• Title/Summary/Keyword: diffusion mechanism

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CALCULATION OF HYDRODYNAMIC CHARACTERISTICS FOR SHIP'S PROPULSION MECHANISM OF WEIS-FOGH TYPE (Weis-Fogh형 선박추진기구의 유체역학적 특성계산)

  • Ro K.D.;Kang M.H.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.10a
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    • pp.305-310
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    • 2005
  • The velocity and pressure fields of a ship's propulsion mechanism of the Weis-Fogh type, in which a airfoil moves reciprocally in a channel, are studied in this paper using the advanced vortex method. The airfoil and the channel are approximated by a finite number of source and vortex panels, and the free vortices are introduced from the body surfaces. The viscous diffusion of fluid is represented using the core-spreading model to the discrete vortices. The velocity is calculated on the basis of the generalized Biot-Savart low and the pressure field is calculated from integrating the equation given by the instantaneous velocity and vorticity fields. Two-dimensional unsteady viscose flows of this propulsion mechanism are numerically clarified, and the calculated results agree well with the experimental ones.

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Mechanism of Action of Various Vehicles That Enhance the Permeation of Ketoprofen (케토프로펜의 피부투과도를 증진시키는 다양한 용매의 작용기전)

  • Cho, Young-Joo;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
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    • v.28 no.3
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    • pp.165-169
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    • 1998
  • The effect of various vehicles on the permeation of a model drug, ketoprofen in solution formulation was evaluated using a flow-through diffusion cell system at $37^{\circ}C$. To investigate the mechanism of permeation rate enhancement, the effects of pretreatment with various vehicles on the permeation of the drug were evaluated using 5 mg/ml solution and saturated solution. The order of permeation rate of ketoprofen across hairless mouse skin after pretreatment with various vehicles was similar to the case where the vehicles and the drug were coadministered except ethanol and oleic acid. The results indicate that the mechanism of enhancement can be direct action of the vehicles on the barrier property of the skin and/or carrier mechanism.

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Deformation Mechanism Map of Nanocrystalline Metallic Materials (나노결정립 금속재료의 변형기구지도)

  • Yoon, S.C.;Bok, C.H.;Kwak, E.J.;Kim, H.S.
    • Transactions of Materials Processing
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    • v.16 no.6
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    • pp.473-478
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    • 2007
  • In this study, a deformation mechanism map of metallic nanocrystalline materials(NCMs) using the phase mixture model is proposed. It is based on recent modeling that appears to provide a conclusive description of the phenomenology and the mechanisms underlying the mechanical properties of NCMs. The proposed models adopted the concept of a 'phase mixture' in which the grain interior and the grain boundaries are treated as separate phases. The volume fraction of this grain boundary 'phase' may be quite appreciable in a NCM. Based on the theoretical model that provides an adequate description of the grain size dependence of plasticity covering all grain size range from coarse down to the nanoscale, the tensile deformation response of NCMs, especially focusing on the deformation mechanisms was investigated. The deformation mechanism map is newly proposed with axes of strain rate, grain size and temperature.

Growth of SiC Nanotube by SLS (Solid-Liquid-Solid) Growth Mechanism (SLS(Solid-Liquid-Solid) 성장기구에 의한 탄화규소 나노튜브의 성장)

  • Rho Dae-Ho;Kim Jae-Soo;Byun Dong-Jin;Yang Jae-Woong;Kim Na-Ri
    • Korean Journal of Materials Research
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    • v.14 no.2
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    • pp.83-89
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    • 2004
  • SiC nanotubes were synthesized by SLS growth mechanism using various metal catalysts. Synthesized nanotubes had mean diameters of 20~50 nm and several $\mu\textrm{m}$ length. The kind of catalysts affected microstructures of SiC nanotubes by different diffusion routes. These differences are attributed to catalysts' physical properties and relative activities to the graphite substrate. Fe acted as a good catalyst of SLS growth mechanism. But in case of Ni, SiC nanotubes grew slowly. Optical property was measured by photoluminescence measurement. Relatively broad peak was obtained and mean peak positioned at about 430 nm. This result was the same as other nanocrystalline SiC materials, but was different from the results of bulk SiC probably due to quantum confinement effect and defect in the grown SiC nanotube.

Forming Mechanism of TiC Hollow Fibers during Self-Propagating High Temperature Synthesis (자전연소합성 반응중 속빈 TiC 섬유의 형성 기구)

  • 윤존도;방환철
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.332-337
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    • 2000
  • Forming mechanism of fibrous TiC during self-propagating high temperature synthetic reaction was analyzed and suggested. It was revealed that critical temperature for the stable fiber formation was not the melting point of TiC, but the eutectic reaction temperature of TiC and C. Minimum amount of TiC diluent addition required to form fibers was calculated to be 25.6%, which was consistent with the experimental result. Synthesized fibers were found hollow tube-like. The morphology was explained by the diffusion rates of C and Ti in TiC, and by the molar volume chnage of C during the reaction. Expanding shell model was suggested for the hollow fiber formation mechanism.

