• Title/Summary/Keyword: direct determination

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Direct Determination of Total Arsenic and Arsenic Species by Ion Chromatography Coupled with Inductively Coupled Plasma Mass Spectrometry

  • Nam, Sang-Ho;Kim, Jae-Jin;Han, Soung-Sim
    • Bulletin of the Korean Chemical Society
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    • v.24 no.12
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    • pp.1805-1808
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    • 2003
  • The simultaneous determination of As(III), As(V), and DMA has been performed by ion chromatography (IC) coupled with inductively coupled plasma-mass spectrometry (ICP-MS). The separation of the three arsenic species was achieved by an anionic separator column (AS 7) with an isocratic elution system. The separated species were directly detected by ICP-MS as an element-selective detection method. The IC-ICP-MS technique was applied for the determination of arsenic species in a NIST SRM 1643d water sample. An As(III) only was detected in the sample. The detection limits of As(III), As(V) and DMA were 0.31, 0.45, and 2.09 ng/mL, respectively. It was also applied for the determination of arsenic species in a human urine obtained by a volunteer, and three arsenic species were identified. The determination of total As in human urines that were obtained from 25 volunteers at the different age was also carried out by ICP-MS.

Determination of Incentive Level of Direct Load Control Program Based on California lest (캘리포니아 테스트에 기초한 직접부하제어 프로그램의 적정 인센티브 산정)

  • 박종배;김민수;신중린;전영환
    • Journal of Energy Engineering
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    • v.11 no.4
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    • pp.342-349
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    • 2002
  • This paper presents the determination of incentive level of Direct Load Control (DLC) program based on California Test. In the most of the Demand-Side Management (DSM) program, the variables art given by constant value during the DSM program's life time. But, in the case of DLC, variables are depen-dent on the executing number and time of the DLC per year. Therefore, we formulate a newly designed Cal-ifornia Test technique to overcome these problems and to apply effectively to the determination of incentive level of the DLC program. We perform case studies for various scenarios using a proposed formulation and review incentive level of the current DLC program. And we propose a plan to activate the DLC program in the competitive electricity market.

Effects of Mothers' Play Belief on Self-determination of Young Children: The Mediating Role of Children's Play Time (어머니의 놀이신념이 유아의 자기결정력에 미치는 영향: 놀이시간의 매개역할)

  • Lee, Hyoim;Shin, Nary
    • Korean Journal of Childcare and Education
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    • v.16 no.3
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    • pp.59-77
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    • 2020
  • Objective: The purpose of this study was to investigate the effect of mothers'play belief and their children's playtime on self-determination of young children. Methods: Participants of this study were 239 mothers of 6-year-old children attending childcare centers. An online self-report survey method was implemented to investigate whether mothers appreciate the contribution of play on their children's development, if mothers allow their children's playtime, and to examine the level of self-determination of their children. SPSS 22.0 was conducted for descriptive statistics and AMOS 21.0 was used for the path analysis to investigate the hypothetical relationship among variables. Results: Mothers' play support belief had a direct influence on their children's self-determination, while young children's playtime that was also affected by their mothers' play support belief had an indirect effect on their self-determination. Conclusion/Implications: The research shows that children's self-determination can be fostered by providing time to play when they can make decisions and demonstrate goal directed behaviors, and by providing an atmosphere that emphasizes the importance of playing in one's childhood.

Effects of Behavioral Inhibition in Young Children on Self-Determination: Sequential Mediating Effects of Mother's Parenting Anxiety and Autonomy Support (유아의 행동억제가 자기결정성에 미치는 영향: 어머니의 양육불안과 자율성 지지의 순차매개효과)

  • Ji-Hyo Kim;Nary Shin
    • Korean Journal of Childcare and Education
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    • v.19 no.6
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    • pp.97-113
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    • 2023
  • Objective: The purpose of this study is to investigate the effect of young children's behavioral inhibition on self-determination, examining the sequential mediating effects of mothers' parenting anxiety and autonomy support. Methods: Participants in this study were 225 mothers with children aged 6 years. An online survey was conducted, and SPSS Statistics 23.0 was used for basic analysis. The research model used the Process Macro 4.0 program. Results: The higher the level of behavioral inhibition, the lower the child's self-determination. Furthermore, a mediating effect was confirmed when parenting anxiety was added. However, in the single mediation model and the sequential mediation model in which autonomy support was added, the direct effects of behavioral inhibition temperament and parenting anxiety on self-determination disappeared. As a result, behavioral inhibition characteristics were found to have an indirect effect on self-determination through the sequential mediating effects of mother's parenting anxiety and autonomy support. Conclusion/Implications: If a mother with a child with a behaviorally inhibited temperament properly handles the negative emotions experienced during parenting based on her understanding of the child and supports the child to have a high degree of autonomy, she can enhance the child's right to self-determination.

