• Title/Summary/Keyword: diffusion

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Effect of Curing Conditions on the Characteristics of Chloride Ion Diffusion in Concrete (콘크리트의 염소이온 확산특성에 미치는 양생조건의 영향)

  • 임병탁;배수호;정영수;심은철;하재담
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.715-720
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    • 2003
  • The chief factors for the penetration and diffusion of chloride ions in concrete are water-cement ratio(W/C), aging, curing conditions, chloride ions concentration of given environment., wet and dry conditions and etc. In this study, of these factors effect of curing conditions such as standard and outdoor curing on the characteristics of chloride ions diffusion in concrete were researched when environmental factors for the penetration and diffusion of chloride ions were constant. For this purpose, the voltages passing through the diffusion cell were measured by using accelerated test method using potential difference, and then diffusion coefficients of chloride ions by using Andrade's method were estimated for 44%, 49.5% and 60% of w/c, respectively. As a result., according to curing conditions correlation among diffusion coefficients of chloride ions, W/C and aging were concluded through multiple regression model.

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A WSR-88D Radar Observation of Chaff Transport and Diffusion in Clear Sky

  • Lee, Dong-In
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.263-271
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    • 2000
  • To investigate the distribution of air pollutants dispersion in the horizontal wind fields, a chaff release experiment was carried out by an airplane. The temporal and spatial variations of a chaff plume from an elevated point source using the WSR-88D(NEXRAD) radar. The observed profiles of radar reflectivity were compared with the Gaussian diffusion model at slightly unstable atmospheric condition. The present study shows that the distributions of radar reflectivity from chaffs and their concentration by the model are in general agreement with time variation. The dispersion coefficients in downwind($\sigma$(sub)x) and crosswind($\sigma$(sub)y) spread data exceeded what has generally been found at Pasquill and Brigg\`s estimates. As a result, it was clearly shown that horizontal and vertical diffusion coefficients are more accurately determined as compared with theoretical coefficients. At longer diffusion distances(than 10km), a radar observation provided the determination of maximum range and diffusion height more qualitatively, too.

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Noise reduction method using mean curvature diffusion (평균곡률 확산을 이용한 잡음감소 기법)

  • Ye Chul-Soo;Chung Hun-Suk;Kim Seong-Jong;Hyun Deuk-Chang
    • 한국컴퓨터산업교육학회:학술대회논문집
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    • 2003.11a
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    • pp.87-94
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    • 2003
  • Anisotropic diffusion is a selective smoothing technique that promotes smoothing within a region instead of smoothing across boundaries. In anisotropic diffusion, the rate of smoothing is controlled by the local value of the diffusion coefficient chosen to be a function of the local image gradient magnitude. El-Fallah and Gary E. Ford represented the image as a surface and proved that setting the inhomogeneous diffusion coefficient equal to the inverse of the magnitude of the surface normal results in surface evolving speed that is proportional to the mean curvature of the image surface. This model has the advantage of having the mean curvature diffusion (MCD) render invariant magnitude, thereby preserving structure and locality. In this paper, the proposed MCD model efficiently reduces diffusion coefficient at the thin edges using the smoothness of the surface.

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Comparison of the Bass Model and the Logistic Model from the Point of the Diffusion Theory (확산이론 관점에서 로지스틱 모형과 Bass 모형의 비교)

  • Hong, Jung-Sik;Koo, Hoon-Young
    • Journal of the Korean Operations Research and Management Science Society
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    • v.37 no.2
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    • pp.113-125
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    • 2012
  • The logistic model and the Bass model have diverse names and formulae in diffusion theory. This diversity makes users or readers confused while it also contributes to the flexibility of modeling. The method of handling the integration constant, which is generated in process of deriving the closed form solution of the differential equation for a diffusion model, results in two different 'actual' models. We rename the actual four models and propose the usage of the models with respect to the purpose of model applications. The application purpose would be the explanation of historical diffusion pattern or the forecasting of future demand. Empirical validation with 86 historical diffusion data shows that misuse of the models can draw improper conclusions for the explanation of historical diffusion pattern.

A Study on Dependence of Smoke Emission in Diesel Engines Upon Diffusion Combustion (디젤기관의 스모크배출의 확산연소 의존성에 관한 연구)

  • 한성빈;문성수;이성열
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.2
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    • pp.397-404
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    • 1994
  • Smoke is emitted in diesel engines because fuel injected into the high-temperatured and high-pressured combustion chamber burns with its mixture with insufficient oxygeny. In consideration of air pollution, above all, it is necessary to illuminate the cause of smoke emission in diesel engines. The smoke emission, which is characteristic of diffusion combustion in diesel engines, results from pyrolysis of fuel not mixed with air. Therefore the smoke emission is dependent on diffusion combustion quantity, which is in turn controlled by engine parameter. The study aims at making clear and interpreting the interdependence of smoke emission in diesel engines with heat released within combustion chamber, camparing diffusion combustion quantity according to each engine parameter (air fuel ratio, injection timing, and engine speed), and showing the relation between smoke emission and fraction of diffusion combustion through experiment.

