• Title/Summary/Keyword: diffusion method

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자기치유 콘크리트의 균열치유 성능평가를 위한 개선된 산소확산 시험방법 제안 (Development of Oxygen Diffusion Test Method for Crack Width Evaluation of Self-Healing Concrete)

  • 이도근;신경준
    • 한국건설순환자원학회논문집
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    • 제9권3호
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    • pp.375-382
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    • 2021
  • 자기치유 콘크리트는 직접적인 보수보강 없이도 스스로 구조물의 균열을 치유하여 효율적으로 콘크리트 구조물의 수명연장이 가능하다는 측면에서 각광받고 있다. 현재 자기치유 콘크리트는 전 세계적으로 활발히 연구가 진행되고 있는 분야이지만 대부분의 연구는 치유 성능의 향상에 초점을 맞추고 있기 때문에 객관적으로 치유성능을 평가하는 방법은 부족한 실정이다. 자기치유 콘크리트의 성능평가에 활용하기 위해 기체확산실험 방법이 개발된 바가 있지만, 시편의 포화도 및 실험시의 온습도 등과 같은 환경조건의 통제가 필요하다는 단점이 있다. 따라서 본 연구에서는 기체 확산 실험시에 필요한 환경조건을 대폭 완화하여 적용성을 향상시키고자 하였다. 아울러 실험시간을 단축시키고자 사전 안정화 과정을 도입하였고, 약 20분이내의 실험시간에서 3%이내의 오차 수준으로 균열폭의 추정이 가능하였다.

Uniformly Convergent Numerical Method for Singularly Perturbed Convection-Diffusion Problems

  • Turuna, Derartu Ayansa;Woldaregay, Mesfin Mekuria;Duressa, Gemechis File
    • Kyungpook Mathematical Journal
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    • 제60권3호
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    • pp.629-645
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    • 2020
  • A uniformly convergent numerical method is developed for solving singularly perturbed 1-D parabolic convection-diffusion problems. The developed method applies a non-standard finite difference method for the spatial derivative discretization and uses the implicit Runge-Kutta method for the semi-discrete scheme. The convergence of the method is analyzed, and it is shown to be first order convergent. To validate the applicability of the proposed method two model examples are considered and solved for different perturbation parameters and mesh sizes. The numerical and experimental results agree well with the theoretical findings.

원통평판법을 이용한 비타민 $B_12$의 정량 (Determination of Vitamin $B_12$ by Agar Diffusion Method)

  • 이성호;조진성;송영준
    • Journal of Pharmaceutical Investigation
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    • 제21권2호
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    • pp.79-84
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    • 1991
  • The agar diffustion method using Escherichia coli was investigated for determination of Vitamin $B_{l2}$ instead of turbidimetric method using Lactobacillus leichannii (USP XXII method). The turbidimetric method is difficult to control the test organism and it has complicated procedure. From this study, it was found that the agar diffusion method on the determination of Vitamin $B_{12}$ in pharamaceutical preparation is simple and convenient as compared with turbidimetric method. Also we found that the coefficient of variation in reproducibility and the standard error in recovery were 2.18% and 1.83%, respectively.

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Development of an Automated Diffusion Scrubber-Conductometry System for Measuring Atmospheric Ammonia

  • Lee, Bo-Kyoung;Lee, Chong-Keun;Lee, Dong-Soo
    • Bulletin of the Korean Chemical Society
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    • 제32권6호
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    • pp.2039-2044
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    • 2011
  • A semi-continuous and automated method for quantifying atmospheric ammonia at the parts per billion level has been developed. The instrument consists of a high efficiency diffusion scrubber, an electrolytic on-line anion exchange device, and a conductivity detector. Water soluble gases in sampled air diffuse through the porous membrane and are absorbed in an absorbing solution. Interferences are eliminated by using an anion exchange devises. The electrical conductivity of the solution is measured without chromatographic separation. The collection efficiency was over 99%. Over the 0-200 ppbv concentration range, the calibration was linear with $r^2$ = 0.99. The lower limit of detection was 0.09 ppbv. A parallel analysis of Seoul air over several days using this method and a diffusion scrubber coupled to an ion chromatography system showed acceptable agreement, $r^2$ = 0.940 (n = 686). This method can be applied for ambient air monitoring of ammonia.

