• Journal of Pharmaceutical Investigation
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• 제23권2호
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• pp.81-87
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• 1993

Five crystalline forms of cimetidine, four anhydrous and a monohydrate, have been prepared, and their thermal behavriours have been studied by differential thermal analysis and thermo-gravimetry. The dissolution rates of the five forms were determined in distilled water at $37^{\circ}C$. The results showed a significant difference in the dissolution rate. Polymorphic transformation occurred spontaneously during storage at room condition and was accelerated by applied energy during formulation process-milling.

• 한국연소학회지
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• 제16권3호
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• pp.21-26
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• 2011

Thermal analyses are conducted to measure chemical kinetic parameters of an unknown liquid fuel with various components. Thermal Analyses are divided into two different methods such as TGA(Thermo-Gravimetric Analysis) and DSC(Differential Scanning Calorimety). Non-isothermal experimental results are analyzed by adopting TGA and they are filtered by Freeman-Carroll method. As a results of the analysis, chemical parameters of the activation temperature and the reaction order are measured to be 6128.2 K and 1.4, respectively. Furthermore, the chemical kinetic parameters are obtained by a variety of mathematical processing methods. It has been found that they show a little difference depending on the processing method.

• Bulletin of the Korean Chemical Society
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• 제22권4호
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• pp.367-371
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• 2001

Lithium inserted into artificial carbon has been synthesized as a function of the Li concentration. The characteristics of these prepared compounds were determined from the studies using X-ray diffraction(XRD), solid nuclear magnetic resonance (NM R) spectrophotometric and differential scanning calorimeter(DSC) analysis. X-ray diffraction showed that lower stage intercalation compounds were formed with increasing Li concentration. In the case of the AG3, most compounds formed were of the stage 1 structure. Pure stage 1 structural defects of artificial graphite were not observed. 7Li-NMR data showed that bands are shifted toward higher frequencies with increasing lithium concentration; this is because non-occupied electron shells of Li increased in charge carrier density. Line widths of the Li inserted carbon compounds decreased slowly because of nonhomogeneous local magnetic order and the random electron spin direction for located Li between graphene layers. The enthalpy and entropy changes of the compounds can be obtained from the differential scanning calorimetric analysis results. From these results, it was found that exothermic and endothermic reactions of lithium inserted into artificial carbon are related to the thermal stability of lithium between artificial carbon graphene layers.

• Computers and Concrete
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• 제31권2호
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• pp.139-149
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• 2023

This article investigates the statically analysis regarding the thermal buckling behavior of a nonuniform small-scale nanobeam made of functionally graded material based on classic beam theories along with the nonlocal Eringen elasticity. The material distribution of functionally graded structures is composed of temperature-dependent ceramic and metal phases in axial and thickness directions, called two-dimensional functionally graded (2D-FG). The partial differential (PD) formulations and end conditions are extracted by using to the conservation energy method. The porosity voids are assumed in the nonuniform functionally graded (FG) structure. The thermal loads are in the axial direction of the beam. The extracted nonlocal PD equations are also solved by employing generalized differential quadrature method (GDQM). Last but not least, the information acquired is used to produce miniature sensors, providing a unique perspective on the growth of nanoelectromechanical systems (NEMS).

• 공업화학
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• 제4권1호
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• pp.75-81
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• 1993

$Ni^{2+}-Faujasite$의 열화학적 안정성을 시차열분석(DTA), 열중량분석(TGA), X선 회절분석(XRD) 및 양자화학적 계산을 통해 고찰하였다. $Ni^{2+}-Faujasite$의 탈수현상은 373-773 K의 온도 구간에서 나타났다. 골격내 T자리를 표현하는 분자모델을 설정하여 전체 에너지와 Wiberg 결합차수를 CNDO/2 분자궤도법을 통해 계산하였다. 계산된 결과는 제올라이트의 결정성 감소가 골격내 Al-O결합의 약화에 직접적으로 연관되어 있음을 나타내었다.

