• 제목/요약/키워드: diffusion mode

검색결과 227건 처리시간 0.028초

실로퓨트의 세팔로마닌 흡착: 등온흡착식 및 속도론적·열역학적 특성 (Adsorption of Cephalomannine onto Sylopute: Isotherm, Kinetic and Thermodynamic Characteristics)

  • 김현식;김진현
    • Korean Chemical Engineering Research
    • /
    • 제57권2호
    • /
    • pp.219-224
    • /
    • 2019
  • 본 연구에서는 흡착공정에 의한 Taxus chinensis 유래 세팔로마닌의 효율적 분리를 위하여, 흡착 온도, 흡착 시간 및 초기 세팔로마닌 농도를 달리하여 상용흡착제 실로퓨트에 의한 세팔로마닌의 흡착 특성을 조사하였다. 흡착 평형 데이터는 Temkin 흡착등온식에 가장 적합하였다. 흡착 온도가 증가함에 따라 흡착 용량은 감소하였으며, 물리적 흡착 공정임을 알 수 있었다. 속도론적 데이터는 유사 이차 반응속도식에 적합하였다. 입자 내 확산 모델에 의하면, 필름 확산과 입자 내 확산은 전체 흡착 속도에 거의 영향을 미치지 않았다. 열역학적 데이터를 통해 흡착 과정은 발열 반응이며 자발적이었다. 또한 흡착량이 증가함에 따라 등량흡착열은 거의 변화가 없었으며 흡착제의 표면 에너지가 균일함을 알 수 있었다.

Mechanism of Tungsten Recovery from Spent Cemented Carbide by Molten Salt Electrodeposition

  • Hongxuan Xing;Zhen Li;Enrui Feng;Xiaomin Wang;Hongguang Kang;Yiyong Wang;Hui Jin;Jidong Li
    • Journal of Electrochemical Science and Technology
    • /
    • 제14권1호
    • /
    • pp.75-84
    • /
    • 2023
  • The accumulation of spent carbide (YG8), not only pollutes the environment but also causes waste of tungsten, cobalt and other rare metal resources. To better address this issue, we proposed a combined electrochemical separation process of low-temperature aqueous solution and high-temperature molten salt for tungsten and cobalt. H2WO4 was obtained from spent carbide in an aqueous solution, and we calcined it to obtain WO3, which was used as a raw material to obtain tungsten by using molten salt electrodeposition. The influence of the current efficiency and the electrochemical behavior of the discharge precipitation of W(VI) were also studied. The calcination results showed that the morphology of WO3 was regular and there were no other impurities. The maximum current efficiency of 82.91% was achieved in a series of electrodeposition experiments. According to XRD and SEM analysis, the recovered product was high purity tungsten, which belongs to the simple cubic crystal system. In the W(VI) reduction mechanism experiments, the electrochemical process of W(VI) in NaCl-Na2WO4-WO3 molten salt was investigated using linear scanning voltammetry (LSV) and chronoamperometry in a three-electrode system. The LSV showed that W(VI) was reduced at the cathode in two steps and the electrode reaction was controlled by diffusion. The fitting results of chronoamperometry showed that the nucleation mechanism of W(VI) was an instantaneous nucleation mode, and the diffusion coefficient was 7.379×10-10 cm2·s-1.

CMOS 이미지 센서용 NMOS-Diode eFuse OTP 설계 (Design of an NMOS-Diode eFuse OTP Memory IP for CMOS Image Sensors)

  • 이승훈;하판봉;김영희
    • 한국정보통신학회논문지
    • /
    • 제20권2호
    • /
    • pp.306-316
    • /
    • 2016
  • 본 논문에서는 프로그램 선택 소자는 채널 폭이 큰 NMOS (N-channel MOSFET) 트랜지스터 대신 DNW (Deep N-Well) 안에 형성된 채널 폭이 작은 isolated NMOS 트랜지스터의 body인 PW (P-Well)과 source 노드인 n+ diffusion 영역 사이에 형성된 기생하는 접합 다이오드를 사용하는 NMOS-Diode eFuse OTP (One-Time Programmable) 셀을 제안하였다. 제안된 eFuse OTP 셀은 프로그램 모드에서 NMOS 트랜지스터에 형성되는 기생하는 접합 다이오드를 이용하여 eFuse를 blowing 시킨다. 그리고 읽기 모드에서는 접합 다이오드를 이용하는 것이 아니고 NMOS 트랜지스터를 이용하기 때문에 다이오드의 contact voltage 강하를 제거할 수 있으므로 '0' 데이터에 대한 센싱불량을 제거할 수 있다. 또한 읽기 모드에서 채널 폭이 작은 NMOS 트랜지스터를 이용하여 BL에 전압을 전달하므로 OTP 셀의 blowing되지 않은 eFuse를, 통해 흐르는 읽기 전류를 $100{\mu}A$ 이내로 억제하여 blowing되지 않은 eFuse가 blowing되는 문제를 해결할 수 있다.

