• 제목/요약/키워드: diffusion mechanism

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The Creep Characteristics of Zirconium-base Alloy (Zirconium계 합금의 Creep특성)

  • Im, S.H.;Rhim, S.K.;Kim, K.H.;Choi, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.3
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    • pp.198-208
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    • 1997
  • The-steady-state creep mechanism and behavior of Zircaloy-4 used as cladding materials in PWR have been investigated in air environment over the temp, ranges from 600 to $645^{\circ}C$ and stress ranges from 4 to $7kg/mm^2$. The stress exponents for the creep deformation of this alloy, n were decreased 4.81, 4.71, 4.64, and 4.56 at 600, 615, 630 and $645^{\circ}C$, respectively; the stress exponents decreased with increasing the temperature and got closer to about 5. The apparent activation energies, Q, were 62.1, 60.0, 57.9 and 55.4 kcal/mole at stresses of 4, 5, 6, $7kg/mm^2$, respectively; the activation energies decreased with increasing the stress and were close to those of volume self diffusion of Zr in Zr-Sn-Fe-Cr system. In results, it can be considered that the creep deformation for Zircaloy-4 was controlled by the dislocation climb over the ranges of this experimental conditions. Larson-Miller parameter, P, for the crept specimens was obtained as P=(T+460)(logt,+23). The failure plane observed by SEM slightly showed up intergranular fracture at this experiment ranges. However, it was essentially dominated by the dimple phenomenon, which was a characteristics of the transgranular fracture.

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Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode with Different Dopants (Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기화학적 특성)

  • 김현철;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.141-146
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    • 2002
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte, KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior, was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the oxidation potential of the PPy was about -02 V vs Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. The falloff of the oxidation potential gave a sign of an improvement in the electron hopoing mechanism on the backbone. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS improved in mass transport or diffusion. That was because the PPy doped with p-TS was more porous than PPy with KCl. We attained an effect of good kinetic parameters, in the case of PP-GOx enzyme electrodes doped with p-TS, which were determined by 58 mmol dm$\^$-3/ for apparent Michaelis constant and by 581 ㎂ for maximum current respectively.

A Numerical Study on the Transmission of Thermo-Acoustic Wave Induced by Step Pulsed Heating in an Enclosure (제한공간내 펄스가열에 기인한 열음향파의 전달특성에 관한 수치적 연구)

  • 황인주;김윤제
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.11
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    • pp.914-922
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    • 2002
  • Thermo-acoustic waves can be thermally generated in a compressible flow field by rapid heating and cooling, and chemical reaction near the boundary walls. This mechanism is very important in the space environment in which natural convection does not exist. Also this may be a significant factor for heat transfer when the fluids are close to the thermodynamic critical point. In this study, the generation and transmission characteristics of thermo-acoustic waves in an air-filled confined domain with two-step pulsed heating are studied numerically. The governing equations are discretized using control volume method, and are solved using PISO algorithm and second-order upwind scheme. For the purpose of stable solution, time step was set to the order of $1\times10_-9s,\;and\;grids\;are\;50\times2000$. Results show that temperature and pressure distributions of fluid near the boundary wall subjected to a rapid heating are increased abruptly, and the induced thermo-acoustic wave propagates through the fluid until it decays due to viscous and heat dissipation. Pressure waves have sharp front shape and decay with a long tail in the case of step heating, but these waves have sharp pin shape in the case of pulsed heating.

Effect of Deformation Temperature on Crystal Texture Formation in Hot Deformed Nanocrystalline SmCo5 Permanent Magnets

  • Ma, Q.;Yue, M.;Lv, W.C.;Zhang, H.G.;Yuan, X.K.;Zhang, D.T.;Zhang, X.F.;Zhang, J.X.;Gao, X.X.
    • Journal of Magnetics
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    • v.21 no.1
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    • pp.25-28
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    • 2016
  • In the present study, bulk anisotropic nanocrystalline $SmCo_5$ magnets were prepared by hot deformation. The effect of deformation temperature on the texture and magnetic properties are presented, based on which the mechanism of plastic deformation and texture formation during the hot deformation process is discussed. Our analyses reveal that deformation temperature is one of the most important parameters that determine the texture of $SmCo_5$ grains. We suggest that diffusion creep plastic deformation occurs during hot deformation, which is very sensitive to the energy gain provided by an increase in temperature.

Analysis of In/Ga Inter-Diffusion Effect on the Thermodynamical Properties of InAs Quantum Dot

  • Abdellatif, M.H.;Song, Jin Dong;Lee, Donghan;Jang, Yudong
    • Applied Science and Convergence Technology
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    • v.25 no.6
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    • pp.158-161
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    • 2016
  • Debye temperature is an important thermodynamical factor in quantum dots (QDs); it can be used to determine the degree of homogeneity of a QD structure as well as to study the interdiffusion mechanism during growth. Direct estimation of the Debye temperature can be obtained using the Varshni relation. The Varshni relation is an empirical formula that can interpret the change of emission energy with temperature as a result of phonon interaction. On the other hand, phonons energy can be calculated using the Fan Expression. The Fan expression and Varshni relation are considered equivalent at a temperature higher than Debye temperature for InAs quantum dot. We investigated InAs quantum dot optically, the photoluminescence spectra and peak position dependency on temperature has been discussed. We applied a mathematical treatment using Fan expression, and the Varshni relation to obtain the Debye temperature and the phonon energy for InAs quantum dots sample. Debye temperature increase about double compared to bulk crystal. We concluded that the In/Ga interdiffusion during growth played a major role in altering the quantum dot thermodynamical parameters.