Determination of Mefenamic acid with ISEs Using Ternary Complex of Metal -phenanthroline -mefenamate as Ion-exchanger (이온교환체로서 금속 -페난드롤린 -메페남산 3원 작물을 이용한 메페남산의 정량)

  • 허문회;김대병;남수자;문현숙;이미나;정문모;안문규
    • YAKHAK HOEJI
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    • v.45 no.1
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    • pp.29-33
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    • 2001
  • A method for the determination of anionic drug, mefenamate with ion-selective electrode using Fe(II)-1,10-phenanthroline chelate as a counter ion was developed. Benzyl nitrophenyl ether (BNPE) plasticized membrane was more selective and sensitive than the other tested membranes. This membrane electrode exhibits a linear response for 10$^{-2}$ M~5 $\times$ 10$^{-5}$ M of mefenamic acid with a slope of -61.4 mV/dec. in borate buffer solutions (pH 9.0). Potentiometric selectivity measurements revealed negligible interferences from various organic and ionorganic anions. Direct potentiometry and potentiometric titration method of mefenamic acid in capsule preparations are presented and compared.

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Direct Determination of Expansion History Using Redshift Distortions

  • Song, Yong-Seon
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.1
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    • pp.29.1-29.1
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    • 2013
  • We investigate the direct determination of expansion history using redshift distortions without plugging into detailed cosmological parameters. The observed spectra in redshift space include a mixture of information: fluctuations of density-density and velocity-velocity spectra, and distance measures of perpendicular and parallel components to the line of sight. Unfortunately it is hard to measure all the components simultaneously without any specific prior assumption. The degeneracy breaking, between the effect of cosmic distances and redshift distortions for example, depends on the prior we assume. An alternative approach is to utilize the cosmological principle inscribed in the heart of the Friedmann-Lematre-Robertson-Walker (hereafter FLRW) universe, that is, the specific relation between the angular diameter distance and the Hubble parameter, in this degeneracy breaking.

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Influence of e-HRM and Human Resources Service Quality on Employee Performance

  • NURLINA, N.;SITUMORANG, Jubair;AKOB, Muhammad;QUILIM, Cici Aryansi;ARFAH, Aryati
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.10
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    • pp.391-399
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    • 2020
  • This study aims to analyze the relationship of e-HRM implementation to employee performance both directly and indirectly through the intervening of the Human Resource service Quality variable, both practically and theoretically. This study uses variance-based structural equation modeling (SEM) techniques with partial least square (PLS) statistical testing tools to test the direct relationship of e-HRM and the performance and relationship moderated by Human Resources service quality tested on 200 civil servants in five offices under the coordination of the Government of the South Sulawesi Province of Indonesia. The data collection model in this study uses an online survey. The data analysis stages through the explanatory concept consist of, first, the interpretation of the distribution of the average frequency of respondents' answers; second, outer-loading; third, determination of the validity and reliability; fourth, the coefficient of determination test and partial test; fifth, the GoF model; sixth, validity test; and seventh, hypothesis testing. This study explores four hypotheses in a comprehensive fashion; the results of this study show that all hypotheses have positive and significant effects both through direct and intervening relationships. Among the three direct relationships, the relationship of e-HRM variables on HR Service Quality is greatest and most dominant.

Determination of Boron in Steels by Precipitation Method and ICP-AES (침전법과 ICP-AES법에 의한 철강 시료 중 Boron의 분석)

  • Lim, Heon-Sung;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.15 no.2
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    • pp.180-183
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    • 2002
  • The new useful method for the direct determination of trace boron in iron matrix was studied by applying the precipitation of $Fe(OH)_3$ and ICP-AES. Optimum pH range was 11 ~ 12.5. Linear concentration range of boron was $0.01{\sim}1.0{\mu}g/m{\ell}$ in $5000 {\mu}g/m{\ell}$ solution as iron.

Determination of the process variables for quality monitoring in direct rolling processes (직접압연 공정에서 품질계측을 위한 공정변수의 선정)

  • 배세철;박영준;조형석
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10b
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    • pp.1364-1367
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    • 1996
  • Recently, direct rolling process, called as strip casting process, has been interested in to save production cost by reducing forming processes. In direct rolling process, since a steel strip of thickness 1-5(mm) can be produced directly from molten metal, it can eliminate secondary hot rolling process. On the other hand, since many process variables are existed in this process and relation of these variables is very complex, it is difficult to realize the process design and the quality control. In this paper, as first step to overcome above difficulties, the quantitative relationship of the process variables affected to quality of the strip has been carried out through the numerical analysis. Also, we determined the process variable to monitor the quality in the direct rolling process. As a result, we show that the solidification final point, called as Nip point, was related directly to quality of the strip.

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