A Study on Diffusion Constant Measurement Using Light Reflectance within Biological Tissue (생체조직내에서 반사광을 이용한 확산 상수의 측정에 관한 연구)

  • 임현수
    • Journal of Biomedical Engineering Research
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    • v.17 no.2
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    • pp.227-234
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    • 1996
  • This paper is the study of the diffusion constant in order to calculate the percent oxygenation and percent blood volume using reflectance light within biological tissue. The diffusion constant play major role in percent oxygenation and percent blood volume and varies with the biological material such as hemolyzed blood, whole blood, dermis and epidermis in vivo tissue. The diffusion constant can be modeled to consist of a contribution from bloodless tissue and blood present in tissue. The reflectance light for experimental are red light of 660nm, infrared light of 880nm, green light of 569nm. The correlation between the diffusion constant and biological tissue was analyzed by the intensity of reflectance light at different depth within human limb. The reflectance light was changed in response to physiological changes within biological tissue. The data for diffusion constant were obtained at different depth beneath the surface of the skin and will be utilized to amen the percent oxygenation and percent blood volume.

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Analysis of the False Diffusion Effects in Numerical Simulation of Diesel Spray Impinging on Inclined Walls (경사진 벽충돌 디젤 분무에 대한 수치해석에서 오류확산이 미치는 영향)

  • Gwon, H.R.;Lee, S.H.
    • Journal of ILASS-Korea
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    • v.13 no.1
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    • pp.22-27
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    • 2008
  • The false diffusion occurs generally when the flow is oblique to the grid lines and when there is a non-zero gradient of the dependent variable in the direction normal to the flow. This numerical problem can overestimate diffusion terms in the continuous phase, causing the numerical inaccuracy for the simulation of impinging sprays on inclined walls because most of spray calculation uses rectangular grid system. Therefore, the main objective of this article is to investigate numerically the influence of false diffusion on numerical simulation for spray-wall impingement on inclined walls. It is found that unlike the spray impingement normal to the wall, the numerical diffusion exists in the case when diesel sprays impinge on the inclined walls with different angles. The results show that the correction function should be considered for accurate prediction of spray penetration length and more elaborate numerical schemes should be utilized to reduce the false diffusion.

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Estimating Diffusion-Controlled Reaction Parameters in Photoinitiated Polymerization of Dimethacrylate Macromonomers

  • Choe, Youngson
    • Macromolecular Research
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    • v.11 no.5
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    • pp.311-316
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    • 2003
  • The kinetics of photoinitiated polymerization of dimethacrylate macromonomers have been studied to determine the diffusion-controlled reaction parameters using attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). A predicted kinetic rate expression with a diffusion control factor was employed to estimate an effective rate constant and to define the reaction-controlled and diffusion-controlled regimes in the photopolymerization. An effective rate constant, k$_{e}$, can be obtained from the predicted kinetic rate expression. At the earlier stages of polymerization, the average values of kinetic rate constants do not vary during the reaction time. As the reaction conversion, $\alpha$, reaches the critical conversion, $\alpha$$_{c}$, in the predicted kinetic expression, the reaction becomes to be controlled by diffusion due to the restricted mobility of dimethacrylate macromonomers. A drop in value of effective rate constant causes a drastic decrease of reaction rate at the later stages of polymerization. By determining the effective rate constants, the reaction-controlled and diffusion-controlled regimes were properly defined even in the photopolymerization reaction system.m.m.

A Study on the Diffusion Barrier Properties of Pt/Ti and Ni/Ti for Cu Metallization (구리 확산에 대한 Pt/Ti 및 Ni/Ti 확산 방지막 특성에 관한 연구)

  • 장성근
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.2
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    • pp.97-101
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    • 2003
  • New Pt/Ti and hi/Ti double-metal structures have been investigated for the application of a diffusion barrier between Cu and Si in deep submicron integrated circuits. Pt/Ti and Ni/Ti were deposited using E-beam evaporator at room temperature. The performance of Pt/Ti and Ni/Ti structures as diffusion barrier against Cu diffusion was examined by charge pumping method, gate leakage current, junction leakage current, and SIMS(secondary ion mass spectroscopy). These evaluation indicated that Pt/Ti(200${\AA}$/100${\AA}$) film is a good barrier against Cu diffusion up to 450$^{\circ}C$.

On the Chemical Diffusion Coefficient of H2O in AB1-xBxO(3-x/2)-type Perobskites

  • Baek, Hyun-Deok;Virkar, Anil V.
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.827-831
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    • 2003
  • In proton-conducting perovskites, oxygen ions and protons make a diffusion pair for a chemical diffusion and thus lead to the transport of $H_2O$ under its chemical potential gradient. The present manuscript develops relationships between the chemical diffusion coefficient of $H_2O$ and the diffusion coefficients of protons and oxygen vacancies with an emphasis on the thermodynamic behavior of the oxygen vacancies. Depending on the degree of hydration X, two different expressions of the chemical diffusion coefficient were obtained : equation omitted and equation omitted.