을 검토한 결과 초기하중의 10%일 때를 파괴시점으로 산정할 경우 10% 이내의 반복횟수 편차를 나타내었다. 아스팔트 콘크리트의 두께가 30 mm에서 50 mm로 증가할 경우 파괴횟수는 13.6배 증가하여 포장두께가 반사균열 저항성에 큰 영향을 미치는 것을 알 수 있었다. 또한 재하변형의 크기가 클수록 반사균열의 진전속도가 증가하는 것으로 나타났다. 반복직접인장시험은 포장 두께, 변형크기, 재료적 특성에 따라 반사균열저항성을 정량적으로 평가할 수 있기 때문에 포장설계시 반사균열 저항성 평가 방법으로 적용 가능한 것으로 나타났다.

세종 테스트베드에서 항측용 디지털카메라의 기하학적 검정 (Geometric calibration of digital photogrammetric camera in Sejong Test-bed)

  • 서상일;원재호;이재원;박병욱
    • 한국측량학회지
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    • 제30권2호
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    • pp.181-188
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    • 2012
  • 최근 항공측량분야에서 항측용 디지털카메라와 라이다 및 GPS/INS와 같은 센서들을 이용해 다양한 공간정보를 획득하고 있다. 또한 GPS/INS와 항측용 디지털카메라의 연계를 통한 Direct Georeferencing 기술이 널리 활용되고 있다. 하지만 여러 센서의 결합에 따른 센서검정(Sensor Calibration)을 실시해야 하는 문제점이 따른다. 특히, 통합센서의 Boresight Calibration은 GPS/INS 항공삼각측량 및 Direct-georeferencing을 사용하는 작업절차에서 중요한 요소이다. 이를 해결하기 위해 본 연구에서는 항공기용 센서의 검정을 위한 국가차원의 테스트베드를 세종시 부지에 설치하고 항공영상의 항공삼각측량에 의해 함께 사용되는 GPS와 INS 센서결합에 따른 정확한 검정을 수행하여 시스템 변수의 정의, 시스템적인 에러를 평가하고 Direct Georeferencing에 필요한 외부표정요소 직접결정을 위한 효율적인 방법의 조사와 통합된 센서의 정확도 평가를 수행하였다.

대청호 상류 유역의 비점오염원 유출특성 분석 및 L-THIA 모형 적용성 평가 (Analysis of the Characteristics of NPS Runoff and Application of L-THIA model at Upper Daecheong Reservoir)

  • 신민환;이재안;천세억;이열재;임경재;최중대
    • 한국농공학회논문집
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    • 제52권1호
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    • pp.1-11
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    • 2010
  • Generation and transportation of runoff and pollutant loads within watershed generated eutrophication at Daecheong reservoir. To improve water quality at Daecheong reservoir, the best management practices should be developed and applied at upper watersheds for water quality improvement at downstream areas. In this study, two small watersheds of upper Daecheong reservoir were selected. The Long-Term Hydrologic Impact Assessment (L-THIA) model has been widely used for the estimation of the direct runoff worldwide. To apply the L-THIA ArcView GIS model was evaluated for direct runoff and water quality estimation at small watershed. And the Web-based Hydrograph Analysis Tool (WHAT) was used for direct runoff separating from total flow. As a result, the $R^2$ (Coefficient of determination) value and Nash-Sutcliffe coefficient value for direct runoff comparison at An-nae watershed were 0.81 and 0.71, respectively. And the $R^2$ value and Nash-Sutcliffe coefficient value at Wol-oe were 0.95 and 0.93. The $R^2$ value of BOD, TOC, T-N and T-P at An-nae watershed were BOD 0.94, TOC 0.81, T-N 0.94 and T-P 0.89. And the $R^2$ value of BOD, TOC, T-N and T-P at Wol-oe watershed were BOD 0.80, TOC 0.93, T-N 0.86 and T-P 0.65. The result that estimated pollutant loadings using the L-THIA ArcView GIS model reflected well the measured pollutant loadings except for T-P in Wol-oe watershed. With L-THIA ArcView GIS model, the direct runoff and non-point pollutant (NPS) loadings in the watershed could be analyzed through simple input data such as daily rainfall, land uses, and hydrologic soil group.

GPS 및 토탈스테이션을 이용한 대학시설물 현황측량의 성과분석 (Evaluation of GPS and Totalstation Surveying for University Facilities Mapping)

  • 박병욱;이대근;서상일
    • 한국측량학회:학술대회논문집
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    • 한국측량학회 2003년도 추계학술발표회 논문집
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    • pp.43-48
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    • 2003
  • This study presents the detailed methods for university facilities mapping using GPS and totalstation. In the control survey by GPS network adjustment, the level of significance for the height value of fourth order triangulation stations was estimated about loom. The accuracy analysis of height determination by totalstation for the traverse points showed that the RMSE came out 9mm to the basis of direct leveling, so it indicated that trigonometric leveling by totalstation was correct comparatively. For GPS/RTK method, the result of accuracy analysis about traverse points showed that the RMSE came out 33㎜ in horizontal location to the basis of totalstation's outcome and 15㎜ in height value to the basis of direct leveling. In the construction survey, GPS/RTK surveying is quicker and more economical than totalstation surveying in the feasible areas of GPS surveying, but there were many impossible areas lot GPS/RTK surveying by the obstacles like a building.