Structure of Edge Flame in a Methane-Oxygen Mixing Layer (메탄/순산소 혼합층에서 Edge Flame의 구조)

  • Choi, S.K.;Kim, J.;Chung, S.H.;Kim, J.S.
    • Journal of the Korean Society of Combustion
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    • v.11 no.1
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    • pp.19-26
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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Approximation of most penetrating particle size for fibrous filters considering Cunningham slip correction factor

  • Jung, Chang Hoon;Yoon, Young Jun;Um, Junshik;Lee, Seoung Soo;Lee, Ji Yi;Chiao, Sen;Kim, Yong Pyo
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.439-445
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    • 2020
  • In the estimation of the aerosol single fiber efficiency using fibrous filters, there is a size range, where the particles penetrate most effectively through the fibrous collectors, and corresponding minimum single fiber efficiency. For small particles in which the diffusion mechanism is dominant, the Cunningham slip correction factor (Cc) affects the single fiber efficiency and the most penetrating particle size (MPPS). Therefore, for accurate estimation, Cc is essential to be considered. However, many previous studies have neglected this factor because of its complexity and the associated difficulty in deriving the appropriate parameterization particularly for the MPPS. In this study, the expression for the MPPS, and the corresponding expression for the minimum single fiber efficiency are analytically derived, and the effects of Cc are determined. In order to accommodate the slip factor for all particle-size ranges, Cc is simplified and modified. Overall, the obtained analytical expression for the MPPS is in a good agreement with the exact solution.

Numerical Assessment for Coastal Water Purification Utilizing a Tidal Jet System (조석분류를 이용한 연안해역의 수질정화에 관한 수치적 평가)

  • Park, Jong-Chun
    • Journal of Ocean Engineering and Technology
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    • v.20 no.4 s.71
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    • pp.58-63
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    • 2006
  • When the costal zone surrounded by a breakwater has a narrow vertical opening, currents in the vicinity of a narrow entrance can result in a jet flow, coinciding with the tide. Such a Tidal-Jet Generator(TJG) can change the water mass distribution and transport processes in the domain of influence of the jet. Also, it can decrease the residual time of them. In the present study, the water purification utilizing tidal jets in the coastal zone over constant bathymetry are estimated numerically, using a finite-difference numerical scheme, named the NS-MAC-TIDE method, which isbased on the fully 3D Navier-stokes(NS) equations. The shear velocity near the inlet of the TJG are predicted from the flow field simulation, and are assessed qualitatively with the development of scouring or sediment that is caused by the change of diffusion or sweeping flowup from the seabed of sediment particles. Finally, through solving a transport equation of concentration, the residual time related on mass transport processes and the flushing mechanism for water purification are investigated.

A Flexible Feature Matching for Automatic face and Facial feature Points Detection (얼굴과 얼굴 특징점 자동 검출을 위한 탄력적 특징 정합)

  • 박호식;손형경;정연길;배철수
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.05a
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    • pp.608-612
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    • 2002
  • An automatic face and facial feature points(FFPs) detection system is proposed. A face is represented as a graph where the nodes are placed at facial feature points(FFPs) labeled by their Gabor features md the edges are describes their spatial relations. An innovative flexible feature matching is proposed to perform features correspondence between models and the input image. This matching model works likes random diffusion process in the image spare by employing the locally competitive and globally corporative mechanism. The system works nicely on the face images under complicated background, pose variations and distorted by facial accessories. We demonstrate the benefits of our approach by its implementation on the fare identification system.

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Bulk Flow Pulsations and Film Cooling from Two Rows of Staggered Holes : Effect of Blowing Ratios (주유동의 맥동과 엇갈린 2열 분사홀로부터의 막냉각 : 분사비의 영향)

  • Sohn, Dong Kee;Lee, Joon Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.9
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    • pp.1195-1207
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    • 1998
  • Periodic pulsations in the static pressure near turbine surfaces as blade rows move relative to each other is one of the important sources of turbine unsteadiness. The present experiment aims to investigate the effect of the static pressure pulsations on the interaction of film coolant flows from two rows of staggered holes with mainstream and its effect on film cooling heat transfer. Potential flow pulsations are generated by the rotating shutter mechanism installed downstream of the test section, The free-stream Strouhal number based on the boundary layer thickness is in the range of 0.033 - 0.33, and the amplitude of about 10-20%. Measured are time-averaged and phase-averaged velocity variations, pressure variations and temperature distributions of the flow field. Experimental conditions are identified by boundary layer measurements. Injectant behavior is characterized by the measurements of unsteady pressure in the plenum chamber and free-stream static pressure. The film cooling effectiveness is evaluated from the insulated wall temperature measurement. It has been found that bulk flow pulsation provides very large diffusion of the injectants and the effectiveness is significantly reduced by the flow pulsations.