• Membrane Journal
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• v.7 no.1
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• pp.1-10
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• 1997

A review is presented for various gas transport mechanisms through microporous membranes of both polymeric and inorganic materials. Different transport modes manifest depending on the pore size and the flow regime, which is a function of pressure, temperature, and the interaction between gas molecules and the pore walls. For microporous membranes whose pores are small and the internal surface area huge, the surface diffusion becomes a significant factor. If the pores become even smaller, then the transport mechanism will be more of an activated diffusion type. When conditions are right capillary condensation will take place to create an enormous capillary pressure gradient, which will greatly enhance the permeation flux. At the same time the capillary condensate of the heavier component may block the membrane pores denying the passage of the lighter gas molecules. All of these phenomena will influence the separation of mixtures.

• Journal of the Korean Society of Combustion
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• v.9 no.4
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• pp.9-21
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• 2004

Stability of laminar premixed planar flames inclined in the gravitational field is asymptotically examined. The flame structure is resolved by a large activation energy asymptotics and a long wave approximation. The coupling between hydrodynamics and diffusion processes is included and near-unity Lewis number is assumed. The results show that as the flame is more inclined from the horizontal plane it becomes more unstable due to not only the decrease of stabilizing effect of gravity but also the increase of destabilizing effect of rotational flow. The obtained dispersion relation involves the Prandtl number and shows the destabilizing effect of viscosity. The analysis predicts that the phase velocity of unstable flame wave depends on not only the flame angle but also the Lewis number. For relatively short wave disturbances, still much larger than flame thickness, the most unstable wavelength is nearly independent on the flame angle and the flame can be stabilized by gravity and diffusion mechanism.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.4
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• pp.355-362
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• 2001

Adsorption isotherms of dichloromethane and 1, 1, 2-trichloro-1,2,2-trifluoroethane on an activated carbon pellet, Norit B4, were studied. For these chemicals, Sips equation gave the best fit for the single component adsorption isotherm. The adsorption affinity on activated carbon was greater for dichloromethane than that of 1, 1, 2-trichloro-1,2,2-trifluoroethane. An experimental and theoretical study was made for the adsorption of dichloromethane and 1, 1,2-trichloro-1,2,2-trifluoroethane in a fixed bed. Experimental results were used to examine the effect of operation variables, such as feed concentration, flow rate and bed height. Intraparticle diffusion was able to be explained by surface diffusion mechanism. An adsorption model baked on the linear driving force approximation (LDFA) was found to be applicable to fit the experimental data.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.113-122
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• 2000

Dynamic structures of unsteady $CH_4$/Air jet diffusion flames with flame-vortex interaction were numerically investigated. A time-dependent, axisymmetric computational model was adopted for this calculation. Two step global reaction mechanism which considers 6 species, was used to calculate the reaction rates. The predicted results including gravitational effect show that the large outer vortices and the small inner vortex street can be well simulated without any additional disturbances in the downstream of nozzle tip. It was found that the temperature and species concentrations had various values for the same mixture fraction in flame-vortex interaction region. This unsteady jet flame configuration accompanying flame-vortex interaction is expected to give good implications for the structure of turbulent flames.

• 한국연소학회:학술대회논문집
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• 2001.11a
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• pp.35-41
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• 2001

A second-order conditional moment closure(CMC) model is applied to the prediction of local extinction in a turbulent hydrocarbon diffusion flame and compared with direct numerical simulation(DNS) results for the flame. Combustion of a hydrocarbon fuel is described by a simple two-step mechanism. A second-order correction for conditional mean reaction rate terms is made by the assumed pdf method. The results show that the second-order closure is necessary for accurate prediction of intermediate species, while first-order CMC gives good predictions for fuel, oxidant, product and temperature. Conditional variances and covariances are well predicted during an extinction process while they are overpredicted during a reignition process.

