• Title/Summary/Keyword: diluted hydrogen

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Quasi-steady State Simulation of Rotating Detonation Engine

  • Niyasdeen, Mohammed;Oh, Sejong;Kim, Kui Soon;Choi, Jeong-Yeol
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.4
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    • pp.548-559
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    • 2015
  • We performed a numerical simulation based on the two-dimensional (2-D) unsteady Euler's equation with a single-step Arrhenius reaction model in order to investigate the detonation wave front propagation of an Argon (Ar) diluted oxy-hydrogen mixture ($2H_2+O_2+12Ar$). This simulation operates in the detonation frame of reference. We examine the effect of grid size and the performance impact of integrated quantities such as mass flow. For a given set of baseline conditions, the minimal and maximum grid resolutions required to simulate the respective detonation waves and the detonation cell structures are determined. Tertiary shock wave behavior for various grids and pre-exponential factors are analyzed. We found that particle fluctuation can be weakened by controlling the mass flow going through the oblique shock waves.

Tribological Properties of DLC film with Precursor Gas Diluted by Hydrogen under Water Environment (수소로 희석된 반응 가스로 합성된 DLC 박막의 수중 환경에서의 마찰마모 특성)

  • Lee, Jin-U
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.121-121
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    • 2013
  • 수소로 희석된 벤젠 가스를 반응 가스로 이용하여 합성된 DLC 박막의 마찰 마모 특성을 평가하기 위하여, 일반 대기 환경 및 수중 환경에서 마모 실험을 수행하였다. 일반 대기 환경에서는 박막의 기계적 특성, 마찰 계수 및 마모 거동이 거의 변화하지 않았다. 반면, 수중 환경에서는 마찰 계수가 대기 환경에서보다 안정적으로 평가되었다. 이는 DI-water가 윤활제(lubricant) 역할을 하기 때문으로 예측된다. 또, 수중 환경에서의 마모 실험 결과, 수소가 희석되지 않은 반응 가스를 이용하여 증착 된 DLC 박막의 경우, delamination wear가 상대적으로 많이 관찰되었다. 하지만, 반응 가스에 희석 된 수소량이 증가함에 따라서, 이런 delamination wear가 현저하게 억제됨을 관찰하였다.

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Hot Filament Chemical Vapor Deposition of Crystalline Boron Films

  • Soto, Gerardo
    • Journal of the Korean Ceramic Society
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    • v.56 no.3
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    • pp.269-276
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    • 2019
  • This article reports on the conditions required for the growth of crystalline boron films on silicon substrates by hot filament chemical vapor deposition method. The reactive gas was 3% diborane diluted in hydrogen. The films were characterized by optical, electronic, and atomic force microscopies; x-ray diffraction; and energy dispersive, electron energy loss, Raman, x-ray photoelectron, and Auger spectroscopies. The parameters that affect the morphologies of the films have been investigated. It was concluded that faceted crystals are produced at low B2H6 flows and working pressures below 200 mT. α-boron is produced between 530 and 600℃. Deposition outside this range produces thin films with a wide variety of morphologies. This result indicates that the films crystallize through a process called "abnormal or discontinuous grain growth." It is assumed that this is due to the anisotropic surfaces of boron allotropes.

Annealing Characteristic of Phosphorus Implanted Silicon Films using an Ion Mass Doping Method (Ion Mass Doping 법을 이용한 Phosphorus 주입된 실리콘 박막의 Annealing 특성)

  • 강창용;최덕균;주승기
    • Journal of the Korean institute of surface engineering
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    • v.27 no.4
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    • pp.234-240
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    • 1994
  • A large area impurity doping method for poly-Si TFT LCD has been developed. The advantage of this method is the doping of impurities into Si over a large area without mass separation and beam scanning. Phosphorus diluted in hydrogen was discharged by RF(13.56MHz) power and ions from discharged gas were accelerated by DC acceleration voltage and were implanted into deposited Si films. The annealing characteristic of this method was similar to that of the ion implantation method in the low doping concentration. Three mechanisms were evolved in the annealing characteristics of phosphorus doped Si films. Point defects annihilation and the retrogradation of dopant atoms at grain boundaries as a result of grain growth played a major role at low and high annealing temperature, respectively. However, due to the dopant segregation, the reverse annealing range existed at intermediate annealing temperature.

