• 대한원격탐사학회지
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• 제32권6호
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• pp.603-616
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• 2016

본 연구에서는 기상청 현업 국지기상모델(Local Data Assimilation and Prediction System, LDAPS)과 전산유체역학(Computational Fluid Dynamics, CFD) 모델을 접합하여, 서울 종로구 송월동에 위치한 지동기상관측소(서울 ASOS) 주변 지역의 기상 환경을 분석하였다. 토지 피복별 차등 가열이 도시 지역의 대기 흐름과 기온에 미치는 영향을 분석하기 위하여, 시간 변화에 따른 토지 피복별 지표면 온도와 그림자 영역에 대한 지표면 온도 감소 효과를 고려하였다. LDAPS 모델은 상세한 건물, 지형, 지표면 가열 효과를 고려하지 못하기 때문에, 풍속을 과대모의 하고 기온을 과소 모의하였다. 건물과 지형의 마찰 효과와 태양 복사에 의한 지표면 가열을 고려할 수 있는 LDAPS-CFD 접합 모델은 서울 ASOS 지점의 관측 풍속과 유사한 풍속을 모의하였고, 관측 기온을 잘 재현하였다. 주로 동풍이 부는 오전 시간대에는 LDAPS-CFD 접합 모델 또한 기온을 과소모의 하였는데, 이는 서울 ASOS 지점의 풍상측(동쪽)에 위치한 경희궁 주변 지역에 주로 수목이 분포하고 있고, 표면 온도가 상대적으로 낮기 때문인 것으로 판단된다. 그러나, 주로 남동풍 계열의 바람이 부는 오후 시간대에는 풍상측에 위치한 건물의 표면 가열의 효과로 인해 서울 ASOS 지점의 관측 기온을 상대적으로 잘 모의하였다.

• 세라미스트
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• 제10권3호
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• pp.67-74
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• 2007

Crystallisation kinetics of the erbium doped soda-tellurite glasses were studied using the differential thermal analysis (DTA) and differential scanning calorimetery (DSC) techniques. The DTA curves in the temperature range of 350 K to 650 K were obtained from isochronal heating rates, chosen in the range of 2 to 20 K/min. DSC isothermal curves were used to calculate the fraction of crystals formed on reheating. The apparent activation energies for devitrification were derived by measuring the shifts in the values of $T_g$ and $T_x$ with heating rates, using the Kissinger method. The derived values of apparent activation energies for isochronal and isothermal methods varied in the range of $190-204\;{\pm}\;5\;kJ\;mol^{-1}$. The X-ray powder diffraction analysis of heat treated and transparent samples showed the presence of nano-scale size sodium-tellurite crystals. These crystallites were found to have a strong influence on the full width of half maxima of the transition in $Er^{3+}:\;^4I_{13/2}{\rightarrow}^4I_{15/2}$, which extended from 70 nm in the vitreous materials to 132 nm in glass-ceramic materials.

• 한국안전학회지
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• 제17권2호
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• pp.39-44
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• 2002

This study was investigated the thermal decomposition characteristics of azo type sponge blowing agent azodicarbonamide(ADCA) using differential scanning calorimeter(DSC). The experimental results showed that the exothermic onset $temperatures(T_{o})$ for ADCA were about $201{\sim}206^{\circ}C$ and evolution heats(Q) were about $144{\sim}150cal/g$. The exothermic onset $temperatures(T_{o})$, exothermic maximum $temperature(T_{m})$ and exothermic final $temperature(T_{f})$ were decreased by decreasing particle size of ADCA and evolution heats(Q) were increased with it. $T_{o}$ and Q for $6.1{\sim}7.2{\mu}m$ ADCA were increased by increasing heating rate at constant sample weight and activation energy was about 37.29kcal/mol. A positive gas pressure was employed in the elucidation of the decomposition behavior of ADCA because it sublimes during linear heating at atmospheric pressure. $T_{o}$ and Q of ADCA tended to increase with a pressure in air or nitrogen. In the case of azo dye, experimental results showed that $T_{o}$ were about $280{\sim}420^{\circ}C$ and Q were about $2{\sim}30cal/g$.