A MODEL STUDY ON MULTISTEP RECOVERY OF ACTINIDES BASED ON THE DIFFERENCE IN DIFFUSION COEFFICIENTS WITHIN LIQUID METAL

  • CHUN, YOUNG-MIN;SHIN, HEON-CHEOL
    • Nuclear Engineering and Technology
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    • 제47권5호
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    • pp.588-595
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    • 2015
  • This study presents an effective method for additional recovery of residual actinides in liquid electrodes after the electrowinning process of pyroprocessing. The major distinctive feature of this method is a reactor with multiple reaction cells separated by partition walls in order to improve the recovery yield, thereby using the interelement difference in diffusion coefficients within the liquid electrode and controlling the selectivity and purity of element recovery. Through an example of numerical simulation of the diffusion scenarios of individual elements, we verified that the proposed method could effectively separate the actinides (U and Pu) and rare-earth elements contained in liquid cadmium. We performed a five-step consecutive recovery process using a simplified conceptual reaction cell and recovered 58% of the initial amount of actinides (U + Pu) in high purity (${\geq}99%$).

확산포집-이온크로마토그래프법을 이용한 대기중 SOx의 자동정량 (Automated Determination of SOx in Air by Diffusion Scrubber-lon Chromatography)

  • 이용근;이동수;백선영
    • 한국대기환경학회지
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    • 제11권4호
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    • pp.307-313
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    • 1995
  • An automatic method is developed for the determination of SOx in atmosphere. The method involves SOx sampling in diffusion scrubber followed by ion chromatographic analysis. Filtered air is withdrawn at 1.8.ell./min through a diffusion scrubber of which inner tube is made of PTFE(Gore-tex) membrane tubing. 1mM $H_{2}$ $O_{2}$ is used as absorbing solution so that SOx is oxidized to S $O_{4}$$^{2-}$. The scrubbered solution is automatically injected into ion chromatograhpy eith conductivity detection for sulphate determination. Replacement of commonly used polyproplene membrane with PTFE gives several merits such as easy preparation of diffusion scrubber, better collection efficiency. No measurable memory effect is experienced, and this isin contrast to previous work for ammonia. Detection limit of this method defined by three times standard deviation is 0.56ppbv. The precision is 0.4% RSD at SOx concentration of 7.3ppbv Results for Seoulatmosphere ate presented.

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반실험적 반전 방법을 이용한 이성분계 기체 혼합물의 점도와 확산계수 계산 (Calculation of the Viscosity and Diffusion Coefficients for Some Binary Gaseous Mixtures Using the Semi-empirical Inversion Method)

  • Rafiee, H.R.;Heidari, N.
    • 대한화학회지
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    • 제55권4호
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    • pp.581-589
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    • 2011
  • 넓은 범위의 온도와 조성 하에 있는 벤젠-톨루엔, 벤젠- 페놀, 벤젠- p-자일렌의 이성분계 기체 혼합물에 대한 점도와 확산계수를 반실험적 반전 방법을 사용하여 예측하였다. 점도와 확산계수에 대한 정확도는 각각 3%와 4% 이내이다.

확산모형에 대한 일반화적률추정법의 개선 (Improved Generalized Method of Moment Estimators to Estimate Diffusion Models)

  • 최영수;이윤동
    • 응용통계연구
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    • 제26권5호
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    • pp.767-783
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    • 2013
  • 일반화적률추정법(GMM)은 금융자료에 대한 모형모수의 추정에 자주 이용되는 방법이다. 특히 GMM은 현대금융 공학 이론의 기본을 이루는 확산모형의 추정에도 매우 자주 사용된다. 그러나 최근의 연구에서 GMM은 확산모형의 모수, 특히 확산계수에 관계되는 모수의 추정에 있어서 그 성능이 좋지 못함이 지적되었다. 본 연구에서는 GMM의 이러한 단점을 개선하기 위한 대안적 방법들을 제시하고 그 통계적 성능을 시뮬레이션 연구를 통해서 비교하게 된다. 이런 과정을 통하여 제안되고 검토된 추정방법들 중, Shoji와 Ozaki (1998)가 제안한 국소선형근사법의 결과를 적용하여 GMM의 성능을 개선한 NGMM-Y 추정량이 매우 우수한 성질을 가지고 있음을 확인하게 된다. 특히 NGMM-Y 추정량은 확산계수에 관계된 모수의 추정에 있어서 비교대상이 된 다른 대안적 GMM 방법들에 비하여 우수한 성질을 가지고 있음을 확인하게 된다.