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Effect of Flame Temperature on the Characteristics of Flame Synthesized TiO2 Nanoparticles (수소 확산화염에서 화염온도가 TiO2 나노입자의 합성에 미치는 영향)

  • Lee Gyo Woo;Lee Seung Bok;Lee Jongsoo;Bae Gwi-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.9 s.240
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    • pp.1013-1021
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    • 2005
  • In this work, $TiO_2$ nanoparticles were synthesized using a N2-diluted hydrogen coflow diffusion flame. The effects of flame temperature on the crystalline structure and the size of formed nanoparticles were investigated. The maximum centerline temperature of the flame ranged from 1,920K for $H_2-only$ flame to 863k for $81\%\;N_2-diluted$ flame. The morphology and the crystal structure of $TiO_2$ nanoparticles were analyzed by a TEM and a XRD, respectively. The particle size distribution was also measured by using a scanning mobility particle size. (SMPS). The mean particle diameter was calculated from the TEM images depended on the flame temperature, having minimum at about 1,look. Based on the SMPS measurements, the mean particle diameter of $TiO_2$ nanoparticles at flame temperatures > 1,300K was smaller than that at flame temperatures < 1,300K. From the XRD analysis, it was evident that the anatase fraction increased with decreasing the flame temperature. The portion of anatase phase in $TiO_2$ nanoparticles might be greater than $80\%$ when the flame temperature was lower than 1,000K.

Effects of Green Tea (Camellia sinensis) Extract Supplementation at Different Dilution Steps on Boar Sperm Cryopreservation and in vitro Fertilization

  • Park, Sang-Hyoun;Jeon, Yubyeol;Yu, Il-Jeoung
    • Journal of Veterinary Clinics
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    • v.35 no.2
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    • pp.39-45
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    • 2018
  • We evaluated the effects of green tea extract (GTE) supplementation at different dilution steps on boar sperm freezing and in vitro fertilization. Sperm intracellular hydrogen peroxide ($H_2O_2$), motility, viability, acrosome integrity and morphology were determined. In addition, sperm IVF parameters (penetration and monospermy) and glutathione (GSH) levels of presumptive zygotes (PZs) were evaluated. Semen was diluted in lactose egg yolk (LEY) and cooled at $5^{\circ}C$ for 3 h (first dilution step) and then diluted in LEY with 9% glycerol and maintained at $5^{\circ}C$ for 30 min (second dilution step). Four experimental groups were compared: first and second dilution steps without GTE (control), first dilution step with GTE (Step 1), second dilution step with GTE (Step 2) and first and second dilution step with GTE (Step 1+2). The spermatozoa were frozen in nitrogen vapor. Higher sperm motility, viability and acrosome integrity after thawing were observed in Step 1, Step 2 and Step 1+2 groups compared with the control (P < 0.05). Lower $H_2O_2$ level was observed in Step 1+2 compared with control and Step 1 (P < 0.05). For IVF, matured oocytes were co-cultured with spermatozoa frozen according to the experimental groups. GSH levels of PZs were significantly higher in Step 2 and Step 1+2 than in control and Step 1 (P < 0.05) without a significant difference in IVF parameters. In conclusion, supplementation with GTE in both first and second dilution steps during the freezing process resulted in better boar sperm cryopreservation and might be beneficial for further embryo development.

Neuroprotective effects of cultured and fermented wild ginseng extracts on oxidative stress induced by hydrogen peroxide in PC12 cells (발효산삼배양근농축액의 산화방지 효과 및 과산화수소로 유발된 PC12 세포독성 보호효과)

  • Choi, Yeo Ok;Kim, Yu-Ri;Shin, Seung-Yong;Lee, Jae Geun;Kim, Chul Joong;Lee, Ye ji;Kang, Byeongju;Kim, Gwansu;Choi, Jee Eun;Han, Beom-Seok
    • Korean Journal of Food Science and Technology
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    • v.50 no.4
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    • pp.383-390
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    • 2018
  • Most neurodegenerative diseases are known to be influenced by oxidative stress. We investigated the anti-oxidative activity of the concentrate of fermented wild ginseng root culture (HLJG0701) containing ginsenosides Rg5 and Rk1. HLJG0701 showed effective DPPH and ABTS radical scavenging ability ($IC_{50}$: 16- and 4-fold dilution, respectively) and was inhibited dose-dependently by the $FeSO_4$-induced lipid peroxidation group (8- and 4-fold dilution: 2.3 and 1.5 nM, respectively). In MTT and LDH assays, 8-, 16-, 32- and 64-fold diluted HLJG0701 significantly increased cell viability by 70, 53, 35, and 26%, respectively. LDH released by HLJG0701 was reduced 1.3-fold with 8-fold diluted HLJG0701 compared to the $H_2O_2$-treated control. In addition, the inhibitory effect of HLJG0701 on oxidative stress in PC12 cells was confirmed by DCF-DA analysis (16-, 4-fold diluted HLJG0701: 50 and 68% ROS inhibition, respectively), TBARS (16- and 4-fold diluted HLJG0701: 50.7 and 46.5% inhibition, respectively), GPx (16- and 4-fold diluted HLJG0701: 133.3 and 227.3% release, respectively), and SOD analysis (16- and 4-fold diluted HLJG0701: 118.2 and 218.2% release, respectively). These results suggested that HLJG0701 protects neuronal cells by its anti-oxidative effects and hence can be a potential preventive material against neurodegenerative diseases.