• 한국잠사곤충학회지
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• 제49권2호
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• pp.77-80
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• 2007

실크단백질을 이용한 나노화 소재개발을 위한 기초연구의 일환으로 실크 피브로인과 PVP를 반응시켜 제조한 견단백질/PVP의 열 특성을 살펴보기 위하여 시차열분석 및 열중량분석을 행하였다. 1. PVP의 유리전이온도는 $175^{\circ}C$ 부근에서 관찰되었으며 실크 단백질과 반응에 의하여 영향을 받지 않았으나 견단백질/PVP는 $220^{\circ}C$ 부근에서 미지의 발열피크를 나타내었다. 2. 열중량 분석 결과 PVP의 함량이 증가함에 따라 실크 단백질에 기인한 열분해시작온도가 상대적으로 증가하는 것으로 관찰되었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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• pp.421-424
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• 2011

본 연구에서는 열분석법을 이용하여 혼합 액체연료의 수치해석에 필요한 여러 가지 인자를 측정하였다. 이러한 열분석법에는 열중량 분석방법(TGA, Thermo-Gravimetric Analyzer)과 시차 주사열량 측정법(DSC, Differential Scanning Calorimetry)이 있다. 열중량 분석방법을 통한 비등온 실험(non-isothermal experimental) 결과를 토대로 Freeman Carroll의 수학적인 후처리 방법을 이용하여 미지의 액체연료의 구성 성분에 대한 동역학적 변수인 활성화 온도와 반응차수로 각각 6128.2 K와 1.4를 얻었다. 그 외 다양한 수학적 처리 방법에 따른 동역학적 변수의 값을 구해보았고, 계산 결과는 처리방법에 따라 약간의 차이를 보였다.

• Advances in Computational Design
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• 제2권2호
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• pp.107-119
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• 2017

The Micro circular diaphragm (MCD) is the mechanical actuator part used in the micro electro-mechanical sensors (MEMS) that combine electrical and mechanical components. These actuators are working under harsh mechanical and thermal conditions, so it is very important to study the mechanical and thermal behaviors of these actuators, in order to do with its function successfully. The objective of this paper is to determine the thermo-mechanical behavior of MCD by developing the traditional bulge test technique to achieve the aims of this work. The specimen is first pre-stressed to ensure that is no initial deflection before applied the loads on diaphragm and then clamped between two plates, a differential pressure (P) and temperature ($T_b$) is leading to a deformation of the MCD. Analytical formulation of developed bulge test technique for MCD thermo-mechanical characterization was established with taking in-to account effect of the residual strength from pre-stressed loading. These makes the plane-strain bulge test ideal for studying the mechanical and thermal behavior of diaphragm in both the elastic and plastic regimes. The differential specimen thickness due to bulge effect to describe the mechanical behavior, and the temperature effect on the MCD material properties to study the thermal behavior under deformation were discussed. A finite element model (FEM) can be extended to apply for investigating the reliability of the proposed bulge test of MCD and compare between the FEM results and another one from analytical calculus. The results show that, the good convergence between the finite element model and analytical model.

• Structural Engineering and Mechanics
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• 제59권2호
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• pp.343-371
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• 2016

In this paper thermo-mechanical vibration analysis of a porous functionally graded (FG) Timoshenko beam in thermal environment with various boundary conditions are performed by employing a semi analytical differential transform method (DTM) and presenting a Navier type solution method for the first time. The temperature-dependent material properties of FG beam are supposed to vary through thickness direction of the constituents according to the power-law distribution which is modified to approximate the material properties with the porosity phases. Also the porous material properties vary through the thickness of the beam with even and uneven distribution. Two types of thermal loadings, namely, uniform and linear temperature rises through thickness direction are considered. Derivation of equations is based on the Timoshenko beam theory in order to consider the effect of both shear deformation and rotary inertia. Hamilton's principle is applied to obtain the governing differential equation of motion and boundary conditions. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of several parameters such as porosity distributions, porosity volume fraction, thermal effect, boundary conditions and power-low exponent on the natural frequencies of the FG beams in detail. It is explicitly shown that the vibration behavior of porous FG beams is significantly influenced by these effects. Numerical results are presented to serve benchmarks for future analyses of FG beams with porosity phases.

• Nuclear Engineering and Technology
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• 제49권8호
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• pp.1636-1644
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• 2017

The main purpose of this article is to describe the magnetohydrodynamic stagnation point flow of Walter-B nanofluid over a stretching sheet. The phenomena of heat and mass transfer are based on the involvement of thermal radiation and chemical reaction. Characteristics of Newtonian heating are given special attention. The Brownian motion and thermophoresis models are introduced in the temperature and concentration expressions. Appropriate variables are implemented for the transformation of partial differential frameworks into sets of ordinary differential equations. Plots for velocity, temperature, and nanoparticle concentration are displayed and analyzed for governing parameters. The skin friction coefficient and local Nusselt and Sherwood numbers are studied using numerical values. The temperature and heat transfer rate are enhanced within the frame of the thermal conjugate parameter.