• Title/Summary/Keyword: diffusion mechanism

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Coherent Precipitation of $Zn_3P_2$ During Zn Diffusion in a GaInAsP/InP Heterostructure (GaInAsP/InP 이종구조에서 Zn 확산에 의한 $Zn_3P_2$의 정합석출)

  • 홍순구;이정용;박효훈
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.206-214
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    • 1993
  • Coherent precipitation of Zn3P2 during Zn diffusion in a GaInAsP/InP heterostructure was studied using high-resolution transmission electron microscopy. Zn-diffusion-induced intermixing of Ga and In across the GaInAsP/InP heterointerface provided a Ga-mixed InP region which was nearly lattice-matched with Zn3P2 crystal and thus allowed thecoherent precipitation of Zn3P2. The Zn3P2 precipitates were preferentially nucleated at stacking faults which were formed to relax interfacial strain built up by the intermixing. The precipitates were grown to planar epitaxial layer along (100) plane in the lattice-matched region. The TEM images and diffraction pettern revealed that the tetragonal Zn3P2 crystals were coherently matched to the fcc structured GaInP matrix by the {{{{ SQRT {2} $\times$ SQRT {2} $\times$2 }} arrangement. The precipitation reaction of Zn3P2 was explained by an atomic migration model based on the kick-out mechanism.

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Physical Property Models and Single Cells Analysis for Solid Oxide Fuel Cell (고체산화물 연료전지를 위한 물성치 모델 및 단전지 해석)

  • Park, Joon-Guen;Kim, Sun-Young;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.379-381
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    • 2009
  • The simulation model for metal-supported Solid Oxide Fuel Cell(SOFC) is developed in this study. Open circuit voltage is calculated using Nernst equation and Gibbs free energy is required by thermodynamic. The exchange current densities are compared with experimental results since exchange current density is most effective factor for the activation loss. Liu's study is used for the exchange current density of cathode, BSCF, and Koide's result is applied for the exchange current density of anode, Ni/YSZ. For the ohmic loss, ionic conductivity of YSZ is described from Kilner's mode and the data are compared with Wanzenberg's experimental data. Diffusivity is an important factor for the mass transfer through the porous medium. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results.

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Rates and Mechanism of Adsorption of Transition Metal Ions on Polystyrene Resins Supported Diethylenetriamine (디에틸렌트리아민을 지지시킨 폴리스틸렌수지에 대한 전이금속이온의 흡착속도와 메카니즘)

  • Kim, Sun-Deuk;Shin, Yun-Yeol;Kim, Chang-Su
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.465-471
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    • 1999
  • Chloromethylated polystyrene resins supported diethylenetriamine of linear and claw types have been prepared by the reaction of diethylenetriamine with chloromethylated polystyrene. The kinetics of adsorption of transition metal ions on polystyrene resins were measured by the limited-bath technique. This paper reports the results of the diffusion coefficients, entropies of activation, and free energies of activation. The ratedetermining step of the adsorption of transition metals on the resins is a process of diffusion through the particles.

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A Numerical Study on the Dynamic Behaviors of Single Vortex in a $CH_4/Air$ Diffusion Flame with Addition of $CO_2$ ($CH_4/Air$ 확산화염에 $CO_2$ 첨가에 따른 단일 와동의 동적 거동에 관한 수치해석)

  • Hwang, Chul-Hong;Oh, Chang-Bo;Lee, Dae-Yup;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2002.06a
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    • pp.68-75
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    • 2002
  • The dynamic behaviors of the single vortex and flame-vortex interaction in a $CH_4/Air$ diffusion flame with addition of $CO_2$ were investigated numerically. The numerical method was based on a predictor-corrector for low Mach number flow. A two-step global reaction mechanism was adopted as a combustion model. Through comparison of results by effect of $CO_2$ added either on the fuel or oxidizer side, it was found that the growth of single vortex and entrainment of surrounding fluid by $CO_2$addition on the fuel side are larger than those by $CO_2$ addition on oxidizer side. Also, when $CO_2$ is added on fuel side, flame-vortex interaction becomes more significant than on air side.

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Solute Transport in Rock Fractures

  • Yeo, In-Wook
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.89-92
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    • 2001
  • This study aims at investigating the relationship between dispersion coefficient ratio to molecular diffusion coefficient (D$_{l}$ /D$_{m}$) and Peclet number (Pe) for multi-solute system in non-Darcian flow regime. Existing understanding on solute dispersion is primarily derived from one-solute system in Darcian flow regime. We found that solute dispersion in rock fractures can be characterized by the mechanism of both macrodispersion and Taylor dispersion, even for non-Darcian f]ow domain. For the Darcian flow regime even different solutes lead to the same D$_{l}$ /D$_{m}$ at same Pe. However, as the flow becomes non-Darcian, solute with a higher molecular diffusion coefficient result in higher D$_{l}$ /D$_{m}$ at tile same Pe than that with a lower diffusion coefficient.cient.