• Smart Structures and Systems
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• 제6권2호
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• pp.91-100
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• 2010

An experimental study was carried out to investigate the shape control of plates via embedded shape memory alloy (SMA) wires. An extensive body of literature proposes the use of SMA wires to actively modify the shape or stiffness of a structure; in most cases, however, the study focuses on modeling and little experimental data is available. In this work, a simple proof of concept specimen was built by attaching four prestrained SMA wires to one side of a carbon fiber laminate plate strip. The specimen was clamped at one end and tested in an environmental chamber, measuring the tip displacement and the SMA temperature. At heating, actuation of the SMA wires bends the plate; at cooling deformation is partially recovered. The specimen was actuated a few times between two fixed temperatures $T_c$ and $T_h$, whereas in the last actuation a temperature $T_f$ > $T_h$ was reached. Contrary to most model predictions, in the first actuation the transformation temperatures are significantly higher than in the following cycles, which are stable. Moreover, if the temperature $T_h$ is exceeded, two separate actuations occur during heating: the first follows the path of the stable cycles; the second, starting at $T_h$, is similar to the first cycle. An interpretation of the phenomenon is given using some differential scanning calorimeter (DSC) measurements. The observed behavior emphasizes the need to build a more comprehensive constitutive model able to include these effects.

• 한국식품영양과학회지
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• 제22권1호
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• pp.40-47
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• 1993

동부 앙금의 호화성질을 조사한 결과 물결합능력은 52$^{\circ}C$이후 급격히 증가하였고, 현탁액의 광투과도는 $65^{\circ}C$ 이후 직선적으로 증가하였으며 호화 온도는 63.4~76.$0^{\circ}C$이었다. 동부 앙금은 일단계의 팽윤과 용해도가 낮은 특징을 보였고, 호화에 필요한 수분 함량은 37%이었다. 아밀로그래프의 최고점도는 농도가 증가 할 수록 높아졌으나 일정한 농도에서 가열 온도에 따른 영향은 없었다. 각 가열 온도에서 20분 후의 점도와 3$0^{\circ}C$에서의 점도는 일정한 농도에서 가열 온도와 부의 상관관계 (p< 0.05)를, 냉각 점도는 20분 후의 점도와 농도에 관계없이 정의 상관관계 (p<0.05)를 보였다.

• 한국결정성장학회지
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• 제6권2호
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• pp.275-285
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• 1996

The effect of heat-treatment on catalytic crystallization in $LI_2O-Al_2O_3-SiO_2$ glass system over its glass transition temperature was investigated. Glass composition $4Li_2O{cdot}22AL_2O_3{cdot}66SiO_2{cdot}2TiO_2{cdot}2.5ZrO_2{cdot}1.5P_2O_5{cdot}1.0Na_2O{cdot}1.0As_2O_3$ (wt%) was selected and heat-treated at different heating conditions to obtain transparent glass-ceramic. Nucleation and crystallization behaviour of this composition were estimated by differential thermal analysis (DTA) and X-ray diffractometer (XRD) and its thermal expansion coefficients were measured by Dilatometer. As a result, glass transition temperature was $730^{\circ}C$ and two maximum nucleation temperatures were estimated at $730^{\circ}C$ and 82$0^{\circ}C$ using JMA(Johson-Mehl-Avrami) equation by DTA. $ZrTiO_4$ $\beta$-Quartz solid solution and $\beta$-Spodumene crystals were identified by XRD. The optimum crystallization temperature was 92$0^{\circ}C$ and three step heating schedule was expected to be useful to obtain transparent glass-ceramic.

• 대한화학회지
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• 제7권1호
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• pp.1-5
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• 1963

The thermal decomposition process of ammonium paratungstate $5(NH_4)_2O{\cdot}12WO_3{\cdot}5H_2O$ was analysed by the methods of thermogravimetric analysis, differential thermal analysis, quantitative analysis of the ammonia which is released during heating and X-ray powder diffraction in air and in vacuo. There are several endothermic peaks which indicate release of ammonia and exothermic peaks which indicate crystal growth and oxidation of decomposed prodects in air. After water is driven off the ammonia is released at intervals corresponding to the endothermic peaks. The highest temperature at which ammonia is released is about $420^{\circ}C$ in air and $480^{\circ}C$ in vacuo. In air the crystal structure of paratungstate is conserved up to a temperature of $300^{\circ}C$ at which the remaining ammonia is about 4 mols. At $320^{\circ}C$ the remaining ammonia becomes less than 2 mols and the paratungstate structure changes into the amorphous state. After that ${\gamma}$ oxide is produced and is oxidized to ${\alpha}$ oxide in the temperature range of 400-$500^{\circ}C$ in air. In vacuo however the endothermic peaks and structural changes occur at lower temperatures and the structure of ${\gamma}$ oxide is conserved up to temperatures higher than $500^{\circ}C$.