산악지형에서의 원자력발전소 사고시의 피폭해석 (Analysis of Radiation Exposure from Nuclear Reactor Accident in Complex Terrain)

  • Moon Hee Han;Sung Ki Chae;Moon Hyun Chun
    • Nuclear Engineering and Technology
    • /
    • 제17권3호
    • /
    • pp.216-223
    • /
    • 1985
  • 원자력 발전소로부터 방출되는 기체상 방사성 물질에 의한 환경 영향을 평가함에 있어서 방사성 물질의 대기중에서의 수송과 확산을 기술하는 모델로써 Gaussian plume mode띠 널리 사용되고 있다. Gaussian plume model은 평탄한 지형에 적용하도록 만들어진 모델이므로 대부분의 국토가 복잡한 산악으로 구성된 한극의 경우에 적용하기 위해서는 모델의 수정이 필요하다. 본 논문에서는 2차원적 x-z 평면에서 확산방정식을 해석한 numerical diffusion model과 Gaussian plume model을 비교하여, Gaussian plume mode에서 가장 중요한 변수인 dispersion coefficient를 지형의 높이에 대하여 보정하였다. 보정된 dispersion coefficient 값을 Gaussian plume mode에 적용시켜 계산을 수행한 결과를 보면, 산악지역에서의 방사성 물질의 농도는 평지에서보다 낮게 나타나고 있다.

  • PDF

Si(111)표면 위에서 Si의 동종층상성장에 관한 연구 (The Study of Si homoepitaxial growth on Si(111) Surface)

  • 곽호원;문병연
    • 한국산업융합학회 논문집
    • /
    • 제7권4호
    • /
    • pp.349-354
    • /
    • 2004
  • The growth mode of the Si layers which were grown on Si(111) by using Ag as surfactant were investigated by intensity oscillations of the RHEED specular spot at the different temperatures. we found that the introduction of Ag as the surfactant alters the growth mode from a three-dimensional clustering mechanism to a two-dimensional layer-by-layer growth. In the growth of Si layers on Si(111) with a surfactant Ag, At $450^{\circ}C$, RHEED intensity oscillation was very stable and periodic from early stage of deposition to 32 ML. RHEED patterns during homoepitaxial growth at $450^{\circ}C$ was changed from $7{\times}7$ structure into ${\sqrt{3}}{\times}{\sqrt{3}}$ structures. Since the ${\sqrt{3}}{\times}{\sqrt{3}}$ structure include no stacking fault, the stacking fault layer seems to be reconstructed into normal stacking one at transition from the $7{\times}7$ structure to a ${\sqrt{3}}{\times}{\sqrt{3}}$ one. We also found that the number of the intensity oscillation of the specular spot for Si growth with a surfactant Ag was more than for Si growth without a surfactant. This result may be explained that the activation energy decrease for the surface diffusion of Si atoms due to segregation of the surfactant toward the growing surface.

  • PDF

고체로켓연소에서 에지화염 불안정성에 대한 실험적 연구 (Experimental Study on Edge Flame Instabilities in Solid Rocket Combustion)

  • 황동진;박정;김정수;김성초;김태권
    • 한국추진공학회:학술대회논문집
    • /
    • 한국추진공학회 2006년도 제26회 춘계학술대회논문집
    • /
    • pp.279-282
    • /
    • 2006
  • 이산화탄소를 첨가한 저 신장률 메탄-공기 대향류 확산화염에서 화염소화 거동과 에지화염 진동을 조사하기 위해 실험을 수행하였다. 화염소화 조건에서의 임계 몰분율을 속도비와 전체화염 신장률에 따라 분석하였다. 또한 에지화염 진동의 시작조건과 관련된 모드들을 전체화염 신장률에 따라 조사하였다. 화염길이는 측면방향 열손실과 밀접한 연관이 있으며, 측면방향 열손실은 화염소화와 에지화염 진동에 중대한 영향을 미친다. 에지화염의 진동 모드는 성장, 감쇠, 조화 세 가지로 분류된다.