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An experimental study on the evaluation of chloride attack resistance in mortar and concrete mixed with pozzolanic admixtures (포졸란계 혼화재를 혼입한 모르타르 및 콘크리트의 내염해 저항성 평가에 관한 실험적 연구)

  • 박정준;김도겸;하진규
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.461-466
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    • 2000
  • To improve the quality of concrete, we usually consider the reduction of water/cement ratio, the increase of concrete cover depth and the use of mineral admixtures. Reportedly, the use of admixtures make concrete more durable and tighten against water. But, it is needed to study more about the relationship between the admixtures and the chloride ion diffusion. Therefore, in this study, we focused on the chloride ion diffusion properties of the pozzolanic admixtures such as fly-ash, slag and silica fume which are known as being useful on chloride attack resistance when mixed into mortar or concrete. Furthermore, we treed to analyze the correlation between mortar and concrete using the admixture, which is useful for analyzing chloride ion diffusion mechanism.

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Low Temperature diffusion by Ion Collisions (이온 충돌에 의한 저온 확산)

  • 이희용
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.11 no.1
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    • pp.33-39
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    • 1974
  • A method of dopant implantation by low temperatme diffusion with ion collisions as well as the mechanism of its apparatus is to be introduced. The implantillg function is mainly based on the Principle of radiation enhanced diffusion due to the collisions of low energy Particles and the preheating of the substrate in an environment of rarefied air plasma. The implanted results of various dopants into semicondctors by the Implanter are also presented.

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FINITE ELEMENT MODEL TO STUDY TWO DIMENSIONAL UNSTEADY STATE CYTOSOLIC CALCIUM DIFFUSION

  • Tewari, Shivendra Gajraj;Pardasani, Kamal Raj
    • Journal of applied mathematics & informatics
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    • v.29 no.1_2
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    • pp.427-442
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    • 2011
  • Calcium is a vital second messenger for signal transduction in neurons. Calcium plays an important role in almost every part of the human body but in neuronal cytosol, it is of utmost importance. In order to understand the calcium signaling mechanism in a better way a finite element model has been developed to study the flow of calcium in two dimensions with time. This model assumes EBA (Excess Buffering Approximation), incorporating all the important parameters like time, association rate, influx, buffer concentration, diffusion constant etc. Finite element method is used to obtain calcium concentration in two dimensions and numerical integration is used to compute effect of time over 2-D Calcium profile. Comparative study of calcium signaling in two dimensions with time is done with other important physiological parameters. A MATLAB program has been developed for the entire problem and simulated on an x64 machine to compute the numerical results.

The Role of Grain Boundary Diffusion in the Activated Sintering of Tungsten Powder (텅스텐 활성소결에서 입계확산의 역할)

  • 이재성
    • Journal of Powder Materials
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    • v.1 no.1
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    • pp.79-84
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    • 1994
  • The mechanism of activated sintering of tungsten powder was discussed in terms of diffusion and segregation of activator atoms at W grain boundaries. Shrinkage behaviours of W-0.2wt.% Ni, W-0.2wt.% Cu or pure W powder compacts during sintering at low temperatures of 900~ $1200^{\circ}C$ were investigated. It was found that the Cu additive inhibits sintering process causing lower densification than pure W compact while remarkable shrinkage occurred in the Ni added W powder. Such contrary effect was explained by comparing self diffusion processes along Ni or Cu segregated W boundaries in which Ni segregants enhance but Cu atoms retard the migration of W atoms at W boundaries.

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The Analysis on the Roles of Patents, Standards, and Licensing as Technology Diffusion Media for Technology Innovation (기술혁신을 위한 기술확산매체로서의 특허와 표준, 그리고 라이센싱의 역할 분석)

  • 이상무
    • Proceedings of the Technology Innovation Conference
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    • 1999.06a
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    • pp.226-244
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    • 1999
  • Very closely related to technologies, patents, standards, and licensing interact with them, cores of technology innovation, as the technology diffusion media for technology innovation. Todays it is usually impressed that no one can face to international technology competetion environment without the strategy of patent, standardization, and licensing. In this paper, the whole configuration of technology innovation is represented including the patent, standard, licensing as these media, their basic characteristics and how they roles as technology diffusion media interacting with the technology, core of the technology innovation configuration are analyzed, and some related practical cases to be understood as the applications of these three media for technology innovation are also explained : such as IMT-2000 and CDMA technology which have been international issues currently involved in patents and standardization together, the advent of Linux operating system being the new event in the field of computer technology. Finally this paper intends to have the implicated meanings needed for national policy improvement, through appreciating the importance and the mechanism of roles of three media factors for technology innovation.

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