• Title/Summary/Keyword: dip treatment

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Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

Manufacture of High Quality Premium Tissue from White Ledger by Bleaching, Blending with Virgin Pulp and the Addition of Softeners (백상고지로부터 표백, 버진펄프와 혼합 및 유연제 처리에 의한 고급화장지 제조)

  • 고경무;남원석;백기현
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.4
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    • pp.30-36
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    • 2002
  • This research was conducted to investigate the feasibility of using deinked pulp of white ledger(DIP) for the manufacture of high quality premium tissue. The three types of tissues were prepared using the softener treated bleached DIP, softener treated mixed pulp of unbleached DIP and virgin pulp, and untreated mixed pulp of bleached DIP and virgin pulp, respectively, and their tensile index. softness, and brightness were measured and compared. The bulk and surface softness increased only slightly by the addition of softener(0.2% mineral oil) into the bleached DIP. The tensile index was decreased by 15∼30%, and the brightness was the range of 86% to 87% ISO. The softener(0.2∼0.8% mineral oil or dialkyl imidazoline) treatment of mixed pulp of unbleached DIP and virgin pulp Improved the bulk and surface of tissue considerably. However, the brightness was low as 85% ISO or below. Although the softness of the tissue made from bleached DIP blended with virgin pulp was the lowest among three types of tissues evaluated, its tensile index was the highest and brightness was 87∼88% ISO. Based on the results, it may be predicted that the bleached DIP blended with virgin pulp is the best raw material for the manufacture of high quality premium tissue if softener treatment is applied to mixed pulp, because the softness can be improved by the addition of softener. In general, the softness of tissue was improved with the increase in the amount of softener: However, the tensile index inversely proportional to the amount of softener added. Dialkyl imidazoline was more effective than mineral oil with respect to the improvement in softness, even though the loss in tensile index was severe with the treatment of dialkyl imidazoline.

A Simulation on Water quality improvement by the effluent treatment of landbase-seawater culture system in the Kamak bay (육상축양장 배출수 처리에 의한 가막만의 수질개선 시뮬레이션)

  • Kim Dong-Myung;Jang Ju-Hyoung;Cho Hyeon-Seo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.6 no.1
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    • pp.44-59
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    • 2003
  • The three-dimensional eco-hydrodynamic model was applied to estimate the effect of water quality improvement by the effluent treatment of landbase-seawater culture system in the Kamak bay The computed residual currents were dominated southward flow at the northern narrow strait and eastward flow and clockwise water circulation at the mouth of the bay, strongly. The mean relative errors of DIP, DIN and COD between the simulated and observed results at 9 stations in the Kamak bay were shown 14.3%, 25.8% and 14.4%, respectively. There were high concentrations of DIP, DIN and COD at the northwestern bay which is influenced by pollution loads. The simulations were performed using an ecosystem model under the conditions of DIP 90%, DIN 80% and COD 60% treatment efficiency by the ozone treatment system of landbase-seawater culture system. As a results of simulation, the improvement effects of DIP, DIN and COD are 34.4~54.0% (average 46.4%), 0.4~25.4%(average 8.4%) and 15.6~29.4%(average 22.7%), respectively. Therefore the area of seawater quality grade I based on COD was extended in the bay.

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The Effect of Coloring Condition on the Surface Characteristic of 304 Stainless Steel (304 스테인리스강의 착색 처리 조건이 표면 특성에 미치는 영향)

  • Kim, Ki-Ho
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.220-225
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    • 2011
  • 304 stainless steel plate was colored by hot dip and electrochemical treatment in a solution containing sulphuric and chromic acids. In the process, treatment variables such as operating time and methode were changed. The surface characteristics that changed by the treatment of the samples such as surface composition, oxide film thickness, color, surface roughness and reflectivity were studied. Surface composition was varied as follows. Fe was decreased, but Cr and O were increased. Ni was increased until 20 min, but reveals decreasing tendency as time passed after that. These means the surface film becomes chrome rich oxide phase as the treatment times increase. The thickness of film was about 220 nm at 30 min by dip treatment and it reduced as the treatment times increased. On the other hand, the thickness was about 150 nm at 10 min by electrochemical method and it doesn't increased with time. Surface color changed from metallic white of the base plate to gray, black, red, and green-blue, gradually, as the treating time increased. The reflectivity of colored surface measured by UVVIS-NIR spectrophotometer was reduced from max 38% of basis metal to min 3.5%.