A Numerical Analysis of Acoustic-Pressure Response of H2-Air Diffusion Flames with Application of Time-Lag Model (시간지연 모델의 적용을 통한 수소/공기 확산화염의 음향파 응답 분석)

  • Sohn, Chae-Hoon;Lim, Jun-Seok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.1
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    • pp.1-8
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    • 2012
  • Acoustic-pressure response of diluted hydrogen-air diffusion flames is investigated numerically by adopting a fully unsteady analysis of flame structures in low and high pressure regimes. As acoustic frequency increases, finite-rate chemistry is enhanced through a nonlinear accumulation of heat release rate for any pressure regime, leading to a high amplification index. Same numerical results are analyzed with application of a pressure-sensitive time lag model, and thereby, interaction index and time lag are calculated for each pressure regime. The interaction index has the largest value in each pressure regime at an acoustic frequency near 1000 Hz. In a high-pressure regime, flames are more unstable than in a low-pressure regime. The interaction index shows a good agreement with the amplification index.

Planar Imaging of Temperature and Concentration of a Laminar Nonpremixed $H_2$/$N_2$flame Using a Tunable KrF Excimer Laser (파장 가변형 KrF 에시머 레이저를 이용한 층류 비예혼합 수소 화염에서의 2차원적 온도 및 농도 계측)

  • Kim, Gun-Hong;Jin, Seong-Ho;Kim, Yong-Mo;Park, Gyeong-Seok;Kim, Se-Won;Kim, Gyeong-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.12
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    • pp.1580-1587
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    • 2000
  • Rayleigh scattering and laser induced predissociative fluorescence are employed for capturing two-dimensional images of temperature and species concentration in a laminar nonpremixed flame of a diluted hydrogen jet. Rayleigh scattering cross-sections are experimentally obtained ar 248nm. Dispersed LIPF spectra of OH and O$_2$ are also measured in a flame in order to confirm the excitation of single vibronic state of OH and O$_2$ .OH and O$_2$ are excited on the P$_1$(8) line of the A $^2\Sigma ^+(v^`=3) - X^2\pi (V^"=0)$ band and R(17) line of the Schumann-Runge band B $^3\Sigma _u^-(v^`=0) - X ^3\Sigma _g^-(v^"=6)$, respectively. Fluorescence spectra of OH and Hot O$_2$ are captured and two-dimensional images of the hydrogen flame field are successfully visualized.

Seasonal Variation of Surface Water Quality in a Catchment Contaminated by $NO_3-N$ (질산성 질소로 오염된 소유역 하천 수질의 계절 변화)

  • Kim Youn-Tae;Woo Nam-Chil;Lee Kwang-Sik;Song Yun-Goo
    • Journal of Soil and Groundwater Environment
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    • v.10 no.2
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    • pp.20-27
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    • 2005
  • The seasonal variation of water quality was studied in the Hwabongcheon. It runs though a small catchment where shallow groundwater was contaminated with $NO_3-N$ by intensive livestock facilities. A direct inflow of animal waste and incoming of contaminated groundwater affected its water quality. In the dry season, an important factor of water quality in the Hwabongcheon was direct inflow of animal waste. In the wet season, concentrations of $NO_3-N$ in the Hwabongcheon were elevated in spite of being diluted by precipitation. It could be explained by the effect of increased incoming of contaminated groundwater and showed by oxygen and hydrogen isotope values. $NO_3-N$ concentration in the Cheongmicheon was lower than that in the Hwabongcheon, so it increased next a junction. This effect was intense in wet season because $NO_3-N$ concentration in the Hwabongcheon was high.