• 전기의세계
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• 제23권6호
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• pp.49-55
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• 1974

Amorphous semiconductor from As 30 Te 48 Ge 10 Si 12 was prepared, and studied electron microscopy, X-ray analysis and resistivity measurement. It's resistivity is 1.56*10$^{6}$ .ohm.-cm when small ampule is used for preparing sample it is found that no phase separation has occurced by electron microscopy, and that phase transition temperature is 232.deg. C by differential Thermal Analysis. The specimen showed threshold switching that the low resistance state occur at critical electric field and the resistance recover at low applied field. Critical electric field of the switching is 10$^{5}$ V/cm at room temperature. Threshold voltage secreace exponentially with increasing ambient temperature and at that each voltage resistance of the switching device increase exponentially. According to the series resistance and applied vottage current slope on the V-I curve is varied. When applied voltage is decreased after switching, the resistance of the switching device is increased. By this result the origin of the switching is the Joule's heating.

• 생물환경조절학회지
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• 제8권3호
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• pp.152-163
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• 1999

온수난방시스템 온실의 디지털 온도제어 수식모형을 수립하고, 이 수식모형을 이용하여 제어시뮬레이션을 실시하여 최적의 온도제어 방법을 구명하였다. 이용된 제어기법은 종래의 온수온도 일정 공급ON-OFF 제어, 비례제어, PI 제어, PID 제어기법이었으며, 시뮬레이션을 이용해 제어기법별 제어성능을 비교 분석하였다. 대상유리온실의 실내온도( T$_{i}$ )에 관한 디지털 제어수식모형은 공급온수온도( T$_{w}$ )와 외기온도( T$_{o}$ )가 관련된 T$_{i}$($textsc{k}$＋1)＝ 0.851.T$_{i}$($textsc{k}$)＋0.055.T$_{w}$($textsc{k}$)＋0.094.T$_{o}$ ($textsc{k}$)로 나타났다. 온실의 실내온도제어 시뮬레이션을 실시한 결과 종래의 온수온도 일정공급 ON-OFF 제어, P 제어, PI 제어,PID 제어의 정정시간, 오버슛트, 정상오차는 각각 무한, 3.5$0^{\circ}C$, 3.5$0^{\circ}C$ / 30분, 2.37$^{\circ}C$, 0.51$^{\circ}C$ / 21분, 0.0$0^{\circ}C$, 0.23$^{\circ}C$ / 18분, 0.0$0^{\circ}C$, 0.23$^{\circ}C$로 나타났으며, 온수난방시스템 온실의 온도제어에 가장 적합한 제어기법은 PI와 PID제어인 것으로 나타났다 또한 미분이득은 온실의 난방계에 거의 영향을 미치지 않지만 적분이득은 큰 영향을 미치는 것으로 나타났다. 나타났다.

• Journal of Welding and Joining
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• 제24권2호
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• pp.57-63
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• 2006

In this study, the curing kinetics and thermal degradation of underfill were investigated using differential scanning calorimetry (DSC) and thermo gravimetry analysis (TGA). The mechanical and thermal properties of underfill were characterized using dynamic mechanical analysis (DMA) and thermo-mechanical analysis (TMA). Also, we presented on underfill dispensing process using Prostar tool. The non-isothermal DSC scans at various heating rates, the exothermic reaction peak became narrower with increasing the heating rate. The thermal degradation of underfill was composed of two processes, which involved chemical reactions between the degrading polymer and oxygen from the air atmosphere. The results of fluidity phenomena were simulated using Star CD program, the fluidity of the underfills with lower viscosity was faster.