The Estimation of the contribution rate of Mokpo Municipal Sewage Treatment Plant to the Improvement of Marine Water Quality in Mokpo Harbour (목포항 수질개선에 대한 목포하수처리장의 기여율 산정)

  • Kim Kwang-Soo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.6 no.4
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    • pp.37-44
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    • 2003
  • In order to evaluate the contribution of MMSTP operation to the improvement of marine water quality of Mokpo harbour and to estimate the change of pollution loads flowing into Mokpo harbour after the operation of Mokpo Municipal Sewage Treatment Plant (MMSTP), the pollution loads flowing into Mokpo harbour from land in dry weather were surveyed and estimated on the bases of the seasonal flow rates and the seasonal water qualities of streams and effluents located around Mokpo harbour from summer, 1997 to spring, 1998 before the operation of MMSTP, and the pollution loads of the inflow and the effluent of MMSTP were also surveyed and estimated from winter, 1998 to spring, 1999 after the operation of MMSTP. The treatment rates of MMSTP were shown to be about 49% in COD, 76% in TSS, 79% in VSS, 3% in T-N, 7% in DIP, 29% In T-P and -32% in DIN. The change rates of pollution loads flowing into the inner harbour of Mokpo due to the operation of MMSTP were shown to be about 56% in COD, 78% in TSS, 84% in VSS, 45% in DIN, 22% in T-N, 34% in T-P and -14% in DIP The contribution rates of MMSTP operation to the reduction of total pollution loads flowing into the entire Mokpo harbour were found to be about 3% in COD, 3% in TSS, 5% in VSS, 1% in DIP, 3% in T-P and -1% in DIN.

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In Vitro Flower Abscission Induction in North American Ginseng

  • Campeau Cindy;Proctor John T. A.
    • Journal of Ginseng Research
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    • v.29 no.2
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    • pp.71-79
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    • 2005
  • In vitro studies using detached inflorescences with peduncles were conducted to investigate flower abscission agents in North American ginseng (Panax quinquefolius L.). Of the nine compounds studied only three, ammonium thiosulphate (ATS), abscisic acid (ABA) and ethephon induced abscission. Anilazine, benzyladenine, carbaryl, gibberellic acid, napthaleneacetic acid and thidiazuron did not induce abscission. ATS dip treatments did not induce abscission but the spray treatments induced $60.5\%$ abscission at $1500\;mg{\cdot}L^{-1}$ and $33.1\%$ at $3000\;mg{\cdot}L^{-1}$. Severe chlorophyll loss occurred on all inflorescences treated with ATS. Both ABA dip treatments and a $250\;{\mu}mol{\cdot}L^{-1}$ spray treatment caused abscission $(40\%)$ without adverse effects, and timing of ABA application was important. Because ABA was only significant in the dip treatments, ABA may not be a practical option for field use on ginseng. Ethephon sprays induced more abscission as the season progressed and as the concentration increased. As the dip concentrations of ethephon increased, the abscission rate decreased and the health of the inflorescences declined. The $1500\;mg{\cdot}L^{-1}$ spray of ethephon gave consistent abscission results over the glowing season with little phytotoxicity. Treatment with the competitive ethylene inhibitor 1-methylcy-clopropene (1-MCP) suggested that flower abscission was due to the liberation of ethylene from the breakdown of ethephon.

A Study on the Improvement of the Interface Contact and the Prevention of the Charge Recombination by the Surface Treatment of Transparent Conductive Oxide in Dye-sensitized Solar Cell (염료감응형 태양전지 투명전도성 막의 표면처리를 통한 계면 접촉 향상 및 재결합 방지 연구)

  • Seo, Hyun-Woong;Hong, Ji-Tae;Son, Min-Kyu;Kim, Jin-Kyoung;Shin, In-Young;Kim, Hee-Je
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.11
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    • pp.2214-2218
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    • 2009
  • Dye-sensitized solar cell (DSC) has been considered as a possible alternative to current silicon based p-n junction photovoltaic devices due to its advantages of high efficiency, simple fabrication process and low production cost. Numerous researches for high efficient DSC in the various fields are under way even now. Among them, the compact layer, which prevents the back electron transfer between transparent conductive oxides and the redox electrolyte, is fabricated by various methods such as a ZnO dip-coating, $TiCl_4$ dip-coating, and Ti sputtering. In this study, we tried to fabricate the $TiO_2$ compact layer by the spin-coating method using aqueous $TiCl_4$ solution. The effect of the spin-coating method was checked as compared with conventional dip-coating method. As a result, DSC with a spin-coated compact layer had 33.4% and 6% better efficiency than standard DSC and DSC with a dip-coated compact layer.