A$_2$O$_3$세라믹과 Ni-Cr-Mo鋼과의 인서트 合金을 이용한 擴散接合에 關한 硏究 (A study on the diffusion bonding of the $Al_2$O$_3$ ceramics to metal)

  • 김영식;박훈종;김정일
    • Journal of Welding and Joining
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    • 제10권3호
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    • pp.63-72
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    • 1992
  • The joining methods of ceramics to metals which can be expected to obtain high temperature strength are mainly classified into the solid-state diffusion bonding method and the active brazing method. Between these two, the solid-state diffusion bonding method is given attentions as substituting method for active brazing method due to being capable of obtaining higher bonding strength at high temperature and accurate bonding. In this paper, the solid-state diffusion bonding of $Al_{2}$O$_{3}$ ceramics to Ni-Cr-Mo alloy steel (SNCM21) using insert metal was carried out. The insert metal employed in this study was experimentally home-made, Ag-Cu-Ti alloy. Influence of several bonding parameters of $Al_{2}$O$_{3}$SNCM21 joint was quantitatively evaluated by bonding strength test, and microstructural analyses at the interlayer were performed by SEM/EDX. From above experiments, the optimum bonding condition of the solid-state diffusion bonding of $Al_{2}$O$_{3}$/SNCM21 using Ag-Cu-Ti insert metal was determined. Futhermore, high temperature strength and thermal-shock properties of $Al_{2}$O$_{3}$/SNCM21 joint were also examined. The results obtained are as follows. 1. The maximum bonding strength was obtained at the temperature of 95% melting point of insert metal. 2. The high temperature strength of $Al_{2}$O$_{3}$/SNCM21 joint appeared to bemaximum value at test temperature 500.deg.C and the bonding strength with increasingtemperature showed parabolic curve. 3. The strength of thermal-shocked specimens was far deteriorated than those of as-bonded specimens. Especially, water-quenched specimen after heated up to 600.deg. C was directly fractured in quenching.

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확산필름 부착 위치에 따른 광선반 성능개선 연구 (Research of the Performance Improvement of a Light Shelf Depending on the Diffusion Film Installation Position)

  • 박은수;이행우;송석재;김용성
    • KIEAE Journal
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    • 제17권3호
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    • pp.91-97
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    • 2017
  • Purpose: Various studies on a light shelf are in progress, but it has the problem of glare occurrence. The present study suggested a diffusion film as the method for resolving the glare problem, and aimed to establish light shelf-related basic data by conducting the performance evaluation of a light shelf depending on the installation position of the diffusion film. Method: To carry out the light shelf performance evaluation depending on the diffusion film installation position, three cases were established: no diffusion film installation (Case 1), diffusion film installation on the reflector (Case 2), and diffusion film installation on the upper glass surface of the window for light shelf installation (Case 3); and the energy reduction performance, luminance, and luminance contrast were analyzed based on a testbed. Result: The conclusions of this study are as follows. 1) When the diffusion film was applied, the amount of light introduced through the light shelf decreased, and the average indoor illumination decreased accordingly. 2) For Case 3, the lighting energy reduction performance was identical to the lighting energy reduction efficiency of the existing light shelf; and for Case 2, it was found to be inappropriate as the lighting energy consumption increased compared to that of the existing light shelf. 3) The analysis of the glare for the cases established in this study showed that the luminance contrast was low for Case 3, and thus the glare problem could be minimized. 4) The specific angle of the light shelf could induce the glare problem by increasing the luminance depending on the external condition. 5) Based on the aforementioned contents, the installation position of the diffusion film for improving the lighting performance and glare problem of the light shelf was found to be the upper glass surface of the window for light shelf installation.