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Determination of Initial Conditions for Tetrahedral Satellite Formation

  • Yoo, Sung-Moon;Park, Sang-Young
    • Journal of Astronomy and Space Sciences
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    • 제28권4호
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    • pp.285-290
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    • 2011
  • This paper presents an algorithm that can provide initial conditions for formation flying at the beginning of a region of interest to maximize scientific mission goals in the case of a tetrahedral satellite formation. The performance measure is to maximize the quality factor that affects scientific measurement performance. Several path constraints and periodicity conditions at the beginning of the region of interest are identified. The optimization problem is solved numerically using a direct transcription method. Our numerical results indicate that there exist an optimal configuration and states of a tetrahedral satellite formation. Furthermore, the initial states and algorithm presented here may be used for reconfiguration maneuvers and fuel balancing problems.

ASC를 이용한 품질특성의 중요도 결정 (Determining the Importance Values of Quality Attributes Using ASC)

  • 장흥엽;송해근;박영택
    • 품질경영학회지
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    • 제40권4호
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    • pp.589-598
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    • 2012
  • Purpose: Determination of the importance values of quality attributes is very important to integrate the Kano model with QFD. A new method to determine the importance values of quality attributes is proposed. Methods: ASC(Average Satisfaction Coefficient) is proposed in order to determine the importance values of quality attributes. To evaluate the effectiveness of ASC, a case study of modern TV sets is conducted, and the performance of ASC is compared with direct importance evaluation and AHP pairwise comparisons. Results: The result of ASC application is similar with those of direct importance evaluation and AHP pairwise comparison. Conclusion: ASC is an effective instrument to determine the importance values of quality attributes. It doesn't need a cumbersome process like AHP pairwise comparison, and can be calculated using the data for the conventional Kano model.

Using grain size to predict engineering properties of natural sands in Pakistan

  • Aziz, Mubashir
    • Geomechanics and Engineering
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    • 제22권2호
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    • pp.165-171
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    • 2020
  • Laboratory determination of strength and deformation behavior of clean sands and gravels has always been challenging due to the difficulty in obtaining their undisturbed samples. An alternative solution to this problem is to develop correlations between mechanical properties of cohesionless soils and their gradation characteristics. This study presents database of 3 natural sands with 11 varying particle size gradation curves to allow investigating relationships between mean particle size, maximum and minimum void ratio, relative density and shear strength of the test soils. Direct shear tests were performed at relative densities of 50, 75 and 95% to explore the effects of gradation and density on the angle of internal friction of the modeled sand samples. It is found that the mean grain size D50 bears good correlations with void ratio range (emax - emin) and peak angle of internal friction 𝜙'peak. The generated regression models are in good agreement with published literature and can be considered as reliable for natural sands in Pakistan. These empirical correlations can save considerable time and efforts involved in laboratory and field testing.

직접미분 설계민감도 해석을 이용한 박판금속성형 공정변수 최적화 (II) -공정 변수 최적화- (Optimum Design of the Process Parameter in Sheet Metal Forming with Design Sensitivity Analysis using the Direct Differentiation Approach (II) -Optimum Process Design-)

  • 김세호;허훈
    • 대한기계학회논문집A
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    • 제26권11호
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    • pp.2262-2269
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    • 2002
  • Process optimization is carried out to determine process parameters which satisfy the given design requirement and constraint conditions in sheet metal forming processes. Sensitivity -based-approach is utilized for the optimum searching of process parameters in sheet metal forming precesses. The scheme incorporates an elasto-plastic finite element method with shell elements . Sensitivities of state variables are calculated from the direct differentiation of the governing equation for the finite element analysis. The algorithm developed is applied to design of the variablc blank holding force in deep drawing processes. Results show that determination of process parameters is well performed to control the major strain for preventing fracture by tearing or to decrease the amount of springback for improving the shape accuracy. Results demonstrate that design of process parameters with the present approach is applicable to real sheet metal forming processes.

고정자 전압의 제3고조파 성분을 이용한 유도전동기의 벡터제어 시스템 (Vector Control System of Induction Motor Using the Third Harmonic Component of the Stator Voltage)

  • 노애숙;정종진;김흥근
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 A
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    • pp.479-481
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    • 1994
  • A direct vector control system of induction machine based determination of the spatial position of the airgap flux from the third harmonic component of the stator voltage is presented in this paper. The Rotor flux, necessary in direct vector control system, is estimated with the stator current and the airgap flux acquired from the third harmonic component of the stator voltage. And it will be used as an important information to implement the vector control system of the induction motor drive.

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