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Contribution of Hydrophobic Interactions to HubWA Folding Reaction (소수성 상호작용이 HubWA 단백질의 폴딩 반응에 끼치는 영향)

  • Park, Soon-Ho
    • Journal of the Korean Chemical Society
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    • v.63 no.6
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    • pp.427-434
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    • 2019
  • The role of hydrophobic residues on protein folding reaction was studied by folding kinetics measurements in conjunction with protein engineering. The HubWA, which was derived from human ubiquitin by mutating the residues at 45 (Phe to Trp) and 26 (Val to Ala), was used as a mutational background. Fourteen hydrophobic residues were mutated to alanine. Among fourteen variants generated, only four variant proteins (V5A, I13A, V17A, and I36A) were suitable for folding study. The folding kinetics of these variants was measured by stopped-flow fluorescence spectroscopy. The folding kinetics of HubWA and V17A was observed to follow a three-state on-pathway mechanism. On the other hand, folding kinetics of V5A, I13A, and I36A was observed to follow a two-state mechanism. Based on these observations, transition of protein folding reaction from collision-diffusion mechanism to nucleation-condensation mechanism was discussed.

Experimental Study on Combustion Noise Characteristics in Turbulent Jet Diffusion Flames (난류 제트확산화염의 연소소음 특성에 관한 실험연구)

  • 김호석;오상헌
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.5
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    • pp.1253-1263
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    • 1994
  • The experimental study is carried out to identify the combustion generated noise mechanism in free turbulent jet diffusion flames. Axial mean fluctuating velocities in cold and reacting flow fields were measured using hot-wire anemometer and LDv.The overall sound pressure level and their spectral distribution in far field with and without combustion were also measured in an anechoic chamber. The axial mean velocity is 10-25% faster and turbulent intensities are about 10 to 15% smaller near active reacting zone than those in nonreacting flow fields. And sound pressure level is about 10-20% higher in reacting flow fields. It is also shown that the spectra of the combustion noise has lower frequency characteristics over a broadband spectrum. These results indicate that the combustion noise characteristics in jet diffusion flames are dominated by energy containing large scale eddies and the combusting flow field itself. Scaling laws correlating the gas velocity and heat of combustion show that the acoustic power of the combustion noise is linearly proportional to the 3.8th power of the mean axial velocity rather than 8th power in nonreacting flow fields, and the SPL increases linearly with logarithmic 1/2th power of the heat of combustion.

THE METHOD OF NONFLAT TIME EVOLUTION (MONTE) IN PDE-BASED IMAGE RESTORATION

  • Cha, Youngjoon;Kim, Seongjai
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.37A no.11
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    • pp.961-971
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    • 2012
  • This article is concerned with effective numerical techniques for partial differential equation (PDE)-based image restoration. Numerical realizations of most PDE-based denoising models show a common drawback: loss of fine structures. In order to overcome the drawback, the article introduces a new time-stepping procedure, called the method of nonflat time evolution (MONTE), in which the timestep size is determined based on local image characteristics such as the curvature or the diffusion magnitude. The MONTE provides PDE-based restoration models with an effective mechanism for the equalization of the net diffusion over a wide range of image frequency components. It can be easily applied to diverse evolutionary PDE-based restoration models and their spatial and temporal discretizations. It has been numerically verified that the MONTE results in a significant reduction in numerical dissipation and preserves fine structures such as edges and textures satisfactorily, while it removes the noise with an improved efficiency. Various numerical results are shown to confirm the claim.

Diffusion-flame instability in the premixed-flame regime (예혼합화염 영역에서 확산화염의 불안정성에 관한 연구)

  • Lee, Su-Ryong;Kim, Jong-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.9
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    • pp.1218-1229
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    • 1997
  • The diffusional-thermal instability of diffusion flames in the premixed-flame regime is studied in a constant-density two-dimensional counterflow diffusion-flame configuration, to investigate the instability mechanism by which periodic wrinkling, travelling or pulsating of the reaction sheet can occur. Attention is focused on flames with small departures of the Lewis number from unity and with small values of the stoichiometric mixture fraction, so that the premixed-flame regime can be employed for activation-energy asymptotics. Cellular patterns will occur near quasisteady extinction when the Lewis number of the more completely consumed reactant is less than a critical value( ~ =0.7). Parametric studies for the instability onset conditions show that flames with smaller values of the Lewis number and stoichiometric mixture fraction and with larger values of the Zel'dovich number tend to be more unstable. For Lewis number greater than unity, near-extinction flame are found to exhibit either travelling instability or pulsating instability.

Characteristics of W-C-N Thin Diffusion Barrier for Cu Interconnection (Cu 금속배선을 위한 카본-질소-텅스텐 확산방지막 특성)

  • Lee, Chang-Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.4 s.37
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    • pp.345-349
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    • 2005
  • Low resistive ($300{\mu}{\Omega}$-cm) W-C-N films have been deposited on tetraethylorthosilicate (TEOS) interlayer dielectric by atomic layer deposition (ALD) with $WF_6-N_2-CH_4$ gas. The exposure cycles of $N_2$ and $CH_4$ are synchronized with pulse plasma. The W-C-N films on TEOS layer follow the ALD mechanism and keep constant deposition rate of 0.2 nm/cycle from 10 to 100 cycles. As a diffusion barrier for Cu interconnection the W-C-N films maintain amorphous phase and Cu inter-diffusion is not occurred even at $800^{\circ}C$ for 30 min.

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