A Study on catalyst-coated ceramic filter for diesel engine exhaust-gas treatment (디젤엔진 배가스 처리를 위한 세라믹 필터 촉매코팅에 관한 연구)

  • Choi, Sun-Hee;Ku, Kuk-Hae;Jung, Deok-Young;Oh, Kwang-Joong
    • Clean Technology
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    • v.7 no.1
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    • pp.65-74
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    • 2001
  • Modified dip-coating method 8.3 times shorten in solution volume-coated and 83.3 times in coating time than existing dip-coating method. Coating weight increased nearly 2~3 times. So modified dip-coating method is evaluated that it is economic and has a efficiency. When we make an experiment in coated $LaCoO_3$ on ceramic monolith in modified dip-coating method which use 2 coating applications with relative viscosity $0.006202kg{\cdot}m/sec$, it showed a superior reaction at 88.56mg per ceramic unit gram in NO-CO reaction(optimum coating amount). When we make an experiment in the same size of ceramic filter cell with different conditions 100, 200cell per square inch, the result in low temperature($200^{\circ}C{\sim}350^{\circ}C$), 200cell3 per square inch is 6~23% higher in NO reduction and 11% in CO oxidation than 100cell per square inch. It is because the more the number of cells in the ceramic filter increase, the more catalytic surface area is expanded.

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The Change of Pollution Loads flowing into Mokpo Harbour Due to the Operation of Mokpo Municipal Sewage Treatment Plant (목포하수처리장 가동에 따른 목포항 유입 오염부하량의 변화)

  • 김광수
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.8 no.2
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    • pp.39-44
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    • 2002
  • In order to study the change of pollution loads flowing into Mokpo harbour after the operation of Mokpo Municipal Sewage Treatment Plant (MMSTP) and to evaluate the contribution of MMSTP operation to the improvement of marine water quality of Mokpo harbour, the pollution loads flowing into Mokpo harbour from land in dry weather were surveyed and estimated on the bases of the seasonal flow rates and the seasonal water qualities of streams and effluents located around Mokpo harbour from summer, 1997 to spring, 1998 before the operation of MMSTP, and the pollution loads of the inflow and the effluent of MMSTP were also surveyed and estimated from winter, 1998 to spring, 1999 after the operation of MMSTP. The treatment rates of MMSTP were shown to be about 49% in COD, 76% in TSS, 79% in VSS, 3% in T-N, 7% in DIP, 29% in T-P and -32% in DIN. The change rates of pollution loads flowing into the inner harbour of Mokpo due to the operation of MMSTP were shown to be about 56% In COD, 78% in TSS, 84% in VSS, 45% in DIN, 22% in T-N, 34% in T-P and -14% in DIP. The contribution rates of MMSTP operation to the reduction of total pollution loads flowing into the entire Mokpo harbour were found to be about 3% in COD, 3% in 755,5% in VSS,1% in DIP, 3% in T-P and -1% in DIN.

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Synthesis and Characterization of Zeolite Composite Membranes (II): Synthesis and $CO_2$ Separation Efficiency of ZSM-5 Zeolite Composite Membranes (제올라이트 복합 분리막의 합성 및 특성화(II): ZSM-5 제올라이트 복합막의 합성 및 $CO_2$ 분리 효율)

  • 현상훈;송재권;김준학
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.747-757
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    • 1997
  • ZSM-5 zeolite composite membranes have been synthesized from a silica sol solution containing TPABr as an organic template by the dip-coating and the pressurized-coating hydrothermal treatment techniques. The CO2 separation efficiency of synthesized composite membranes was also investigated. The permeation mechanism of CO2 through ZSM-5 membranses was the surface diffusion, and that of N2, O2, and He gases was Knudsen diffusion or activated diffusion depending on the synthetic method of membranes and the measurement temperature. The CO2/N2 separation factor of the membrane prepared by the dip-coating hydrothermal treatment was 2.5 at about 12$0^{\circ}C$, while the ZSM-5 composite membrane synthesized by the pressurized-coating hydrothermal treatment technique showed the CO2/N2 separation factor of 9.0 at room temperature higher than that ever reported in the literature.

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