  • PDF

$LiNbo_3$의 음향광학효과와 음향파 장벽을 이용한 편광모드 변환형, 파장가변 광 필터에 관한 연구 (A study of polarized mode convertible, wavelength tunable optical filter utilizing acoustic barrier and acouxto-optic effect in $LiNbo_3$)

  • 임경훈;정홍식
    • 한국광학회지
    • /
    • 제11권3호
    • /
    • pp.193-197
    • /
    • 2000
  • 음향파 장벽 구조와 음향광학효과를 이용한 편광모드 변환형 파장가변 광 필터를 LiNbo3와 Ti 이중 확산 공정 기술을 이용하여 제작하였다. 1552.6nm 파장의 TE, TM 입사 편광모드에 대해서 173.07MHz, 173.05MHz의 Rf 주파수에서 81% 이상의 변환효율과 ∼200kHz(∼1.83nm)의 통과대역폭을 얻어Tdmaum 구동파워는 10.97mW로서 음향파 장벽이 없는 광 필터 파워의 10%에 불과 하였다. 파장 변화율과 부 모드 레벨리 각각 8.2nm/MHz와 -4dB로 측정하였다.

  • PDF

수동 Mode에서 PSD System 최적화 연구 (A Study on PSD System optimization from manual mode)

  • 손영진;민경윤;이강원;방연근
    • 한국철도학회:학술대회논문집
    • /
    • 한국철도학회 2004년도 추계학술대회 논문집
    • /
    • pp.162-167
    • /
    • 2004
  • The ascent and descent market screen door (PSD-Platform Screen Door) between the electromotive car which is in the process of operating from the subway ascent and descent market and the passenger it is an immediacy and crisis as the system which it intercepts currently the inside and outside of the country of course signal system automatic operation signal system (ATO) establishment is operated from the segment. Manual operation signal system (the ATS and the ATC) almost it is a condition which is wholly lacking from the segment. This year from second half of the year 2 line manual operation signal system (ATS). It established the shutting tightly elder brother and the railing elder brother in PSD system in segment 12 reverses and the death accident due to the passenger hurt accident which occurs from the subway. It prevented an energy curtailment in the same time when it raises air cooling efficiency, It gathered it restricted the underground space which is comfortable in the use citizen and and and service it did interface the electromotive car and PSD entrance and exit literature course from the manual operation segment to sleep technically optimizationt. It researched a minute dust diffusion.

  • PDF

광통신용 도파로형 $Ti:LiNbO_3$ AOTF 제작 및 특성 (Characteristics and Fabrication of a Waveguide Type $Ti:LiNbO_3$(Acousto-Optic Tunable Filter) for Optical Communications)

  • 김성구;한상필;윤형도;임영민;윤대원;정운조;박계춘;정해덕
    • 한국전기전자재료학회논문지
    • /
    • 제11권8호
    • /
    • pp.637-645
    • /
    • 1998
  • The characteristics of waveguide, electrode and packaging fabricated for acousto-optic tunable filters(AOTF) used for optical communications were analyzed. A $Ti:LiNbO_3$in-diffusing method was employed for the formation of the optical waveguide with a dimension of width $8{\mu}m$, length $30000-50000{\mu}m$ and varying the thickness. The diffusion was carried at $1050^{\circ}C$ for 8 hours to pattern the optical waveguide. The resulted waveguide exhibited a single mode at 1550nm optical wavelength. The width of IDT, with 10 SAM periods, was $5000{\mu}m$ . Impedances of the electrodes deposited with Au were analyzed using a network analyzer; $48.1\Omega$ at the center frequency of 193MHz for electrode thickness of $1500{\AA}$ and $50.7\Omega$ at the center frequency of 192MHz for $1600\AA$. And the characteristics of packaged AOTF was analyzed. When the electrical frequency 177.1MHz was applied to the device, the mode conversion efficiency was measured as 63% at the optical wavelength 1515nm.

  • PDF

종자계형 진공 인터럽터에서 접점전극 슬릿의 영향에 관한 연구 (A Study on the Effect of the Contact Electrode Slits in the Vacuum Interrupter with Axial Magnetic Field Type)

  • 하덕용;강형부;최승길;최경호
    • 한국전기전자재료학회논문지
    • /
    • 제15권9호
    • /
    • pp.822-829
    • /
    • 2002
  • This paper deals with the distribution characteristics of the current density and axial magnetic flux density for each slits made on the contact electrode in the vacuum interrupter with axial magnetic field type using 3-dimension finite element analysis. It has been known that the presence of an axial magnetic field parallel to the current flow in the arc plasma can increase the high current breaking capacity of vacuum interrupter by carrying out the arc plasma from constricted mode to diffusion mode. The axial magnetic field is created of itself by current flow in the segments of coil electrode behind the contact electrode. The analyzed results show that if the slits are made in the contact electrode, they can increase the current density and axial magnetic flux density in the contact electrode surface and at the gap distance, which is due to decrease the effect of eddy currents flowing in the contact electrode. The phase shift due to eddy currents, defined 3s time difference between the maximum value of current and axial magnetic field, is decreased still more by increasing the number of slits made in the contact electrode at the center point of gap distance. These results demonstrate that 3-dimension finite element analysis has a great deal of merits in the development and evaluation of new electrode at the design of vacuum interrupter.