• Journal of Welding and Joining
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• v.13 no.4
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• pp.147-154
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• 1995

In order to study the bonding mechanism of Ni/B/Ni transient liquid phase bonding system, width of liquid layers were calculated, where in this system melting point of insert material(B) is higher than bonding temperature and melting point of base metal(Ni). Caclulated values were compared with experimental ones which were measured by bonding Ni/B/Ni system at 1433-1474K under vacuum atmosphere. As results, the width of initial liquid layer of Ni/B/Ni system was calculated as $W_{IL}$ = $W_{o}$[1 + {2.100..rho.$_{S/}$ ( $X_{3}$ + $X_{4}$)..rho.$_{Ni}$ }-.rho.$_{S/}$.rho. Ni/], and it was nearly same with experimental values. Maximum width of liquid layer, width of liquid layer during isothermal solidification and isothermal solidification time were calculated also.o.o.o.

• Journal of Welding and Joining
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• v.15 no.2
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• pp.43-53
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• 1997

The complete joining method for dissimilar press punch materials and its real-time evaluation method is not available at present. Brazing method has been used for joining them, but it is known that the welded joint by the brazing has the lower bonding efficiency and reliability than the diffusion welding. The friction welding with a diffusion mechanism in bonding was applied in this study. This work was carried out to determine the proper friction welding conditions and to analyze mechanical properties of friction welded joints of sintered carbide tool materials (SKNM50 for the blade part of press punch) to alloy steel (SCM440 for the shank part of press punch) using aluminum (A6061 for the interlayer material) as an insert material between the sintered carbide tool materials and the alloy steel. In addition, acoustic emission test was carried out during friction welding to evaluate the weld quality.

• Membrane Journal
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• v.3 no.3
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• pp.108-116
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• 1993

In PVC/PS pelyblend laminated membranes, perrneabilities were increased as increasing the blend ratio of PS and selectivities were increased with increasing the blend ratio of PVC. The gas permeation mechanism was shifted from the combination of Poiseuille and Knudsen flow model to the solution-diffusion model as decreasing the PS blend ratio. The structure of polyblend laminated membranes showed series model, where PS rich phase was formed at air side and PVC rich phase was at water side. The model of permeation in the polyblend laminated membranes also showed series model structure.

• Proceedings of the Membrane Society of Korea Conference
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• 1995.09a
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• pp.1-13
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• 1995

A review is presented for various gas tranport mechanisms through microporous membranes of both polymeric and inorganic materials. Different transport modes manifest depending on the pore size and the flow regime, which is a function of pressure, temperature, and the inateraction between gas molecules and the pore walls. For microporous membranes whose pores are small and the intenal surface area huge, the surface diffusion becomes a significant factor. If the pores become even smaller, them the transport mechanism will be more of an activated diffusion type. When conditions are right capillary condensation will take place to create an enormous capillary pressure gradient, which will greatly enhance the permeation flux. At the same time the capillary condensate of the heavier component may block the membrane pores denying the passage of the lighter gas molecules. All of these phenomena will influence the separation of mixtures.

• Carbon letters
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• v.9 no.2
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• pp.121-126
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• 2008

High modulus pitch based carbon fibers (HM) were exposed to isothermal oxidation using tube furnace in carbon dioxide gas to study the oxidation kinetics under the temperature of $800-1100^{\circ}C$. The kinetic equation $f=1-{\exp}(-at^b)$ was introduced and the constant b was obtained in the range of 1.02~1.42. The oxidation kinetics were evaluated by the reaction-controlling regime (RCR) depending upon the apparent activation energies with the conversion increasing from 0.2 to 0.8. The activation energies decrease from 24.7 to 21.0 kcal/mole with the conversion increasing from 0.2 to 0.8, respectively. According to the RCR, the reaction was limited by more diffusion controlling regime for the HM fibers with the conversion increasing. Therefore, it seems that the oxidation which is under the diffusion controlling regime takes place continuously from the skin to the core of the fiber.